An organic–inorganic hybrid polymeric complex, [BaPt(NCS)4(C20H36O6)(H2O)] n or [[Ba(DC18C6-A)(H2O)][Pt(SCN)4]] n (1) (DC18C6-A = cis-syn-cis-dicyclohexyl-18-crown-6) has been synthesized by the reaction of cis-syn-cis-dicyclohexyl-18-crown-6 with Ba(SCN)2, BaCO3 and H2PtCl4, and characterized by elementary analysis, FT-IR spectra and X-ray single-crystal diffraction. It crystallizes as monoclinic, space group P 21/n with crystallographic data: a = 14.275(6) Å, b = 13.165(5) Å, c = 18.971(8) Å, β = 106.294(6)°, V = 3422(2) Å3, Z = 4, D calcd = 1.854 g/cm3, F(000) = 1856, R 1 = 0.0491, wR 2 = 0.0709. The asymmetric unit of complex 1 contains one [Ba(DC18C6-A)(H2O)]2+ complex cation and one [Pt(SCN)4]2− complex anion, which are assembled into an infinite polymeric chain via the bridging SCN groups. The coordinated water molecule gives two different intrachain and interchain hydrogen bonds.
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We acknowledge the financial support of the Natural Science Foundation of Shandong Province (Y2003B01) and Liaocheng University, People's Republic of China.
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CCDC-227556 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, by e-mailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033.
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Sun, YM., Dong, FY., Dou, JM. et al. Synthesis and crystal structure of catena-poly[aqua(cis-syn-cis-dicyclohexyl-18-crown-6) tetra(thiocyanato)barium(II) platinum(II)]: [BaPt(NCS)4(C20H36O6)(H2O)] n . J Chem Crystallogr 36, 315–319 (2006). https://doi.org/10.1007/s10870-005-9066-0
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DOI: https://doi.org/10.1007/s10870-005-9066-0