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Synthesis and characterization of new coordination polymer with l-proline amino acid ligand; new precursor for preparation of pure phase lead(II) oxide nanoparticles via thermal decomposition

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Abstract

A new two-dimensional lead(II) coordination polymer, [Pb(Pro)2] n (1); Pro = l-proline amino acid, has been synthesized and characterized by IR and X-ray diffraction. Structural determination of compound 1 reveals the Pb(II) ion is four-coordinated, bonded to two nitrogen atoms and two oxygen atoms from the l-proline ligand. PbO nanoparticles were synthesized by calcination of compound 1 at 500, 550 and 600 °C under air atmosphere. The PbO nanostructure was characterized by scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). The thermal stability of compound 1 was studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA). Increase in calcination temperature decreased particles size and also led to layer-shape nanostructures morphology.

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Acknowledgements

Support of this investigation by Payame Noor University, Mazandaran Gas Company and Tarbiat Modares University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, Abhar, Zanjan, Islamic Republic of Iran

    Soghra Varzdar

  2. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Islamic Republic of Iran

    Lida Hashemi & Ali Morsali

  3. Institute of Physics ASCR, Cukrovarnicka 10, 162 00, Prague, Czechia

    Michal Dusek

Authors
  1. Soghra Varzdar
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  2. Lida Hashemi
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  3. Ali Morsali
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  4. Michal Dusek
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Correspondence to Ali Morsali.

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Varzdar, S., Hashemi, L., Morsali, A. et al. Synthesis and characterization of new coordination polymer with l-proline amino acid ligand; new precursor for preparation of pure phase lead(II) oxide nanoparticles via thermal decomposition. J IRAN CHEM SOC 14, 2255–2261 (2017). https://doi.org/10.1007/s13738-017-1162-5

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  • DOI: https://doi.org/10.1007/s13738-017-1162-5

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