Abstract
The modification of graphene oxide (GO) with octadecylamine was performed to emulsify dimethyl formamide droplets in octane via Pickering mechanism for copolymerization of styrene and n-butyl acrylate monomers. The copolymerization in oil in oil Pickering emulsion was led to obtain appropriate copolymer composition. To confirm the modification, different characterization techniques were applied comprising Fourier-transform infrared spectroscopy (FT-IR), X-ray diffractometer, Atomic force microscopy, dynamic light scattering technique, contact angle and thermal analysis. The successful preparation of Pickering emulsion was followed by imaging and stability observations. The 1HNMR, FT-IR and conversion measurements were applied to identify the composition and chemical structure of the obtained copolymer. The St–BA copolymer film was formed after polymerization in Pickering emulsion by ODA–GO. The conductivity value (0.077*10–6) or the amount of resistance volume (13 MΩ) were gained for copolymer film which depended on the components amounts. These findings will help explore Pickering mechanism along with modification of GO structures and their eventual application in copolymerization of monomer with different polarity nature.
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M. Klapper, S. Nenov, R. Haschick, K. Müller, K. Müllen, Acc. Chem. Res. 41, 1190 (2008). https://doi.org/10.1021/ar8001206
B.P. Binks, A.T. Tyowua, Soft Matter 12, 876 (2016). https://doi.org/10.1039/C5SM02438B
A.M. Tawfeek, A.K.F. Dyab, H.A. Al-Lohedan, J. Dispers. Sci. Technol. 35, 265 (2014). https://doi.org/10.1080/01932691.2013.769110
D. Gonzalez Ortiz, C. Pochat-Bohatier, J. Cambedouzou, M. Bechelany, P. Miele, J. Eng. 6, 468 (2020). https://doi.org/10.1016/j.eng.2019.08.017
B.P. Binks, S.O. Lumsdon, Langmuir 17, 4540 (2001). https://doi.org/10.1021/la0103822
J. Marto, A. Ascenso, S. Simoes, A.J. Almeida, H.M. Ribeiro, Expert Opin. Drug Deliv. 13, 1093 (2016). https://doi.org/10.1080/17425247.2016.1182489
T. Sharma, G.S. Kumar, B.H. Chon, J. Sangwai. Korea. Aust. Rheol. J. 26, 377 (2014). https://doi.org/10.1007/s13367-014-0043-z
H. Wang, E.K. Hobbie, Langmuir 19, 3091 (2003). https://doi.org/10.1021/la026883k
G. Lu, L.E. Ocola, J. Chen, Nanotechnology 20(44), 445502 (2009). https://doi.org/10.1021/nn404889b
J. Pyun, Angew. Chem. Int. Ed. 50(1), 46–48 (2011). https://doi.org/10.1002/anie.201003897
G.Z. Kyzas, E.A. Deliyanni, K.A. Matis, J. Chem. Tech. Biotech. 89(2), 196–205 (2014). https://doi.org/10.1002/jctb.4220
A.M. Elshurafa, M.N. Almadhoun, K.N. Salama, H.N. Alshareef, Appl. Phys. Lett. 102(23), 232901 (2013). https://doi.org/10.1063/1.4809817
P. Xie, X. Ge, B. Fang, Z. Li, Y. Liang, C. Yang, Colloid Polym. Sci. 291(7), 1631–1639 (2013). https://doi.org/10.1007/s00396-013-2897-x
A. Zia, E. Pentzer, S. Thickett, K. Kempe, ACS Appl. Mater. Interfaces 12, 38845 (2020). https://doi.org/10.1021/acsami.0c07993
X. Song, Y. Yang, J. Liu, H. Zhao, Langmuir 27, 1186 (2011). https://doi.org/10.1021/la103856h
