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Growth of Pt Subnano Clusters on Limited Surface Areas of Prussian Blue Nanoparticles

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Abstract

We synthesized insoluble Prussian blue nanoparticles (PB NPs) and water-soluble PB NPs ([Fe(CN)6]4−-modified PB NPs) as synthetic fields and carriers of Pt subnano clusters. Pt2+ can attach on their surface Fe–CN sites. The amount of the attached Pt2+ on the insoluble and water-soluble PB NP surfaces was saturated to reach Pt/Fe = 15 and 40 mol%, respectively, based on the total metal ions of PB. The results showed that the attachment amount of Pt2+ on the surface CN sites was controlled by the surface modification. From results of TEM and STEM-HADDF-EDS, Pt subnano clusters (1.4 nm) were observed on water-soluble PB NPs after the reduction using hydrazine.

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References

  1. A. Kraft, Bull. Hist. Chem. 33, 61 (2008)

    CAS  Google Scholar 

  2. A. Omura, H. Shiozaki, S. Hara, T. Kawamoto, A. Gotoh, M. Kurihara, M. Sakamoto, H. Tanaka, IEICE Trans. Electron. E91-C, 1887 (2008)

    Article  Google Scholar 

  3. S. Hara, H. Shiozaki, A. Omura, H. Tanaka, T. Kawamoto, M. Tokumoto, M. Yamada, A. Gotoh, M. Kurihara, M. Sakamoto, Appl. Phys. Express 1, 104002 (2008)

    Article  Google Scholar 

  4. H. Shiozaki, T. Kawamoto, H. Tanaka, S. Hara, M. Tokumoto, A. Gotoh, T. Satoh, M. Ishizaki, M. Kurihara, M. Sakamoto, Jpn. J. Appl. Phys. 47, 1242 (2008)

    Article  CAS  Google Scholar 

  5. S. Hara, H. Tanaka, T. Kawamoto, M. Tokumoto, M. Yamada, A. Gotoh, H. Uchida, M. Kurihara, M. Sakamoto, Jpn. J. Appl. Phys. 46, L945 (2007)

    Article  CAS  Google Scholar 

  6. D.M. DeLongchamp, P.T. Hammond, Adv. Funct. Mater. 14, 224 (2004)

    Article  CAS  Google Scholar 

  7. M. Ishizaki, M. Sakamoto, H. Tanaka, T. Kawamoto, M. Kurihara, Mol. Cryst. Liq. Cryst. 539, 18 (2011)

    Article  CAS  Google Scholar 

  8. K. Itaya, N. Shoji, I. Uchida, J. Am. Chem. Soc. 106, 3423 (1984)

    Article  CAS  Google Scholar 

  9. Y. Zhang, X. Sun, L. Zhu, H. Shen, N. Jia, Electrochim. Acta 56, 1239 (2011)

    Article  CAS  Google Scholar 

  10. A. Eftekhari, J. Power Sources 132, 291 (2004)

    Article  CAS  Google Scholar 

  11. M. Yang, J. Jiang, Y. Yang, X. Chen, G. Shen, R. Yu, Biosens. Bioelectron. 21, 1791 (2006)

    Article  CAS  Google Scholar 

  12. M. Yang, J. Jiang, Y. Lu, Y. He, G. Shen, R. Yu, Biomaterials 28, 3408 (2007)

    Article  CAS  Google Scholar 

  13. O. Sato, S. Hayami, Y. Einaga, Z.Z. Gu, Bull. Chem. Soc. Jpn. 76, 443 (2003)

    Article  CAS  Google Scholar 

  14. T. Yamauchi, A. Nakamura, Y. Moritomo, T. Hozumi, K. Hashimoto, S. Ohkoshi, Phys. Review B 72, 214425 (2005)

    Article  Google Scholar 

  15. D.M. Pajerowski, F.A. Frye, D.R. Talham, M.W. Meisel, New J. Phys. 9, 222 (2007)

    Article  Google Scholar 

  16. S.S. Kaye, J.R. Long, J. Am. Chem. Soc. 127, 6506 (2005)

    Article  CAS  Google Scholar 

  17. K.W. Chapman, P.D. Southon, C.L. Weeks, C.J. Kepert, Chem. Commun. 26, 3322 (2005)

    Article  Google Scholar 

  18. A. Gotoh, H. Uchida, M. Ishizaki, T. Satoh, S. Kaga, S. Okamoto, M. Ohta, M. Sakamoto, T. Kawamoto, H. Tanaka, M. Tokumoto, S. Hara, H. Shiozaki, M. Yamada, M. Miyake, M. Kurihara, Nanotechnology 18, 345609 (2007)

