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Electrochemical Detection of Hydrogen Peroxide Using Copper-Based Metal–Organic Frameworks: Nanoarchitectonics and Sensing Performance

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Abstract

Cu-MOFs are exciting materials with lots of unique characteristics which will be suitable for sensing applications. To date, there have not been any published review on the suitability and efficiency of Cu-MOFs on hydrogen peroxide sensing, despite its huge potential in this regard. This systematic review assessed published articles on the subject using the Web of Science. The included studies were assessed in terms of quality using the risk of bias assessment criteria. Out of the 101 screened articles, 50 studies were eligible and included in this review. Non-enzymatic detection of hydrogen peroxide using copper-based MOFs exhibited better performance in terms of limit of detection, sensitivity, and linear response than enzyme-assisted detection. Ligand type and Cu-MOF synthetic techniques demonstrated a great effect on the structural property of the synthesized MOF, which in turn improved its catalytic property. Based on the available data in the reviewed articles. Cu-MOFs has great potential for use as commercial hydrogen peroxide sensor. The successful design of a sensitive, accurate, and stable hydrogen peroxide sensor will be a significant breakthrough for industrial, medical, and environmental applications.

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(Reproduced with permission from the publisher). b Amperometric response of CuCo–Cu@CoCH with various interferences [38] (Reproduced with permission from the publisher). c Current response of: of h-PtCu/C [27] d current response of PtCu@MOF-74/C [27] (Reproduced with permission from the publisher). e Current response of CuxO NPs@ZIF-8/GCE and f CuxO NPs/GCE to 50 μM H2O2, glucose, d-fructose, sucrose, α-lactose, l-cysteine, AA, UA and DA [41] (Reproduced with permission from the publisher).

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Acknowledgements

The authors gratefully acknowledge Shaqra University, dwadami, Saudi Arabia for the provision of research facilities.

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  1. Department of Chemistry, Faculty of Science and Humanities, Shaqra University, P.O. Box 33, Dawadmi, 17452, Saudi Arabia

    Raja Saad Alruwais

  2. Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Kingdom of Saudi Arabia

    Waheed A. Adeosun

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Alruwais, R.S., Adeosun, W.A. Electrochemical Detection of Hydrogen Peroxide Using Copper-Based Metal–Organic Frameworks: Nanoarchitectonics and Sensing Performance. J Inorg Organomet Polym 34, 14–37 (2024). https://doi.org/10.1007/s10904-023-02787-6

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