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Hybrid Cyclic Water–Chloride Cluster Self-assembled in a Ruthenium(II) Polypyridyl Complex

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Abstract

A two-dimensional cyclic water–chloride anionic {[H2O)18(Cl)8]8−}n network has been identified in a ruthenium(II) complex [Ru(bpy)2(tdzp)]2·tdzp·Cl4·9H2O (bpy = 2,2′-bipyridine, tdzp = [1,2,5]-thiadiazolo-[3,4-f]-[1,10]-phenanthroline). The compound crystallized in monoclinic space group P21/c.

Graphical Abstract

A two-dimensional cyclic water-chloride anionic {[H2O)18(Cl)8]8−}n network has been identified in a ruthenium(II) complex [Ru(bpy)2(tdzp)]2⋅tdzp⋅Cl4⋅9H2O (bpy=2,2′-bipyridine, tdzp=[1,2,5]-thiadiazolo-[3,4-f]-[1,10]-phenanthroline).

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Acknowledgments

S. S. Bhat acknowledges University Grants Commission, New Delhi, India, for providing Dr. D. S. Kothari Postdoctoral grant (Award Letter No. 13-856/2013(BSR)). S. S. Bhat thanks T. Karishnachary for his help in collecting single crystal data. We thank Professor M. V. Rajasekharan for useful discussions and suggestions. Authors are also grateful to UGC Networking Resource Centre, School of Chemistry, and University of Hyderabad for providing the laboratory and instrumental facilities.

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  1. Department of Chemistry, Karnatak University, Dharwad, Karnataka, 580003, India

    Satish S. Bhat & Vidyanand K. Revankar

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  1. Satish S. Bhat
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  2. Vidyanand K. Revankar
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Correspondence to Satish S. Bhat or Vidyanand K. Revankar.

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Bhat, S.S., Revankar, V.K. Hybrid Cyclic Water–Chloride Cluster Self-assembled in a Ruthenium(II) Polypyridyl Complex. J Chem Crystallogr 46, 9–14 (2016). https://doi.org/10.1007/s10870-015-0621-z

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  • DOI: https://doi.org/10.1007/s10870-015-0621-z

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