Skip to main content
SpringerLink
Log in

Fabrication and Boosting the Morphological and Optical Properties of PVP/SiC/Ti Nanosystems for Tailored Renewable Energies and Nanoelectronics Fields

  • Research
  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

The present study objects to synthesize of PVP/SiC/Ti nanostructures as a future and promising nanomaterials for nanoelectronics, energy storage and optical approaches. The morphological and optical properties of PVP/SiC/Ti nanostructures were examined. Results of optical characteristics demonstrated the PVP/SiC/Ti nanostructures have stable absorbance(A) at UV and NIR spectra where the absorbance increased about 65.7% at λ = 400 nm and 65.3% at λ = 760 nm while transmission decreased when the concentration of PVP/SiC/Ti nanostructures increased of 37.5 gm/L, these results can be useful in solar energy fields, optical devices, anti-reflectance coating material, and other modern fields. When the concentration reached of 37.5 gm/L, energy band gap decreased from 3.25 to 2.25 eV, this behaviour makes the PVP/SiC/Ti nanostructures are suitable in numerous optoelectronics fields. The other optical factors of PVP/SiC/Ti nanostructures improved with rising concentration. The thermal energy storage results illustrated to obtain on gain of melting time reached 60%, this result makes the PVP–SiC–Ti–H2O nanofluids are multifunctional for renewable energy applications. Finally, the achieved results indicated to the PVP/SiC/Ti nanostructures are potential and promising to utilize in solar energy and optoelectronics approaches with excellent optical factors compared of other nanomaterials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

Data Availability

Yes, the data are available.

References

  1. I.A. Aljarrah, A.A. Bani-Salameh, A. Ahmad et al., Effect of UV-illumination on refractive index of PMMA/metal oxide nanocomposite films. Polym. Bull. (2022). https://doi.org/10.1007/s00289-022-04409-6

    Article  Google Scholar 

  2. R.M. Abdullah, S.M. Aziz, S.M. Mamand, A.Q. Hassan, S.A. Hussein, M.F.Z. Kadir, Reducing the crystallite size of spherulites in PEO-based polymer nanocomposites mediated by carbon nanodots and Ag nanoparticles. Nanomaterials (2019). https://doi.org/10.3390/nano9060874

    Article  PubMed  PubMed Central  Google Scholar 

  3. A. Hashim, A. Hadi, Novel piezoelectric materials prepared from (carboxymethyl cellulose–starch) blend-metal oxide nanocomposites. Sensor Letters (2017). https://doi.org/10.1166/sl.2017.3910

    Article  Google Scholar 

  4. M.A. Habbeb, A. Hashim, A.R.K. Abdul, The dielectric properties for (PMMA-LiF) composites. Eur. J. Sci. Res. 61(3), 367–371 (2011)

    Google Scholar 

  5. H.O. Gülsoy, S. Özbey, S. Pazarlioglu, M. Çiftci, A.H. Akyurt, Sintering and mechanical properties of titanium composites reinforced nano sized Al2O3 particles. Int. J. Mater. Mech. Manuf. 4(2), 111–114 (2016)

    Google Scholar 

  6. A. Hashim, S.M. Alshrefi, H.H. Abed et al., Synthesis and boosting the structural and optical characteristics of PMMA/SiC/CdS hybrid nanomaterials for future optical and nanoelectronics applications. J. Inorg. Organomet. Polym. (2023). https://doi.org/10.1007/s10904-023-02866-8

    Article  Google Scholar 

  7. H.K. Jaafar, A. Hashim, B.H. Rabee, Fabrication and tuning the morphological and optical characteristics of PMMA/PEO/SiC/BaTiO3 newly quaternary nanostructures for optical and quantum electronics fields. Opt. Quant. Electron. 55, 989 (2023). https://doi.org/10.1007/s11082-023-05208-7

