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Coordination Architectures of 5-Aminotetrazole-1-Acetic Acid (Hatza) Flexible Ligand and 2,2′-Bipy Rigid Auxiliary Ligand with Mn(II)

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Abstract

Two Mn(II) coordination polymers [Mn(atza)2(H2O)2] n (1) and [Mn(atza)(2,2′-bipy)(H2O)] n ·nClO4 (2) (2) [atza = 5-aminotetrazole-1-acetato] have been synthesized and characterized by X-ray diffraction analysis, element analysis and IR spectra. Each Mn(II) ion has a distorted octahedral coordination geometry in 1 and 2, and the Mn(II) ion centres are connected through the atza bridging ligands to form a 1D ribbon-type polymeric chain for 1 and a 2D layer structure for 2.

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Acknowledgments

We greatly appreciate financial support from the Fundation of Suzhou Science and Technology of Jiangsu Province of China (SYN201015), and Key Laboratory of Advanced Functional Materials of Jiangsu Province of China (No. 10KFJJ002).

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Authors and Affiliations

  1. Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, 215500, People’s Republic of China

    Gao Wen Yang, Ming Hua He, Wei Shen, Qiao Yun Li, Lei shen & Jie Yang

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  1. Gao Wen Yang
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  2. Ming Hua He
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  3. Wei Shen
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  4. Qiao Yun Li
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Corresponding author

Correspondence to Qiao Yun Li.

Appendix A: Supplementary Material

Appendix A: Supplementary Material

CCDC 716738 and 716737 contain the supplementary crystallographic data for 1 and 2 in this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or e-mail: deposit@ ccdc.cam.ac.uk.

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Yang, G.W., He, M.H., Shen, W. et al. Coordination Architectures of 5-Aminotetrazole-1-Acetic Acid (Hatza) Flexible Ligand and 2,2′-Bipy Rigid Auxiliary Ligand with Mn(II). J Chem Crystallogr 42, 721–726 (2012). https://doi.org/10.1007/s10870-012-0306-9

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  • DOI: https://doi.org/10.1007/s10870-012-0306-9

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