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Remarkable Removal of Pb(II) Ions from Aqueous Media Using Facilely Synthesized Sodium Manganese Silicate Hydroxide Hydrate/Manganese Silicate as a Novel Nanocomposite

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Abstract

The presence of Pb(II) ions in water causes many diseases, such as anemia, kidney disorders, and nervous system disorders. Therefore, this paper presents the facile hydrothermal synthesis of a novel type of nanocomposites, specifically sodium manganese silicate hydroxide hydrate/manganese silicate nanocomposite (Na4Mn5Si10O24(OH)6·6H2O/Mn2+Mn63+SiO12), which exhibits remarkable efficiency in the uptake of Pb(II) ions from aqueous solutions. The nanocomposites were chemically constructed using the hydrothermal technique in the absence and presence of polyethylene glycol 400 as an organic template to control the morphology, BET surface area, and mean crystallite size. The nanocomposites, which were chemically fabricated in the absence and presence of polyethylene glycol 400, are abbreviated as NF and NP, respectively. In addition, the XRD analysis exhibited that the calculated mean crystallite size of the NF and NP nanocomposites was found to be 18.28 and 60.26 nm, respectively. Due to the inverse relationship between crystallite size and BET surface area, the NF nanocomposite exhibits a higher BET surface area (71.52 m2/g) compared to the NP nanocomposite (46.26 m2/g). Hence, the greatest uptake capacity of the NF nanocomposite towards Pb(II) ions (292.39 mg/g) is greater than that of the NP nanocomposite (210.97 mg/g). Both NF and NP nanocomposites chemically and exothermically capture Pb(II) ions. Also, the adsorption processes obey the pseudo-second-order kinetic model and Langmuir equilibrium isotherm.

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Acknowledgements

Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R185), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

Funding

Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R185), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, 11623, Saudi Arabia

    Ehab A. Abdelrahman & Faisal K. Algethami

  2. Chemistry Department, Faculty of Science, Benha University, Benha, 13518, Egypt

    Ehab A. Abdelrahman

  3. Department of Chemistry, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh, 11671, Saudi Arabia

    Huda S. AlSalem

  4. Department of Chemistry, College of Sciences & Arts, King Abdulaziz University, Rabigh, Saudi Arabia

    Soha T. Al-Goul

  5. Department of Chemistry, Faculty of Applied Sciences, Umm Al-Qura University, Makkah, 21955, Saudi Arabia

    Fawaz A. Saad

  6. Microbiology and Immunology Department, Faculty of Pharmacy, Galala University, Galala City, 11566, Suez, Egypt

    Gharieb S. El-Sayyad

  7. Microbiology and Immunology Department, Faculty of Pharmacy, Ahram Canadian University (ACU), Giza, 12451, Egypt

    Gharieb S. El-Sayyad

  8. Department of Chemistry, College of Science, University of Jeddah, Jeddah, 21589, Saudi Arabia

    Reem M. Alghanmi

  9. Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, 29111, KPK, Pakistan

    Khalil ur Rehman

Authors
  1. Ehab A. Abdelrahman
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  2. Faisal K. Algethami
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  8. Khalil ur Rehman
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Contributions

FKA (Preparing figures and tables-Writing the introduction-Experimental Work), HSA (Research review-Research writing-Experimental work), STA (Experimental work), FAS (Preparing tables and figures), RMA (Revision-Writing the introduction), GSE (Resources-Experimental work), KR (Revision), EAA (Experimental work-Idea-Research review-Research Writing). All authors reviewed the manuscript.

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Correspondence to Ehab A. Abdelrahman.

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Abdelrahman, E.A., Algethami, F.K., AlSalem, H.S. et al. Remarkable Removal of Pb(II) Ions from Aqueous Media Using Facilely Synthesized Sodium Manganese Silicate Hydroxide Hydrate/Manganese Silicate as a Novel Nanocomposite. J Inorg Organomet Polym 34, 1208–1220 (2024). https://doi.org/10.1007/s10904-023-02895-3

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