    Article  CAS  Google Scholar 

  8. A. Hashim, B. Mohammed, A. Hadi et al., Synthesis and augment structural and optical characteristics of PVA/SiO2/BaTiO3 nanostructures films for futuristic optical and nanoelectronics applications. J. Inorg. Organomet. Polym. (2023). https://doi.org/10.1007/s10904-023-02846-y

    Article  Google Scholar 

  9. N.A.H. Al-Aaraji, A. Hashim, H.M. Abduljalil et al., Tailoring the design, structure and spectroscopic characteristics of SiC/CuO doped transparent polymer for photonics and quantum nanoelectronics fields. Opt. Quant. Electron. 55, 743 (2023). https://doi.org/10.1007/s11082-023-05048-5

    Article  CAS  Google Scholar 

  10. M.H. Meteab, A. Hashim, B.H. Rabee, Synthesis and characteristics of SiC/MnO2/PS/PC quaternarynanostructures for advanced nanodielectrics fields. Silicon 15, 1609–1620 (2023). https://doi.org/10.1007/s12633-022-02114-7

    Article  CAS  Google Scholar 

  11. M.H. Meteab, A. Hashim, B.H. Rabee, Controlling the structural and dielectric characteristics of PS-PC/Co2O3-SiC hybrid nanocomposites for nanoelectronics applications. Silicon 15, 251–261 (2023). https://doi.org/10.1007/s12633-022-02020-y

    Article  CAS  Google Scholar 

  12. H. Ahmed, A. Hashim, Geometry optimization optical and electronic characteristics of novel PVA/PEO/SiC structure for electronics applications. Silicon 13, 2639–2644 (2021). https://doi.org/10.1007/s12633-020-00620-0

    Article  CAS  Google Scholar 

  13. H. Ahmed, A. Hashim, Structural optical and electronic properties of silicon carbide doped PVA/NiO for low cost electronics applications. Silicon 13, 1509–1518 (2021). https://doi.org/10.1007/s12633-020-00543-w

    Article  CAS  Google Scholar 

  14. N.A.H. Al-Aaraji, A. Hashim, A. Hadi et al., Effect of silicon carbide nanoparticles addition on structural and dielectric characteristics of PVA/CuO nanostructures for electronics devices. Silicon 14, 4699–4705 (2022). https://doi.org/10.1007/s12633-021-01265-3

    Article  CAS  Google Scholar 

  15. G. Colston, M. Myronov, Controlling the optical properties of monocrystalline 3C–SiC heteroepitaxially grown on silicon at low temperatures. Semicond. Sci. Technol. (2017). https://doi.org/10.1088/1361-6641/aa8b2a

    Article  Google Scholar 

  16. W. Li, C. Guo, C. Cui, J. Bao, G. Zhang, Y. Zhang, S. Li, G. Wang, Microstructure evolution and performance improvement of silicon carbide ceramics via impregnation method. Materials 15, 1 (2022). https://doi.org/10.3390/ma15051717

    Article  CAS  Google Scholar 

  17. N.S. Alghunaim, Effect of CuO nanofiller on the spectroscopic properties, dielectric permittivity and dielectric modulus of CMC/PVP nanocomposites. J. Mater. Res. Technol. 8, 3596–3602 (2019). https://doi.org/10.1016/j.jmrt.2019.05.022

    Article  CAS  Google Scholar 

  18. N.S. Alatawi, A.M. Abdelghany, N.H. Elsayed, The correlation between density functional theory (DFT) and spectroscopic investigations of PVA/PVP nanocomposites containing gold nanoparticles. Res. J. Pharm. Biol. Chem. Sci. 8(3), 263–272 (2017)

    CAS  Google Scholar 

  19. A.A.A. Ahmed, A.M. Al-Hussam, A.A. Abdulwahab, A.N.A.A. Ahmed, The impact of sodium chloride as dopant on optical and electrical properties of polyvinyl alcohol. AIMS Mater. Sci. (2018). https://doi.org/10.3934/matersci.2018.3.533

