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Synthesis and structure of trans-diaquabis(dimethylsulfoxide)bis(3,5-dinitrobenzoato)copper(II)

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Abstract

Single crystal of [Cu(DMSO)2(3,5-DNB)2(OH2)2], where DMSO-dimethylsulfoxide, 3,5-DNB-3,5-dinitrobenzoate, has been synthesized and its crystal structure is determined. Crystals belong to monoclinic symmetry, space group is P21/n, Z = 2, a = 10.911(4) Å, b = 5.362(2) Å, c = 22.673(7) Å, β = 92.06(2)°, V = 1325.8(1) Å3, T = 293 K. Final value of R = 0.040 was obtained for 1804 independent reflections with I > 3σ(I). The structure is built from complex molecules.

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References

  1. M. L. Rozenfeld, Corrosion and Protection from Corrosion [in Russion], V. 1, Itogi Nauki, Moscow (1971) p. 156.

    Google Scholar 

  2. M. L. Rozenfeld and V. P. Persiantseva, Dokl. Akad. Nauk SSSR, 156, No. 1, 162 (1964).

    CAS  Google Scholar 

  3. V. P. Persiantseva, M. L. Rozenfeld, and N. M. Gavrish, Metal Protection [in Russia], 1, No. 4, 392 (1971).

    Google Scholar 

  4. A. E. Shvelashvili, É. B. Miminoshvili, and V. K. Bel’skii, GEN, 1, 105–109 (2001).

    Google Scholar 

  5. É. B. Miminoshvili, A. N. Sobolev, K. É. Miminoshvili, and T. N. Sakvarelidze, Acta Crystallogr., E60, 319–321 (2004).

    Google Scholar 

  6. É. B. Miminoshvili, A. N. Sobolev, T. N. Sakvarelidze, et al., ibid., C59, 118–120 (2003).

    Google Scholar 

  7. É. B. Miminoshvili, K. É. Miminoshvili, and A. N. Sobolev, ibid., E61, 775–777 (2005).

    Google Scholar 

  8. É. B. Miminoshvili, “X-ray Investigation of Structure and Packing Pecularities of Structural Units in Coordinate Compounds of 3d-Metals,” Physico-Mathematical Sciences Candidate’s Dissertattion, Tbilisi, Georgia (2005).

  9. G. M. Sheldrick, User Manual, Revision 4, Nicolet XRD Corporation, USA (1983).

    Google Scholar 

  10. T. Hökelek, Y. Mert, and C. Ünalerouglu, Acta Crystallogr., 54, 310–313 (1998).

    Google Scholar 

  11. I. Leban, N. Grgurevic, J. Sieler, and P. Segedin, ibid., 53, 854–856 (1997).

    Google Scholar 

  12. A. F. Wells, Structural Inorganic Chemistry (Unknown Binding), Clarendon Press, 4th edition (1975), 1095 p.

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Authors and Affiliations

  1. Georgian Technical University, Tbilisi

    É. B. Miminoshvili & K. É. Miminoshvili

  2. Institute of Physical and Organic Chemistry, Georgian Academy of Sciences, Tbilisi

    G. P. Adeishvili

Authors
  1. É. B. Miminoshvili
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  2. K. É. Miminoshvili
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  3. G. P. Adeishvili
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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 1, pp. 95–99, January–February, 2006.

Original Russian Text Copyright © 2006 by É. B. Miminoshvili, K. É. Miminoshvili, and G. P. Adeishvili

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Miminoshvili, É.B., Miminoshvili, K.É. & Adeishvili, G.P. Synthesis and structure of trans-diaquabis(dimethylsulfoxide)bis(3,5-dinitrobenzoato)copper(II). J Struct Chem 47, 91–96 (2006). https://doi.org/10.1007/s10947-006-0271-2

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  • DOI: https://doi.org/10.1007/s10947-006-0271-2

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