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Sequential Synthesis of 3d–3d Heterometallic Complexes Based on Lacunary Molybdovanadate with Magnetic Properties and Electrocatalytic Activities for Ascorbic Acid

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Abstract

Two new molybdovanadate-based heterometallic complexes, (NH4)15[Na(H2O)3]2[Co(H2O)4]2[Cu8(OH)2(H2O)2(V9Mo30O130)]·30H2O (1), (NH4)15[Na(H2O)3]2[Mn(H2O)4]2[Cu8(OH)2(H2O)2(V9Mo30O130)]·36H2O (2) have been synthesized from the reaction of the {V10Mo30Cu8} precursor and transition-metal ions (Mn2+ and Co2+) in aqueous solution. Compounds 1 and 2 are isostructural and exhibit the 1D all-inorganic framework constructed from the Z-shaped {V9Mo30Cu8} anions linked with Co2+ or Mn2+ ions, which is first observed in molybdovanadate system. Magnetic investigations of 1 and 2 indicate the occurrence of strong antiferromagnetic interactions within transition-metal ions. Electrocatalytic experiments demonstrate that 1- and 2-CPEs exhibit good electrocatalytic activities towards the oxidation of ascorbic acid.

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Acknowledgements

The authors are thankful for the financial support from the Thirteen Five-Year Science and Technology Research Project of the Education Department of Jilin Province (Grant No. JJKH20181234KJ).

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Authors and Affiliations

  1. School of Pharmaceutical Sciences, Changchun University of Chinese Medicine, Changchun, 130117, People’s Republic of China

    Qiao Gao, Ji-Yu Gong, Dong-Hua Hu & Jing Yang

  2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Lin Xu

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  1. Qiao Gao
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  2. Lin Xu
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Correspondence to Qiao Gao.

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Gao, Q., Xu, L., Gong, JY. et al. Sequential Synthesis of 3d–3d Heterometallic Complexes Based on Lacunary Molybdovanadate with Magnetic Properties and Electrocatalytic Activities for Ascorbic Acid. J Clust Sci 30, 1131–1137 (2019). https://doi.org/10.1007/s10876-019-01576-x

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  • DOI: https://doi.org/10.1007/s10876-019-01576-x

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