    Article  Google Scholar 

  20. A.M.A. Henaish, A.S. Abouhaswa, Effect of WO3 nanoparticle doping on the physical properties of PVC polymer. Bull. Mater. Sci. (2020). https://doi.org/10.1007/s12034-020-2109-5

    Article  Google Scholar 

  21. K. Mahalakshmi, V. Lakshmi, R. MaryJenila, Optical, structural and morphological analysis of rGO decorated CoSe2 nanocomposites,. J. Innov. Sci. Eng. Technol. 8, 180 (2021)

    Google Scholar 

  22. N. Mahfoudh, K. Karoui, A. Ben, Rhaiem, Optical studies and dielectric response of [DMA]2MCl4 (M¼ Zn and Co) and [DMA]2ZnBr4. RSC Adv. (2021). https://doi.org/10.1039/d1ra03652a

    Article  PubMed  PubMed Central  Google Scholar 

  23. O. Peshawa, K.A. Amin, S.R. Ketuly, F. Saeed, F.F. Muhammadsharif, M.D. Symes, K. Sulaiman, Synthesis, spectroscopic, electrochemical and photophysical properties of high band gap polymers for potential applications in semi-transparent solar cells. BMC Chem. (2021). https://doi.org/10.1186/s13065-021-00751-4

    Article  Google Scholar 

  24. A.O. Salohub, A.A. Voznyi, O.V. Klymov, N.V. Safryuk, D.I. Kurbatov, A.S. Opanasyuk, Determination of fundamental optical constants of Zn2SnO4 films. Quantum Electron. Optoelectron. (2017). https://doi.org/10.15407/spqeo20.01.079

    Article  Google Scholar 

  25. S.M. Ahmed, A.A.A. Darwish, E.A. El-Sabagh, N.A. Mansour, D.E. Abulyazied, E.S. Ali, Physicochemical properties of prepared ZnO/ polystyrene nanocomposites: structure, mechanical and optical. J. Ovonic Res. 16(1), 71 (2020)

    Article  CAS  Google Scholar 

  26. H. Ahmed, A. Hashim, H.M. Abduljalil, Determination of optical parameters of films Of PVA/TiO2/SiC and PVA/MgO/SiC nanocomposites for optoelectronics and UV-detectors. Ukr. J. Phys. Vol (2020). https://doi.org/10.15407/ujpe65.6.533

    Article  Google Scholar 

  27. H. Ahmed, A. Hashim, Exploring the design, optical and electronic characteristics of silicon doped (PS-B) new structures for electronics and renewable approaches. Silicon 14, 7025–7032 (2022). https://doi.org/10.1007/s12633-021-01465-x

    Article  CAS  Google Scholar 

  28. H. Ahmed, A. Hashim, Structure optical, electronic and chemical characteristics of novel (PVA-CoO) structure doped with silicon carbide. Silicon 13, 4331–4344 (2021). https://doi.org/10.1007/s12633-020-00723-8

    Article  CAS  Google Scholar 

  29. H. Ahmed, A. Hashim, Design and characteristics of novel PVA/PEG/Y2O3 structure for optoelectronics devices. J. Mol. Model. 26, 210 (2020). https://doi.org/10.1007/s00894-020-04479-1

    Article  CAS  PubMed  Google Scholar 

  30. A. Hashim, Enhanced morphological, optical and electronic characteristics of WC NPs doped PVP/PEO for flexible and lightweight optoelectronics applications. Opt. Quant. Electron. 53, 478 (2021). https://doi.org/10.1007/s11082-021-03100-w

    Article  CAS  Google Scholar 

  31. F.L. Rashid, A. Hashim, M.A. Habeeb, S.R. Salman, H. Ahmed, Preparation of PS-PMMA copolymer and study the effect of sodium fluoride on its optical properties. J. Eng. Appl. Sci. 8(5), 137–139 (2013)

