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Hemidirected Coordination Sphere on Novel Lead(II) Nano Coordination Polymer: Synthesis, Structural Characterization and DFT Calculation of [Pb(p-2-einh)ClO4(MeOH)2]n

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Abstract

The novel nano lead(II) 1D zigzag coordination polymer [Pb(p-2-einh)ClO4(MeOH)2]n (1) (p-p-2-einh = (1-(pyridin-2-yl)ethylidene)isonicotinohydrazide) was synthesized by a sonochemical method. The new nanostructure was characterized by using scanning electron microscopy (SEM) and high-resolution transmission electron microscopy, X-ray powder diffraction and elemental analysis. The single-crystal X-ray analysis reveals a one dimensional zigzag coordination polymer structure for 1, that is further extended into a three-dimensional (3-D) supramolecular structure by π–π and other labile intermolecular interactions. The coordination number of the lead(II) ions is six, PbN3O3. The PbO nanoparticles were obtained by the thermolysis of 1 at 180 °C in presence of oleic acid as a surfactant. The Scherrer equation estimated the average diameter of the nanoparticles to be 15 nm. The morphology and size of the prepared PbO samples were further observed using SEM. The structure of the title complex has been optimized by density functional theory calculations. Calculated structural parameters and IR spectra for the title complex are consistent with the crystal structure.

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Notes

  1. A description of the basis sets and theory level used in this work can be found in the following Ref. [48]

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Acknowledgments

Support of this investigation by Yasuj University and Iran National Science Foundation is gratefully acknowledged. Moreover, the authors wish to thank to the Yeungnam University-Korea for their valuable assistance in accomplishing this study.

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Authors and Affiliations

  1. Department of Civil Engineering, Yeungnam University, Gyungsan, 712-749, South Korea

    Alireza Valipour

  2. Department of Chemistry, Yasouj University, Yasouj, 75918-74831, Islamic Republic of Iran

    Babak Mirtamizdoust & Mehrorang Ghaedi

  3. Department of Physics, Yasouj University, Yasouj, 75918-74831, Islamic Republic of Iran

    Fardin Taghizadeh

  4. School of Chemical Engineering, University of Adelaide, Adelaide, SA, 5005, Australia

    Pejman Talemi

  5. Department of Chemistry, Faculty of Science, University of Qom, PO Box 37185-359, Qom, Islamic Republic of Iran

    Babak Mirtamizdoust

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  1. Alireza Valipour
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Correspondence to Alireza Valipour or Babak Mirtamizdoust.

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Valipour, A., Mirtamizdoust, B., Ghaedi, M. et al. Hemidirected Coordination Sphere on Novel Lead(II) Nano Coordination Polymer: Synthesis, Structural Characterization and DFT Calculation of [Pb(p-2-einh)ClO4(MeOH)2]n . J Inorg Organomet Polym 26, 197–207 (2016). https://doi.org/10.1007/s10904-015-0286-2

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