Skip to main content
SpringerLink
Log in

Direct Synthesis of Lead and Lead Chloride Nanoparticles via Simple One-Pot Calcination of One-Dimensional Lead(II) Coordination Polymer

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A new lead(II) one-dimensional coordination polymer, {[Pb2(μ2-Cl-8-Hq)(μ3-Cl-8-Hq)(NO3)2(H2O)0.5(CH3OH)0.5](Cl-8-HqH)0.5}n (1) [Cl-8-HqH = (5-chloro-8-hydroxyquinoline], has been synthesized and characterized. The single-crystal X-ray data of compound 1 shows that it has two types of PbII ions with stereo-chemically active lone electron pair. Mixture of Pb and PbCl2 nanoparticles, with regular morphology, was prepared from simple one-pot calcination of 1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. A.U. Czaja, N. Trukhan, U. Muller, Chem. Soc. Rev. 38, 1284 (2009)

    Article  CAS  Google Scholar 

  2. X. Zhang, W. Wang, Z. Hu, G. Wang, K. Uvdal, Coord. Chem. Rev. 284, 206 (2015)

    Article  CAS  Google Scholar 

  3. J.R. Li, R.J. Kuppler, H.C. Zhou, Chem. Soc. Rev. 38, 1477 (2009)

    Article  CAS  Google Scholar 

  4. J.-P. Zhang, P.-Q. Liao, H.-L. Zhou, R.-B. Lin, X.-M. Chen, Chem. Soc. Rev. 43, 5789 (2014)

    Article  CAS  Google Scholar 

  5. K. Akhbari, A. Morsali, Dalton Trans. 42, 4786 (2013)

    Article  CAS  Google Scholar 

  6. K. Akhbari, A. Morsali, Inorg. Chem. Commun. 10, 1189 (2007)

    Article  CAS  Google Scholar 

  7. K. Akhbari, A. Morsali, J. Organomet. Chem. 692, 5141 (2007)

    Article  CAS  Google Scholar 

  8. Q. Hua, Y. Zhao, G.C. Xu, M.S. Chen, Z. Su, K. Cai, W.Y. Sun, Cryst. Growth Des. 10, 2553 (2010)

    Article  CAS  Google Scholar 

  9. K. Akhbari, A. Morsali, Polyhedron 30, 1456 (2011)

    Article  CAS  Google Scholar 

  10. K. Akhbari, A. Morsali, Inorg. Chim. Acta 362, 1692 (2009)

    Article  CAS  Google Scholar 

  11. K. Akhbari, A. Morsali, Coord. Chem. Rev. 254, 1977 (2010)

    Article  CAS  Google Scholar 

  12. R.L. Davidovicha, V. Stavila, D.V. Marinin, E.I. Voit, K.H. Whitmire, Coord. Chem. Rev. 253, 1316 (2009)

    Article  Google Scholar 

  13. Q.Y. Liu, L. Xu, Eur. J. Inorg. Chem. 8, 1620 (2006)

    Article  Google Scholar 

  14. D. Hazari, S.K. Jana, M. Fleck, E. Zangrando, S. Dalai, J. Solid State Chem. 219, 43 (2014)

    Article  CAS  Google Scholar 

  15. Q. Y. Liu, L. Xu, Eur. J. Inorg. Chem. 2006, 1621 (2006)

  16. J. Yang, J.F. Ma, Y.Y. Liu, J.C. Ma, S.R. Batten, Inorg. Chem. 46, 6545 (2007)

    Google Scholar 

  17. R. Ferreiros-Martinez, D. Esteban-Gomez, E. Toth, A. de Blas, C. Platas-Iglesias, T. Rodriguez-Bals, Inorg. Chem. 50, 3772 (2011)

    Article  CAS  Google Scholar 

  18. R.J. Andersen, R.C. Targiani, R.D. Hancock, C.L. Stern, D.P. Goldberg, H.A. Godwin, Inorg. Chem. 45, 6574 (2006)

    Article  CAS  Google Scholar 

  19. M.Y. Masoomi, A. Morsali, Coord. Chem. Rev. 256, 2921 (2012)

    Article  CAS  Google Scholar 

  20. K. Akhbari, A. Morsali, CrystEngComm 363, 1435 (2010)

    CAS  Google Scholar 

  21. K. Akhbari, A. Morsali, P. Retailleau, Polyhedron 29, 3304 (2010)

    Article  CAS  Google Scholar 

  22. F.Z. Karizi, V. Safarifard, S.K. Khani, A. Morsali, Ultrason. Sonochem. 23, 238 (2015)

    Article  CAS  Google Scholar 

  23. J. Hyuk Im, E. Kang, S.J. Yang, H.J. Park, J. Kim, ChR Park, Bull. Korean Chem. Soc. 35, 2477 (2014)

    Article  Google Scholar 

  24. B. Liu, X. Zhang, H. Shioyama, T. Mukai, T. Sakai, Q. Xu, J. Power Sour. 195, 857 (2010)

    Article  CAS  Google Scholar 

  25. K. Akhbari, A. Morsali, CrystEngComm 13, 2047 (2011)

    Article  CAS  Google Scholar 

  26. K. Akhbari, S. Beheshti, A. Morsali, V.T. Yilmaz, O. Büyükgüngör, J. Mol. Struct. 1074, 279 (2014)

    Article  CAS  Google Scholar 

  27. K. Akhbari, A. Morsali, CrystEngComm 15, 8915 (2013)

    Article  CAS  Google Scholar 

  28. G.M. Sheldrick, SHELXS-97 and SHELXL-97 (Göttingen University, Germany, 1997)

    Google Scholar 

  29. C.F. Macrae, P.R. Edgington, P. McCabe, E. Pidcock, G.P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Cryst. 39, 453 (2006)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to acknowledge the financial support of University of Tehran for this research under Grant Number 01/1/389845 and supporting of this investigation by Tarbiat Modares University.

Author information

Authors and Affiliations

  1. School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Islamic Republic of Iran

    Kamran Akhbari

  2. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-4838, Tehran, Islamic Republic of Iran

    Ali Morsali

Authors
  1. Kamran Akhbari
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ali Morsali
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Kamran Akhbari or Ali Morsali.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 105 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Akhbari, K., Morsali, A. Direct Synthesis of Lead and Lead Chloride Nanoparticles via Simple One-Pot Calcination of One-Dimensional Lead(II) Coordination Polymer. J Inorg Organomet Polym 25, 930–935 (2015). https://doi.org/10.1007/s10904-015-0192-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-015-0192-7

Keywords

Search

Navigation