    Google Scholar 

  32. A. Hashim, A. Hadi, Synthesis and characterization of (MgO–Y2O3–CuO) nanocomposites for novel humidity sensor application. Sens. Lett. (2017). https://doi.org/10.1166/sl.2017.3900

    Article  Google Scholar 

  33. F.A. Jasim, A. Hashim, A.G. Hadi, F. Lafta, S.R. Salman, H. Ahmed, Preparation of (pomegranate peel-polystyrene) composites and study their optical properties. Res. J. Appl. Sci. 8(9), 439–441 (2013)

    Google Scholar 

  34. A. Hashim, A. Jassim, Novel of (PVA-ST-PbO2,) bio nanocomposites: preparation and properties for humidity sensors and radiation shielding applications. Sens. Lett. (2017). https://doi.org/10.1166/sl.2018.3915

    Article  Google Scholar 

  35. H. Ahmed, A. Hashim, Lightweight flexible and high energies absorption property of PbO2 doped polymer blend for various renewable approaches. Trans. Electr. Electron. Mater. 22, 335–345 (2021). https://doi.org/10.1007/s42341-020-00244-6

    Article  Google Scholar 

  36. M.H. Meteab, A. Hashim, B.H. Rabee, Synthesis and tailoring the morphological, optical, electronic and photodegradation characteristics of PS–PC/MnO2–SiC quaternary nanostructures. Opt. Quant. Electron. 55, 187 (2023). https://doi.org/10.1007/s11082-022-04447-4

    Article  CAS  Google Scholar 

  37. A. Hashim, A. Hadi, N.A.H. Al-Aaraji, Fabrication and augmented electrical and optical characteristics of PMMA/CoFe2O4/ZnCoFe2O4 hybrid nanocomposites for quantum optoelectronics nanosystems. Opt. Quant. Electron. 55, 716 (2023). https://doi.org/10.1007/s11082-023-04994-4

    Article  CAS  Google Scholar 

  38. A. Hashim, A. Hadi, N.A.H. Al-Aaraji et al., Fabrication and augmented structural, optical and electrical features of PVA/Fe2O3/SiC hybrid nanosystem for optics and nanoelectronics fields. Silicon 15, 5725–5734 (2023). https://doi.org/10.1007/s12633-023-02471-x

    Article  CAS  Google Scholar 

  39. A.M. Alsaad, A.A. Ahmad, I.-A. Qattan, A.R. El-Ali, S.A.A. Al Fawares, Q.M. Al-Bataineh, Synthesis of optically tunable and thermally stable PMMA–PVA/CuO NPs hybrid nanocomposite thin films. Polymers (2021). https://doi.org/10.3390/polym13111715

    Article  PubMed  PubMed Central  Google Scholar 

  40. N.A.H. Al-Aaraji, A. Hashim, A. Hadi et al., Synthesis and enhanced optical characteristics of silicon carbide/copper oxide nanostructures doped transparent polymer for optics and photonics nanodevices. Silicon 14, 10037–10044 (2022). https://doi.org/10.1007/s12633-022-01730-7

    Article  CAS  Google Scholar 

  41. A. Hashim, M.H. Abbas, N.A.H. Al-Aaraji et al., Facile fabrication and developing the structural, optical and electrical properties of SiC/Y2O3 nanostructures doped PMMA for optics and potential nanodevices. Silicon 15, 1283–1290 (2023). https://doi.org/10.1007/s12633-022-02104-9

    Article  CAS  Google Scholar 

  42. A. Hashim, Z.S. Hamad, Novel of (niobium carbide-biopolymer blend) nanocomposites: characterization for bioenvironmental applications. J. Bionanosci. (2018). https://doi.org/10.1166/jbns.2018.1551

    Article  Google Scholar 

  43. D. Hassan, A. Hashim, Preparation and studying the structural and optical properties of (poly-methyl methacrylate-lead oxide) nanocomposites for bioenvironmental applications. J. Bionanosci. (2018). https://doi.org/10.1166/jbns.2018.1537