P. Wei, E. Pentzer, S. Thickett, K. Kempe, ACS Appl. Mater. Interfaces 10, 21765 (2018). https://doi.org/10.1021/acsami.8b07178
B.T. McGrail, B.J. Rodier, E. Pentzer, Chem. Mater. 26, 5806 (2014). https://doi.org/10.1021/cm5031409
B.J. Rodier, E.P. Mosher, S.T. Burton, R. Matthews, E. Pentzer, Macromol. Rapid Commun. 37, 894 (2016). https://doi.org/10.1002/marc.201600093
B.J. Rodier, A.D. Leon, C. Hemmingsen, E. Pentzer, Polym. Chem. 9, 1547 (2018). https://doi.org/10.1039/C7PY01819C
E.J. Arlman, H.W. Melville, L. Valentine, Recl. Trav. Chim. Pays-Bas. 68, 945 (1949). https://doi.org/10.1002/recl.19490681007
K. Fang, R. Xie, X. Liu, G. Zhao, D. Han, W. Chen, Z. Shi, L. Hao, Y. Cai, Cellulose 26, 5807 (2019). https://doi.org/10.1007/s10570-019-02498-7
L. Francisco-Vieira, R. Benavides, E. Cuara-Diaz, D. Morales-Acosta, Int. J. Hydrogen Energy 44, 12492 (2019). https://doi.org/10.1016/j.ijhydene.2019.01.181
X. Jiang, D. Zou, X. Zhengkong, X. Zhu, Zh. Zhang, J. Polym. Res. 21, 473 (2014). https://doi.org/10.1007/s10965-014-0473-9
H.J. Naghash, A. Karimzadeh, A.R. Massah, J. Appl. Polym. Sci. 112, 1037 (2009). https://doi.org/10.1002/app.29555
G.E.P. Box, W.G. Hunter, J. Stuart-Hunter, Statistics for Experimenters—An Introduction to Design, Data Analysis, and Model Building (Wiley, Hoboken, 1978)
D.A. Dikin, S. Stankovich, E.J. Zimney, R.D. Piner, G.H.B. Dommett, G. Evmenenko, S.T. Nguyen, R.S. Ruoff, Nature 448, 457 (2007). https://doi.org/10.1038/nature06016
S.-P. Zhang, H.-O. Song, New J. Chem. 36, 1733 (2012). https://doi.org/10.1039/C2NJ40214A
R.D. Hazlett, J. Colloid Interface Sci. 137, 527 (1990). https://doi.org/10.1016/0021-9797(90)90425-N
T. Ghosh, P. Bardhan, M. Mandal, N. Karak, Mater. Sci. Eng. C 105, 110055 (2019). https://doi.org/10.1016/j.msec.2019.110055
W. Lee, J.U.K. Lee, B.M. Jung, J.-H. Byun, J.-W. Yi, S.-B. Lee, B.-S. Kim, Carbon 65, 296 (2013). https://doi.org/10.1016/j.carbon.2013.08.029
A.W. Coats, J.P. Redfern, Analyst 88, 906 (1963). https://doi.org/10.1039/AN9638800906
Y. Wu, H. Duan, Y. Yu, Ch. Zhang, J. Appl. Polym. Sci. 79, 333 (2001). https://doi.org/10.1002/1097-4628(20010110)79:2%3c333::AID-APP160%3e3.0.CO;2-8
G. Tang, Z.-G. Jiang, X. Li, H.-B. Zhang, Z.-Z. Yu, Chin. J. Polym. Sci. 32(8), 975–985 (2014). https://doi.org/10.1007/s10118-014-1488-8
G. Bayramoglu, M.Y. Arica, Ind. Eng. Chem. 51, 10629 (2012). https://doi.org/10.1021/ie301105w
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This work was financial supported by University of Kashan and Iran Polymer and Petrochemical Institute which is greatly acknowledged.
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This work was financial supported by University of Kashan and Iran Polymer and Petrochemical Institute.
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Khalaj-Amirhosseini, Z., Ashjari, M., Jamjah, R. et al. Emulsion Based Nanoarchitectonics for Styrene–Butyl Acrylate Copolymerization upon Pickering Mechanism. J Inorg Organomet Polym 32, 864–874 (2022). https://doi.org/10.1007/s10904-022-02224-0
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DOI: https://doi.org/10.1007/s10904-022-02224-0