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Construction and Properties of Ag-I Polymeric Clusters Attach with Nitrogen Heterocyclic Transition Metal Moiety

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Abstract

Two silver cluster compounds {[Co(1,10′-phen)3]2‧[Ag8I12]} (1) and {[Co(2, 2′-bipy)3]‧[Ag10I11]‧(OH)‧3DMF‧2H2O} (2) (1,10′-phen = 1,10′-phenanthroline, 2, 2′-bipy = 2,2′-bipyridine) were designed and synthesized by solvent evaporation method. The two silver cluster compounds were characterized by elemental analysis, infrared spectroscopy, ultraviolet spectroscopy, thermogravimetric analysis and X-ray powder diffraction. The crystal structures of compounds 1 and 2 were determined by X-ray crystallography diffraction. Through the electrostatic interaction between the metallic Ag cluster moiety and the metallic Co cluster moiety, form stable interlaced layered super molecular structures. In order to explore functional properties, the catalytic reduction of p-nitrophenol (PNP) and electrochemical behavior of compounds 1 and 2 were explored. The results show that compounds 1 and 2 can efficiently catalyze the reduction of PNP in the aqueous solution, and the reduction and removal rate can reach more than 90%.

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Acknowledgements

This work was supported by the grants of the National Natural Science Foundation of China (No.21571091), Liaoning Normal University High-end Scientific Research Achievement Funding Program (No. 21GDL003), and Open Project of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University in China (No. 2020-10).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian City, 116029, People’s Republic of China

    Min Liu, Yu Xin, Yong Heng Xing & Feng Ying Bai

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, People’s Republic of China

    Zhan Shi

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  1. Min Liu
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Contributions

Min Liu, experiment, process data, writing; Yu Xin, reviewing; Yong Heng Xing, reviewing and editing, supervision; Feng Ying Bai, reviewing and editing, supervision; Zhan Shi, software.

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Correspondence to Yong Heng Xing or Feng Ying Bai.

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10904_2022_2229_MOESM1_ESM.docx

The following files are available free of charge CCDC 2114111 and 2115232 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif. Full experimental details are presented in the Supporting Information. (DOCX 434 KB)

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Liu, M., Xin, Y., Xing, Y.H. et al. Construction and Properties of Ag-I Polymeric Clusters Attach with Nitrogen Heterocyclic Transition Metal Moiety. J Inorg Organomet Polym 32, 1695–1711 (2022). https://doi.org/10.1007/s10904-022-02229-9

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