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Interaction of [Mo6Cl14]2− with H2Se: Selective Preparation of [Mo6SeCl13]3−

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Abstract

Reaction of [Mo6(μ3-Cl)8Cl6]2− with H2Se, generated in situ from ZnSe and 4 M HCl under hydrothermal conditions lead to the substitution of one or two bridging chlorides, depending on the reagents ratio. With the Mo6/ZnSe 1:3 molar ratio [Mo6(μ3-SeCl7)Cl6]3− forms selectively in high yield. Further substitution is more hindered, and even at 1:20 cluster-to-selenide molar ratio a mixture of [Mo6(μ3-SeCl7)Cl6]3− and [Mo6(μ3-Se2Cl6)Cl6]4− is formed. The products were characterized by X-ray, Raman spectra and electrospray ionization mass spectrometry.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Prospekt Lavrentyeva 3, Novosibirsk, 630090, Russia

    Pavel A. Abramov, Maxim N. Sokolov, Alexandr V. Virovets, Eugenia V. Peresypkina & Vladimir P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia

    Pavel A. Abramov, Maxim N. Sokolov & Vladimir P. Fedin

  3. Universitat Jaume I, Campus de Riu Sec, 12071, Castello, Spain

    Cristian Vicent

Authors
  1. Pavel A. Abramov
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  2. Maxim N. Sokolov
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  3. Alexandr V. Virovets
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  4. Eugenia V. Peresypkina
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  5. Cristian Vicent
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  6. Vladimir P. Fedin
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Correspondence to Maxim N. Sokolov.

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Abramov, P.A., Sokolov, M.N., Virovets, A.V. et al. Interaction of [Mo6Cl14]2− with H2Se: Selective Preparation of [Mo6SeCl13]3− . J Clust Sci 20, 83–92 (2009). https://doi.org/10.1007/s10876-008-0203-8

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  • DOI: https://doi.org/10.1007/s10876-008-0203-8

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