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Syntheses, crystal structures, and properties of various one- dimensional coordination polymers based on macrocyclic metallic tectons and dicarboxylic acid ligand

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Abstract

The reaction of different macrocyclic metallic tectons and dicarboxylic acid ligand yielded six new coordination polymers, namely, {[(NiL1)(4,4'-Bpdc)] • DMF • 2.5H2O} n (I), {[(NiL2)(4,4'-Bpdc)] • DMF • 2.5H2O} n (II), [(NiL3)2(4,4'-Bpdc)1.5][(NiL3)(4,4'-Bpdc)] • ClO4 • 28H2O (III), {[(NiL4)(4,4'-Bpdc)] • 4H2O} n (IV), {[(NiL5)(4,4'-Tpdc)] • 5H2O} n (V), {[(NiL3)(4,4'-Tpdc)]} n (VI) (L1 = 1,4,7,9,12,14-hexaaza-tricyclo[12.2.1.14.7]octadecane, L2 = 1,3,10,12,15,18-hexaazatetracyclo[16.2.1.112.15.04.9]docosane, L3 = 11-methyl-1,4,8,10,13,15-hexaaza-tricyclo[13.3.1.14.8]icosane, L4 = 1,3,10,12,16,19-hexaazate-tracyclo[17.3.1.1.12.16,04.9]tetracosane, L5 = 1,4,8,10,13,15-hexaaza-tricyclo[13.3.1.14.8]icosane, 4,4'-Bpdc = 4,4'-biphenyldicarboxylic acid and 4,4'-Tpdc = 4,4'-terphenyldicarboxylic acid) (CIF files CCDC nos. 1055545–1055550 for I–VI, respectively). Except for the different conformations of the macrocyclic metallic tectons or dicarboxylic acid ligands, complexes I–VI crystallized under the same environment, however, they exhibit diverse packing mode of infinite 1D coordination polymers, showing macrocyle or dicarboxylic acid ligand regulated self-assemble. The solid states UV-Vis for complexes I–VI also have been investigated.

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Authors and Affiliations

  1. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan, 430074, P.R. China

    G. X. Zhou, X. Y. Wang, G. Yan, G. Y. Liao & H. Xia

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  1. G. X. Zhou
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  2. X. Y. Wang
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  3. G. Yan
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  4. G. Y. Liao
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  5. H. Xia
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Zhou, G.X., Wang, X.Y., Yan, G. et al. Syntheses, crystal structures, and properties of various one- dimensional coordination polymers based on macrocyclic metallic tectons and dicarboxylic acid ligand. Russ J Coord Chem 42, 461–469 (2016). https://doi.org/10.1134/S1070328416060105

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  • DOI: https://doi.org/10.1134/S1070328416060105

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