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Immobilization of Zn(II) on Chitosan from Callinectes Sapidus Shells as an Efficient Heterogeneous Catalyst for the Synthesis of 4H-Pyran Derivatives

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Abstract    

A new sustainable heterogeneous catalyst for the effective synthesis of 4H-pyran derivatives under mild reaction conditions was investigated. This heterogeneous catalyst was prepared through the complexation reaction between the naturally obtained chitosan from Callinectes sapidus shells and zinc(II) ions (Zn(II)/Chitosan), and characterized using a variety of techniques, including thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM), and infrared spectroscopy (IR). The corresponding 4H-pyran derivatives were obtained in good to excellent yields (58–96%) in the presence of Zn(II)/chitosan catalyst using water as solvent at 60°C for only 20 min. The catalyst was easily separated from the reaction mixture by simple filtration, resulting in the desired products with excellent purity. In comparison to numerous other catalyst systems for the synthesis of 4H-pyran derivatives, Zn(II)/chitosan, a new sustainable heterogeneous catalyst, demonstrated remarkable efficacy in an environmentally benign solvent, allowing the desired products to be produced under more environmentally friendly reaction conditions.

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Acknowledgements

The authors are thankful to Chouaib Doukkali University and Cadi Ayyed University for providing laboratory and analytical facilities.

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Authors and Affiliations

  1. Laboratoire de Chimie de Coordination et d’Analytique (LCCA), Département de Chimie, Faculté des Sciences, Université Chouaïb Doukkali, P.O. Box 20, 24000, El Jadida, Morocco

    Azzeddine Taoufyk & Mahfoud Agunaou

  2. Laboratory of Plant Biotechnology, Ecology and Ecosystem Valorization—URL CNRST N=10, Faculty of Sciences El Jadida, University Chouaib Doukkali, P.O. Box 20, 24000, El Jadida, Morocco

    Zahira Belattmania & Brahim Sabour

  3. Laboratoire de Recherche en Développement Durable et Santé, Faculté des Sciences et Techniques de Marrakech, Université Cadi Ayyad, 40000, Marrakech, Morocco

    Khaoula Oudghiri & Moha Taourirte

  4. Laboratoire de Spectroscopie, Modélisation Moléculaire, Matériaux Nanomaterial’s Eeau et Environnement, Faculté des Sciences, Université Mohamed V à Rabat, Rabat, Morocco

    Elhouceine Benhadria

  5. Département de Chimie, Faculté des Sciences, Université Ibn Zohr, 80000, Agadir, Morocco

    Noura Aflak

  6. Laboratory of Catalysis and Corrosion of Materials, Faculty of Sciences, University Chouaib Doukkali, P.O. Box 20, 24000, El Jadida, Morocco

    Fouad Bentiss

  7. Materials and Transformations Unit, UMR 8207-UMET, University of Lille, CNRS, INRAE, Centrale Lille, 59000, Lille, France

    Fouad Bentiss

  8. Laboratoire de Chimie Analytique et Moléculaire, LCAM, Faculté Polydisciplinaire de Safi, Université Cadi Ayyad, 46030, Safi, Morocco

    Lahoucine Bahsis

Authors
  1. Azzeddine Taoufyk
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  2. Zahira Belattmania
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  3. Khaoula Oudghiri
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  4. Elhouceine Benhadria
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  6. Moha Taourirte
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  9. Lahoucine Bahsis
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  10. Mahfoud Agunaou
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Contributions

Taoufyk Azzeddine: Conceptualization, Methodology. Zahira Belattmania: Data curation, Writing- Original draft preparation. Khaoula Oudghiri: Data curation. Elhouceine Benhadria: Data curation. Noura Aflak: Data curation. Moha Taourirte: Investigation; Fouad Bentiss: Visualization, Investigation; Brahim Sabour: Visualization, Investigation. Mahfoud Agunaou: Supervision. Lahoucine Bahsis: Conceptualization, Methodology, and Writing- Reviewing and Editing,

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Correspondence to Lahoucine Bahsis.

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Taoufyk, A., Belattmania, Z., Oudghiri, K. et al. Immobilization of Zn(II) on Chitosan from Callinectes Sapidus Shells as an Efficient Heterogeneous Catalyst for the Synthesis of 4H-Pyran Derivatives. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-024-03128-x

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