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Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands

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Abstract

Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924–1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    D. S. Ogienko, A. I. Smolentsev, D. A. Bashirov, M. Yu. Afonin, P. A. Petrov & S. N. Konchenko

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    A. I. Smolentsev, D. A. Bashirov, P. A. Petrov & S. N. Konchenko

Authors
  1. D. S. Ogienko
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  2. A. I. Smolentsev
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  3. D. A. Bashirov
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  4. M. Yu. Afonin
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  5. P. A. Petrov
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  6. S. N. Konchenko
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Corresponding author

Correspondence to S. N. Konchenko.

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Original Russian Text © D.S. Ogienko, A.I. Smolentsev, D.A. Bashirov, M.Yu. Afonin, P.A. Petrov, S.N. Konchenko, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 11, pp. 687–692.

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Ogienko, D.S., Smolentsev, A.I., Bashirov, D.A. et al. Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands. Russ J Coord Chem 41, 759–764 (2015). https://doi.org/10.1134/S1070328415110056

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  • DOI: https://doi.org/10.1134/S1070328415110056

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