    Article  Google Scholar 

  44. A. Hashim, K.H.H. Al-Attiyah, S.F. Obaid, Fabrication of novel (biopolymer blend-lead oxide nanoparticles) nanocomposites: structural and optical properties for low cost nuclear radiation shielding. Ukr. J. Phys. (2019). https://doi.org/10.15407/ujpe64.2.157

    Article  Google Scholar 

  45. H. Ahmed, A. Hashim, Design and tailoring the optical and electronic characteristics of silicon doped PS/SnS2 new composites for nano-semiconductors devices. Silicon 14, 6637–6643 (2022). https://doi.org/10.1007/s12633-021-01449-x

    Article  CAS  Google Scholar 

  46. A. Hashim, A. Hadi, M.H. Abbas, Synthesis and unraveling the morphological and optical features of PVP-Si3N4-Al2O3 nanostructures for optical and renewable energies fields. Silicon (2023). https://doi.org/10.1007/s12633-023-02529-w

    Article  Google Scholar 

  47. A. Hashim, A. Hadi, M.H. Abbas, Fabrication and unraveling the morphological, optical and electrical features of PVA/SnO2/SiC nanosystem for optics and nanoelectronics applications. Opt. Quant. Electron. 55, 642 (2023). https://doi.org/10.1007/s11082-023-04929-z

    Article  CAS  Google Scholar 

  48. A. Hashim, A. Jassim, Novel of biodegradable polymers-inorganic nanoparticles: structural, optical and electrical properties as humidity sensors and gamma radiation shielding for biological applications. J. Bionanosci. (2018). https://doi.org/10.1166/jbns.2018.1518,(

    Article  Google Scholar 

  49. T.S. Soliman, S.A. Vshivkov, Effect of Fe nanoparticles on the structure and optical properties of polyvinyl alcohol nanocomposite films. J. Non-cryst. Solids (2019). https://doi.org/10.1016/j.jnoncrysol.2019.05.028

    Article  Google Scholar 

  50. I.R. Agool, F.S. Mohammed, A. Hashim, The effect of magnesium oxide nanoparticles on the optical and dielectric properties of (PVA-PAA-PVP) blend. Adv. Environ. Biol. 9(11), 1–10 (2015)

    Google Scholar 

  51. B.H. Rabee, A. Hashim, Synthesis and characterization of carbon nanotubes -polystyrene composites. Eur. J. Sci. Res. 60(2), 247–254 (2011)

    Google Scholar 

  52. F.A. Jasim, F. Lafta, A. Hashim, M. Ali, A.G. Hadi, Characterization of palm fronds-polystyrene composites. J. Eng. Appl. Sci. 8(5), 140–142 (2013)

    Google Scholar 

  53. S. Hadi, A. Hashim, A. Jewad, Optical properties of (PVA-LiF) composites. Aust. J. Basic Appl. Sci. 5(9), 2192–2195 (2011)

    CAS  Google Scholar 

  54. A. Atta, M.M. Abdelhamied, A.M. Abdelreheem, M.R. Berber, Flexible methyl cellulose/polyaniline/silver composite films with enhanced linear and nonlinear optical properties. Polymers (2021). https://doi.org/10.3390/polym13081225

    Article  PubMed  PubMed Central  Google Scholar 

  55. H.M. Gayitri, M. Al-Gunaid, Optical, structural and thermal properties of hybrid PVA/CaAl2ZrO6 nanocomposite films. Indian J. Eng. Mater. Sci. 27, 320–332 (2020)

    CAS  Google Scholar 

  56. C. Tyagi, A. Devi, Alteration of structural, optical and electrical properties of CdSe incorporated polyvinyl pyrrolidone nanocomposite for memory devices. J. Adv. Dielectr. Vol (2018). https://doi.org/10.1142/S2010135X18500200

