Abstract
A new organic–inorganic hybrid, [NH4]10[Cu(im)2]2[Cu4(AsIIIMo10V4O47)2]·20H2O (1) has been synthesized and structurally characterized. Compound 1 exhibits the 2D layered framework constructed from the sandwich-type [Cu4(\({\text{As}}^{{\text{III}}} {\text{Mo}}^{{\text{VI}}}_{10} {\text{V}}^{{\text{V}}}_{4} {\text{O}}_{47}\))2]14− fragments linked alternately with [Cu(im)2]2+ units, which represents the first 2D organic–inorganic hybrid containing tetra-CuII substituted sandwich-type Mo/V-arsenite-based heteropolymolybdate. Interesting, the magnetic measurement of 1 indicates the presence of ferromagnetic interactions among the {Cu4O16} cluster. In addition, the functional application of 1 in electrochemical sensing of ascorbic acid is also investigated in details.
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Acknowledgements
This work was supported by the Thirteen Five-Year Science and Technology Research Project of the Education Department of Jilin Province (Grant Number JJKH20181234KJ).
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Gao, Q., Hu, DH., Duan, MH. et al. A Novel 2D Organic–Inorganic Hybrid Based on Tetra-CuII Substituted Sandwich-Type Mo/V-Arsenite-Based Heteropolymolybdate with Magnetic Property and Electrochemical Sensing of Ascorbic Acid. J Clust Sci 30, 727–733 (2019). https://doi.org/10.1007/s10876-019-01531-w
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DOI: https://doi.org/10.1007/s10876-019-01531-w