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Thermal stability and behavior of platelet-shaped SBA-15 containing Zr

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Abstract

SBA-15 with a platelet shape, containing Zr(IV), (Zr-SBA-15) was prepared to characterize its thermal stability and thermal behavior in comparison with conventional, rod-shaped SBA-15. The small angle X-ray diffraction (SAXRD) lines of Zr-SBA-15 and SBA-15 disappeared at 1,373 and 1,273 K, respectively. The pore diameter of the Zr-SBA-15 was almost constant from 773 to 1,073 K and decreased above 1,173 K, whereas the SBA-15 pore diameter decreased with increasing calcination temperature from 773 to 1,173 K. Therefore, the thermal stability of the Zr-SBA-15 was higher than that of SBA-15. Zr(IV) distributed within the framework prevents the pores from shrinkage by heating, and the Zr(IV) forms a ZrO2 crystalline phase above 1,273 K. When calcined at 1,873 K, the Zr-SBA-15 mesostructure collapsed while maintaining its hexagonal platelet shape. The collapse of the mesostructure at 1,373 K, caused the Zr-SBA-15 to shrink in the width direction by approximately 40% compared with that calcined at 773 K, although the dimension hardly changed in the thickness direction.

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Acknowledgments

The authors thank Mr. Masatoshi Nakazawa, Mr. Mitsuaki Huruya, Mr. Makoto Miyashita, and Mr. Takahiro Gotou of the Materials Characterization Central Laboratory of Waseda University for SAXRD measurements, FE-SEM and TEM observations.

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Authors and Affiliations

  1. Department of Resources and Environmental Engineering, School of Creative Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, 169-8555, Japan

    Yoshihiro Usami & Atsushi Yamazaki

  2. Department of Materials and Life Science, Faculty of Science and Technology, Seikei University, 3-3-1 Kichijoji-Kitamachi, Musashino, Tokyo, 180-8633, Japan

    Teruhisa Hongo

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  1. Yoshihiro Usami
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  2. Teruhisa Hongo
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  3. Atsushi Yamazaki
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Correspondence to Teruhisa Hongo.

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Usami, Y., Hongo, T. & Yamazaki, A. Thermal stability and behavior of platelet-shaped SBA-15 containing Zr. J Porous Mater 19, 897–902 (2012). https://doi.org/10.1007/s10934-011-9547-9

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