    Article  Google Scholar 

  19. M. Ishizaki, A. Gotoh, M. Makiko, M. Sakamoto, H. Tanaka, T. Kawamoto, M. Kurihara, Chem. Lett. 39, 762 (2010)

    Article  CAS  Google Scholar 

  20. M. Ishizaki, K. Kanaizuka, M. Abe, Y. Hoshi, M. Sakamoto, T. Kawamoto, H. Tanaka, M. Kurihara, Green Chem. 14, 1537 (2012)

    Article  CAS  Google Scholar 

  21. M. Ishizaki, Y. Sajima, S. Tsuruta, A. Gotoh, M. Sakamoto, T. Kawamoto, H. Tanaka, M. Kurihara, Chem. Lett. 2009, 38 (1058)

    Google Scholar 

  22. J. de Graaf, A.J. van Dillen, K.P. de Jong, D.C. Koningsberger, J. Catal. 203, 307–321 (2001)

    Article  Google Scholar 

  23. R. Narayanan, M.A. El-Sayed, Nano Lett. 4, 1343 (2004)

    Article  CAS  Google Scholar 

  24. C. Wang, H. Daimon, T. Onodera, T. Koda, S. Sun, Angew. Chem. Int. Ed. 47, 3588 (2008)

    Article  CAS  Google Scholar 

  25. M.A. Mahmoud, M.A. El-Sayed, J. Phys. Chem. C 111, 17180 (2007)

    Article  CAS  Google Scholar 

  26. Y. Borodko, P. Ercius, V. Pushkarev, C. Thompson, G. Somorjai, J. Phys. Chem. Lett. 3, 236–241 (2012)

    Article  CAS  Google Scholar 

  27. Y. Miao, J. Chen, X. Wu, J. Miao, Colloids Surf. A Physicochem. Eng. Asp. 295, 135 (2007)

    Article  CAS  Google Scholar 

  28. N. Yan, C. Xiao, Y. Kou, Coord. Chem. Rev. 254, 1179 (2010)

    Article  CAS  Google Scholar 

  29. J. Chen, B. Lim, E.P. Lee, Y. Xia, Nano Today 4, 81 (2009)

    Article  Google Scholar 

  30. H. Liu, C. Song, L. Zhang, H. Wang, D.P. Wilkinson, J. Power Sources 155, 95 (2006)

    Article  CAS  Google Scholar 

  31. J. Zhang, J. Li, F. Yang, B. Zhang, X. Yang, Sens. Actuators B 143, 373 (2009)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Sasakawa Scientific Research Grant from The Japan Science Society, a Grant-in-Aid for Scientific Research (C) (No. 24550069) of the Japan Society for the Promotion of Science (JSPS).

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Authors and Affiliations

  1. Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata, 990-8560, Japan

    Manabu Ishizaki, Shoko Tsuruta, Katsuhiko Kanaizuka, Masatomi Sakamoto & Masato Kurihara

  2. Nanosystem RI, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba, 305-8565, Japan

    Masatomi Sakamoto, Tohru Kawamoto, Hisashi Tanaka & Masato Kurihara

Authors
  1. Manabu Ishizaki
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  2. Shoko Tsuruta
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  3. Katsuhiko Kanaizuka
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  4. Masatomi Sakamoto
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  5. Tohru Kawamoto
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  6. Hisashi Tanaka
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  7. Masato Kurihara
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Correspondence to Masato Kurihara.

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Ishizaki, M., Tsuruta, S., Kanaizuka, K. et al. Growth of Pt Subnano Clusters on Limited Surface Areas of Prussian Blue Nanoparticles. J Inorg Organomet Polym 23, 216–222 (2013). https://doi.org/10.1007/s10904-012-9721-9

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  • DOI: https://doi.org/10.1007/s10904-012-9721-9

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