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Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties

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Abstract

A series of zinc coordination polymers, {Zn2X2(BDC)(L)}n (X = Cl (1 and 3) or Br (2 and 4), BDC = 1,4-benzenedicarboxylate, L = 4,4′-bipyridine (1 and 2) or 1,4-diazabicyclo[2.2.2]octane (3 and 4)), have been synthesized by ionothermal reactions and characterized by X-ray crystallography and powder X-ray diffraction (PXRD). Compounds 1, 2 and 4 were also characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and their chemical stability towards various organic solvents were investigated. Compound 1 displays strong luminescence in the solid state and high luminescent selectivity and sensitivity for Fe3+ ions and nitroaromatics (NACs) in ethanol solutions, rendering it a potential fluorescence probe for these substrates. In addition, investigation on organic dye adsorptions shows that, among these coordination polymers, only complex 4 can selectively adsorb Congo red dye from other dye molecules. This demonstrates that the function of these coordination polymers can be regulated through subtle modification of their components.

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Acknowledgements

This work was supported by Pearl River S&T Nova Program of Guangzhou (No. 201610010118), Natural Science Foundation of Guangdong Province (No. 2018A0303130021), the National Natural Science Foundation of China (No. 21301070), the Fundamental Research Funds for the Central Universities (No. 21615401), and Jinan University.

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  1. Department of Chemistry, College of Chemistry and Materials Science, Jinan University, Guangzhou, 510632, China

    Zhicai Mai, Xiaojun Luo & Hao Lei

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  1. Zhicai Mai
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  2. Xiaojun Luo
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  3. Hao Lei
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Correspondence to Hao Lei.

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Mai, Z., Luo, X. & Lei, H. Ionothermal Synthesis of Zn(II) Coordination Polymers with Fluorescent Sensing and Selective Dye Adsorption Properties. J Inorg Organomet Polym 29, 1746–1754 (2019). https://doi.org/10.1007/s10904-019-01136-w

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