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A 2D Co(II) Coordination Polymer Containing Tri-flexural Helical Chains from Achiral Materials

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Abstract

A 2D cobalt(II) chiral coordination polymer (CP), namely [Co(bimb)(tbip)]n (1) (bimb = 4,4′-bis(imidazol-1-ylmethyl)biphenyl and H2tbip = 5-tert-butylisophthalic acid) containing tri-flexural helix structures has been hydrothermally synthesized and structurally characterized. CP 1 features a 2D (4,4) layer, which is further extended into a 3D supramolecular framework through weak hydrogen bonding interactions. Intermolecular interactions in the crystal framework have been analyzed by Hirshfeld surface and fingerprint plots in detail. The thermogravimetric analyses (TGA), luminescence, and electrochemical properties of CP 1 have been investigated. Furthermore, CP 1 exhibits promising photocatalytic activities for the degradation of methylene blue (MB) under UV irradiation with the degradation efficiency is up to 96.7%.

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Acknowledgements

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation–Steel and Iron Foundation of Hebei Province (B2015209299).

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Authors and Affiliations

  1. Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, College of Chemical Engineering, North China University of Science and Technology, Tangshan, 063009, Hebei, People’s Republic of China

    Hai Ning Chang, Yue Hua Li, Zeng Chuan Hao & Guang Hua Cui

Authors
  1. Hai Ning Chang
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  2. Yue Hua Li
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  3. Zeng Chuan Hao
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  4. Guang Hua Cui
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Corresponding author

Correspondence to Guang Hua Cui.

Electronic supplementary material

CCDC 1540178 contains the supplementary crystallographic data for CP 1. The data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk

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Supplementary material 2 (DOC 415 KB)

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Chang, H.N., Li, Y.H., Hao, Z.C. et al. A 2D Co(II) Coordination Polymer Containing Tri-flexural Helical Chains from Achiral Materials. J Inorg Organomet Polym 27, 1190–1198 (2017). https://doi.org/10.1007/s10904-017-0566-0

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  • DOI: https://doi.org/10.1007/s10904-017-0566-0

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