Skip to main content
SpringerLink
Log in

Synthesis and Structural Characterization of a New 1-D Lead(II) Coordination Polymer: A New Precursor for Preparation Pb3I2O2 Nano Particles Via Thermal Decomposition

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A new lead (II) coordination polymer [Pb2(8-HQuin)2(μ-I)2] n (1) was prepared from reaction of ligand 8-hydroxyquinolin (8-HQuin) with lead(II) acetate and potassium iodide. The compound was characterized by elemental analysis, IR spectroscopy and structurally determined by X-ray single crystal diffraction. The structure of compound 1 may be considered coordination polymer of lead (II) that Pb(II) ions are bridged by iodide ions forming double chains and making one dimensional array of Pb(II) and 8-HQuin, respectively. Pure phase Lead(II) Oxide Iodide Pb3I2O2 nano particles were obtained by calcination of compound 1 at 400 °C under air atmosphere which were characterized by scanning electron microscopy (SEM) and X-ray powder diffraction (XRD).

Graphical Abstract

Coordination polymers are good precursors to synthesis of nano oxides. SEM image of Pb3I2O2 nanoparticles produced by calcination of [Pb2(8-HQuin)2(μ-I)2] n .

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Morsali A, Masoomi MY (2009) Coord Chem Rev 253:1882

    Article  CAS  Google Scholar 

  2. Blake AJ, Champness NR, Hubberstey P, Li W-S, Withersby MA, Schröder M (1999) Coord Chem Rev 183:117

    Article  CAS  Google Scholar 

  3. Barnett SA, Champness NR (2003) Coord Chem Rev 246:145

    Article  CAS  Google Scholar 

  4. Roesky HW, Andruch M (2003) Coord Chem Rev 236:91

    Article  CAS  Google Scholar 

  5. James SL (2003) Chem Soc Rev 32:276

    Article  CAS  Google Scholar 

  6. Robin AY, Fromm KM (2011) Coord Chem Rev 255:2821

    Article  Google Scholar 

  7. Akhbari K, Morsali A (2010) Coord Chem Rev 254:1977

    Article  CAS  Google Scholar 

  8. Sadeghzade H, Morsali A (2009) Inorg Chem 48:10871

    Article  Google Scholar 

  9. AbuYousefi MAM, Escuer A, Gatteschi D, Goher MAS, Mautner FA, Vicente R (1999) Inorg Chem 38:5716

    Article  Google Scholar 

  10. Aoyagi M, Biradha K, Fujita M (1999) J Am Chem Soc 121:7457

    Article  CAS  Google Scholar 

  11. Fujita YJ, Kwon S, Washizu K, Oyura J (1994) J Am Chem Soc 116:1151

    Article  CAS  Google Scholar 

  12. Morsali A, Mahjoub AR (2005) Solid State Sci 7:1429

    Article  CAS  Google Scholar 

  13. Xiao H-P, Morsali A (2005) Helv Chim Acta 88:2543

    Article  CAS  Google Scholar 

  14. Morsali A, Abedini J (2005) Inorg Chem Commun 8:460

    Article  CAS  Google Scholar 

  15. Soudi AA, Marandi F, Ramazani A, Ahmadi E, Morsali A (2005) C R Chim 8:157

    Article  CAS  Google Scholar 

  16. Morsali A, Zhu L-G (2004) Inorg Chem Commun 7:1184

    Article  CAS  Google Scholar 

  17. Morsali A, Mahjoub AR, Soltanian MJ, Darzi SJ (2003) Z Anorg Allg Chem 629:2596

    Article  CAS  Google Scholar 

  18. Morsali A, Mahjoub AR (2003) J Coord Chem 56:779

    Article  Google Scholar 

  19. Shi W-J, Hou L, Li D, Yin Y-G (2007) Inorg Chim Acta 360:588

    Article  CAS  Google Scholar 

  20. Morsali A, Monfared HH, Morsali A (2009) Inorg Chim Acta 362:3427

    Article  CAS  Google Scholar 

  21. Soltanian Fard MJ, Rastaghi F, Ghanbari N (2013) J Mol Struct 1032:133

    Article  Google Scholar 

  22. Soltanian Fard MJ, Morsali A (2010) J Inorg Organomet Polym 20:727

    Article  Google Scholar 

  23. Soltanian Fard MJ, Morsali A (2010) Ultrason Sonochem 17:435

    Article  Google Scholar 

  24. Hashemi L, Morsali A, Retailleau P (2011) Inorg Chim Acta 367:207

    Article  CAS  Google Scholar 

  25. Hashemi L, Morsali A (2012) J Inorg Organomet Polym 22:272

    Article  CAS  Google Scholar 

  26. Hashemi L, Morsali A (2011) J Coord Chem 64:4085

    Article  Google Scholar 

  27. Hashemi L, Morsali A (2010) J Inorg Organomet Polym 20:856

    Article  CAS  Google Scholar 

  28. Mercury 1.4.1 (2001–2005) Copyright Cambridge Crystallographic Data Centre, Cambridge

  29. Farrugia LJ (1997) Ortep-3 for Windows. J Appl Crystallogr 30:56

    Article  Google Scholar 

Download references

Acknowledgments

This study was supported by the Firoozabad branch of Islamic Azad university.

Author information

Authors and Affiliations

  1. Department of Chemistry, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117, Firoozabad, Fars, Iran

    Mohammad Jaafar Soltanian Fard & Hakimeh Sadat Naraghi

Authors
  1. Mohammad Jaafar Soltanian Fard
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hakimeh Sadat Naraghi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohammad Jaafar Soltanian Fard.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fard, M.J.S., Naraghi, H.S. Synthesis and Structural Characterization of a New 1-D Lead(II) Coordination Polymer: A New Precursor for Preparation Pb3I2O2 Nano Particles Via Thermal Decomposition. J Chem Crystallogr 43, 207–212 (2013). https://doi.org/10.1007/s10870-013-0406-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-013-0406-1

Keywords

Search

Navigation