Abstract
The reaction of (Bu4N)2[М6I14] with silver p-toluenesulfonate (tosylate) AgO3SC6H4CH3 affords iodide cluster complexes (Bu4N)2[М6I8(Рts)6] (М = Mo (I), W (II); Рts is tosylate anion CH3C6H4SO3). According to the X-ray diffraction data (СIF file CCDC no. 1027969), the molybdenum atoms in (Bu4N)2[Мo6I8(Рts)6] · 2Et2O · 2MeCN (I′) are coordinated via the monodentate mode by the tosylate ligands. The 1H NMR and mass spectrometry data show that in donor solvents the complexes undergo solvolysis followed by the substitution of the tosylate ligands by the solvent molecules, which is accompanied by changes in the electrochemical properties, as shown by the cyclic voltammetry data.
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Prokopuk, N. and Shriver, D.F., Adv. Inorg. Chem., 1999, vol. 46, p. 1.
Maverick, A.V. and Gray, H.B., J. Am. Chem. Soc., 1981, vol. 103, p. 1298.
Sokolov, M.N., Mihailov, M.A., Peresypkina, E.V., et al., Dalton Trans., 2011, vol. 40, p. 6375.
Sokolov, M.N., Mikhailov, M.A., and Brylev, K.A., et al., Inorg. Chem., 2013, vol. 52, p. 12477.
Sokolov, M.N., Mikhailov, M.A., Virovets, A.V., et al., Russ. Chem. Bull., 2013, vol. 62, p. 1764.
Elistratova, J., Mikhailov, M., Burilov, V., et al., RSC Advances, 2014, vol. 53, p. 27922.
Cordier, S., Kirakci, K., Merry, D., et al., Inorg. Chim. Acta, 2006, vol. 359, p. 1705.
Efremova, O.A., Shestopalov, M.A., Chirtsova, N.A., et al., Dalton Trans., 2014, vol. 43, p. 6021.
Kirakci, K., Fejfarova, K., Kucerakova, M., and Lang, K., Eur. J. Inorg. Chem., 2014, p. 2331.
Kirakci, K., Kubat, P., Dusek, M., et al., Eur. J. Inorg. Chem., 2012, p. 3107.
Ramirez-Tagle, R. and Arratia-Perez, R., Chem. Phys. Lett., 2008, vol. 460, p. 438.
Ramirez-Tagle, R. and Arratia-Perez, R., Chem. Phys. Lett., 2008, vol. 455, p. 38.
Mussel, R.D. and Nocera, D.G., Inorg. Chem., 1990, vol. 29, p. 3711.
Franolic, J.D., Long, J., and Holm, R.H., Inorg. Chem., 1995, vol. 117, p. 8139.
Johnston, D.H., Gaswick, D.C., Lonergan, M.C., et al., Inorg. Chem., 1992, vol. 31, p. 1869.
Sokolov, M.N., Mikhailov, M.A., Abramov, P.A., and Fedin, V.P., J. Struct. Chem., 2012, vol. 53, no. 1, p. 197.
Weinert, C.S., Stern, C.L., and Shriver, D.F., Inorg. Chem., 2000, vol. 39, p. 240.
Weinert, C.S., Stern, C.L., and Shriver, D.F., Inorg. Chim. Acta, 2000, vol. 307, p. 139.
Weinert, C.S., Prokopuk, N., Arendt, S.M., et al., Inorg. Chem., 2001, vol. 40, p. 5162.
Efremova, O.A., Brylev, K.A., Vorotnikov, Y.A., et al., J. Met. Chem. C, 1916, vol. 4, p. 497.
Kirakci, K., Cordier, S., and Perrin, C., Z. Anorg. Allg. Chem., 2005, vol. 631, p. 411.
Hogue, R.D. and McCarley, R.E., Inorg. Chem., 1970, vol. 9, no. 6, p. 1354.
Smith, G., Lynch, D.E., and Kennard, C.H.L., Inorg. Chem., 1996, vol. 35, p. 2711.
Sheldrick, G.M., SADABAS. Program for Empirical X-ray Absorption Correction, Bruker AXS, 1990-2007.
Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.
Blatov, V.A., Shevchenko, A.P., and Proserpio, D.M., Cryst. Growth Des., 2014, vol. 14, p. 3576.
Allen, F.H., Acta Crystallogr., Sect. B: Struct. Sci., 2002, vol. 58, p. 380.
Fry, A. and Britton, W.E., Laboratory Techniques in Electroanalytical Chemistry, Kissenger, P.T. and Heineman, W.R., Eds., New York: Marcel Dekker, 1984, Ch. 13.
Gutmann, V., Coordination Chemistry in Non-Aqueous Solutions, Wien Springer, 1971.
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Original Russian Text © M.A. Mikhailov, A.L. Gushchin, M.R. Gallyamov, A.V. Virovets, M.N. Sokolov, D.G. Sheven’, V.V. Pervukhin, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 3, pp. 184–192.
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Mikhailov, M.A., Gushchin, A.L., Gallyamov, M.R. et al. Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W). Russ J Coord Chem 43, 172–180 (2017). https://doi.org/10.1134/S107032841702004X
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DOI: https://doi.org/10.1134/S107032841702004X