Skip to main content
Log in

Influence of size effects on chemical reactions inside a nanoparticle and on its surface

  • Published:
Journal of Engineering Physics and Thermophysics Aims and scope

The influence of size effects on the course of chemical reactions both inside a nanosized particle and on its surface has been investigated theoretically.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. C. Vanithakumari and K. K. Nanda, A universal relation for the cohesive energy of nanoparticles, Phys. Lett. A, 372, No. 46, 6930–6934 (2008).

    Article  MATH  Google Scholar 

  2. W. H. Qi and M. P. Wang, Size and shape dependent melting temperature of metallic nanoparticles, Mater. Chem. Phys., 88, 280–284 (2004).

    Article  Google Scholar 

  3. V. V. Levdansky, J. Smolik, and P. Moravec, Size effects in physicochemical transformations in aerosol systems with nanoparticles, Int. Commun. Heat Mass Transf., 37, No. 1, 593–595 (2010).

    Article  Google Scholar 

  4. M. S. Yaghmaee, B. Shokri, and M. R. Rahimipour, Size dependence surface activity of metallic nanoparticles, Plasma Process. Polym., 6, S876–S882 (2009).

    Article  Google Scholar 

  5. J. Keizer, Diffusion effects on rapid bimolecular chemical reaction, Chem. Rev., 87, No. 1, 167–180 (1987).

    Article  Google Scholar 

  6. H. M. Lu and X. K. Meng, Theoretical model to calculate catalytic activation energies of platinum nanoparticles of different sizes and shapes, J. Phys. Chem. C, 114, 1534–1538 (2010).

    Article  Google Scholar 

  7. S. Sh. Rekhviashvili and E. V. Kishtikova, Concerning the melting temperature of nanoparticles and nanostructured substances, Pis’ma Zh. Tekh. Fiz., 32, Issue 10, 50–55 (2006).

    Google Scholar 

  8. R. C. Tolman, The effect of droplet size on surface tension, J. Chem. Phys., 17, No. 3, 333–337 (1949).

    Article  Google Scholar 

  9. K. A. Connors, Chemical Kinetics. The Study of Reaction Rates in Solution, VCH Publishers, Inc., New York (1990).

  10. V. V. Levdanskii, J. Smolik, and P. Moravec, Chemical reactions in nanoparticles, Inzh.-Fiz. Zh., 83, No. 2, 376–380 (2010).

    Google Scholar 

  11. J. N. Crowley, M. Ammann, R. A. Cox, et al., Evaluated kinetic and photochemical data for atmospheric chemistry, Vol. V, Heterogeneous reactions on solid substrates, Atmos. Chem. Phys., 10, 9059–9223 (2010).

    Google Scholar 

  12. D. Yu. Murzin, Thermodynamic analysis of nanoparticle size effect on catalytic kinetics, Chem. Eng. Sci., 64, 1046–1052 (2009).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Levdanskii.

Additional information

Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 86, No. 4, pp. 807–811, July–August, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Levdanskii, V.V., Smolik, J., Zdimal, V. et al. Influence of size effects on chemical reactions inside a nanoparticle and on its surface. J Eng Phys Thermophy 86, 863–867 (2013). https://doi.org/10.1007/s10891-013-0905-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10891-013-0905-0

Keywords

Navigation