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Hydrothermal Synthesis, Crystal Structure and Spectroscopic Characterization of a Novel 2D → 3D Parallel Polycatenated Coordination Framework [Cd(cmb)(bix)] n

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Abstract

A novel entangled coordination polymer [Cd(cmb)(bix)] n (1) [H2cmb = 2,2′-(2-(carboxymethoxy)benzoic acid), bix = 1,4-bis(imidazol-1-ylmethyl)benzene], has been synthesized by hydrothermal reaction of Cd(Ac)2·2H2O, bix and H2cmb, and characterized by elemental analysis, IR spectra, PXRD, and single-crystal X-ray diffraction. The structure determination reveals that the complex 1 shows a new 2D → 3D parallel polycatenation framework based on highly undulating 2D 44 -sql layers, in which each layer is polycatenated with adjacent two others (one above and one below, DOC = 4) which have parallel but not coincident mean planes. Moreover, the thermal stability and photoluminescence property of 1 were also discussed.

Graphical Abstract

A novel 2D → 3D parallel polycatenated coordination polymer [Cd(cmb)(bix)] n (1), based on highly undulating 2D 44 -sql layers, has been hydrothermally synthesized and characterized. Moreover, the thermal stability and photoluminescence property of 1 were also investigated.

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Acknowledgments

This work was financially supported by the NSF of China (Nos. 21073106, 21201109 and 21373122), the NSF of Hubei Provinces of China (2011CDA118).

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Authors and Affiliations

  1. College of Mechanical & Material Engineering, Research Institute of Materials, China Three Gorges University, Yichang, 443002, China

    Liang Bai, Dong-Sheng Li, Jing-Jing Yang, Ya-Ping Duan, Jun Zhao & Ya-Pan Wu

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  1. Liang Bai
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  2. Dong-Sheng Li
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  3. Jing-Jing Yang
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  5. Jun Zhao
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Correspondence to Dong-Sheng Li.

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Bai, L., Li, DS., Yang, JJ. et al. Hydrothermal Synthesis, Crystal Structure and Spectroscopic Characterization of a Novel 2D → 3D Parallel Polycatenated Coordination Framework [Cd(cmb)(bix)] n . J Inorg Organomet Polym 23, 1341–1346 (2013). https://doi.org/10.1007/s10904-013-9933-7

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  • DOI: https://doi.org/10.1007/s10904-013-9933-7

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