    Article  Google Scholar 

  57. H.A.J. Hussien, A. Hashim, Synthesis and exploring the structural, electrical and optical characteristics of PVA/TiN/SiO2 Hybrid nanosystem for photonics and electronics nanodevices. J. Inorg. Organomet. Polym. 33, 2331–2345 (2023). https://doi.org/10.1007/s10904-023-02688-8

    Article  CAS  Google Scholar 

  58. H.A.J. Hussien, R.G. Kadhim, A. Hashim, Investigating the low cost photodegradation performance against organic pollutants using CeO2/MnO2/ polymer blend nanostructures. Opt. Quant. Electron. 54, 704 (2022). https://doi.org/10.1007/s11082-022-04094-9

    Article  CAS  Google Scholar 

  59. N.H. Al-Garah, F.L. Rashid, A. Hadi, A. Hashim, Synthesis and characterization of novel (organic–inorganic) nanofluids for antibacterial, antifungal and heat transfer applications. J. Bionanosci. (2018). https://doi.org/10.1166/jbns.2018.1538

    Article  Google Scholar 

  60. A.S. Shareef, F.L. Rashid, A. Hadi, A. Hashim, Water-polyethylene glycol/(SiC–WC) and (CeO2–WC) nanofluids for saving solar energy. Int. J. Sci. Technol. Res. 8(11), 1041 (2019)

    Google Scholar 

  61. A. Hadi, D. Hashim, Fabrication of new ceramics nanocomposites for solar energy storage and release. Bull. Electr. Eng. Inf. (2020). https://doi.org/10.11591/eei.v9i1.1323

    Article  Google Scholar 

  62. F.L. Rashid, S.M. Talib, A. Hadi, A. Hashim, Novel of thermal energy storage and release: water/(SnO2 -TaC) and water/(SnO2–SiC) nanofluids for environmental applications. Series: Mater. Sci. Eng. 454, 012113 (2018). https://doi.org/10.1088/1757-899X/454/1/012113

    Article  Google Scholar 

  63. A. Hadi, F.L. Rashid, H.Q. Hussein, A. Hashim, Novel of water with (CeO2-WC) and (SiC-WC) nanoparticles systems for energy storage and release applications, IOP Conference Series. Materials Science and Engineering (2019). https://doi.org/10.1088/1757-899X/518/3/032059

    Article  Google Scholar 

Download references

Acknowledgements

Acknowledgment to University of Babylon.

Funding

The authors have not disclosed any funding.

Author information

Authors and Affiliations

  1. Department of Physics, College of Education for Pure Sciences, University of Babylon, Babylon, Iraq

    Ahmed Hashim

  2. Department of Ceramic and Building Materials, College of Materials Engineering, University of Babylon, Babylon, Iraq

    Aseel Hadi

  3. Al-Zahraa University for Women, Karbala, Iraq

    Hamed Ibrahim

  4. Petroleum Engineering Department, College of Engineering, University of Kerbala, Karbala, Iraq

    Farhan Lafta Rashid

Authors
  1. Ahmed Hashim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Aseel Hadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hamed Ibrahim
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Farhan Lafta Rashid
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

AH, AH, HI, FLR wrote the main manuscript text, prepared figures and reviewed the manuscript.

Corresponding author

Correspondence to Ahmed Hashim.

Ethics declarations

Conflict of interest

The authors have not disclosed any conflict of interest.

Research Involving Human and Animal Participants

The Research is not involving the studies on human or their data.

Consent to Participate

Consent to participate.

Consent for Publication

Consent for Publication.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hashim, A., Hadi, A., Ibrahim, H. et al. Fabrication and Boosting the Morphological and Optical Properties of PVP/SiC/Ti Nanosystems for Tailored Renewable Energies and Nanoelectronics Fields. J Inorg Organomet Polym 34, 1678–1688 (2024). https://doi.org/10.1007/s10904-023-02908-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-023-02908-1

Keywords

Search

Navigation