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Unusual 1D Tape of Pentameric and Tetrameric Water Clusters Trapped in a 2D Cobalt(II) Coordination Polymer: Synthesis, Characterization, and Catalytic Properties

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Abstract

1D tape of pentameric and tetrameric water clusters have been observed in a complex of [Co(oba)(H2O)3]·(H2O)2·(dmbpy)]n (1), (H2oba = 4,4′-oxybis(benzoic acid), dmbpy = 2,2′-dimethyl-4,4′-bipyridine), which has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction and single-crystal X-ray diffraction. In 1, a cyclic pentamer formed by four water molecules and one carboxylate oxygen, as well as a chain-like tetrameric water-(carboxyl oxygen) cluster are observed. The uncoordinated carboxylate oxygen atoms of oba anions, water molecules and free dmbpy ligands interact via hydrogen bonds forms a tape in which the dmbpy ligands point alternately up and down, and extend 2D 1 into a 3D supramolecular structure. Moreover, 1 has a remarkable activity for degradation of methyl orange in a photo-assisted Fenton-like process.

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Acknowledgments

This work was supported by the Distinguished Young Talents in Higher Education of Guangdong Province (2014KQNCX222), the Natural Science Foundation of Guangdong Province (2015A030310407), the Training Plan of Guangdong Province Outstanding Young Teachers in Higher Education Institutions (YQ2015168) and the Natural Science Foundation of Zhaoqing University (201532).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Liang Qin, Kuan Lu, Xiang Li, Jingjing Yan, Weijie Lin, Wanqiu Ding, Husheng Lu, Dongting Lin & Deyun Ma

  2. College of Life Science, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Fenglan Liang

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  1. Liang Qin
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  2. Kuan Lu
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  3. Xiang Li
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Correspondence to Deyun Ma or Fenglan Liang.

Electronic Supplementary Material

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10904_2016_334_MOESM1_ESM.doc

Fig. S1 including the IR spectra of 1. Crystallographic data for the structure reported in this article has been deposited with the Cambridge Crystallographic Data Centre, CCDC No. 1412441. Copies of this information may be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge, CB21EZ, UK (fax: +44 1223 336 033; e-mail: deposit@ccdc.cam.ac.uk or (http://www.ccdc.cam.ac.uk) or also available from the author on request. Supplementary material 1 (DOC 409 kb)

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Qin, L., Lu, K., Li, X. et al. Unusual 1D Tape of Pentameric and Tetrameric Water Clusters Trapped in a 2D Cobalt(II) Coordination Polymer: Synthesis, Characterization, and Catalytic Properties. J Inorg Organomet Polym 26, 460–466 (2016). https://doi.org/10.1007/s10904-016-0334-6

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