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Structural and magnetic influence by mg on BaFe10Al2O19 hexaferrites prepared via ceramic route for potential magnetic applications

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Abstract

Cationic substitutions and sintering temperature both are crucial variables in modifying the structural and magnetic properties of M-type hexaferrites. The effect of the cationic substitutions on M-type BaFe10−xAl2MgxO19 hexaferrites is examined in the current work. An XRD analysis reveals that Fe2O3 phases are present as an impurity in all of the samples. Firstly, lattice parameters a and c show a decrease, then start increasing. The(Mr/Ms) ratio confines within a specific stable range. Morphology of the samples shows the uniform distribution of the particles throughout all the compositions.The anisotropy field-(Ha) and coercivity-(Hc) show an increase with increasing doping levels. The average grain size (D) grew continuously between 200 and 900 nm as the the doping content of Mg ascended. At a doping content of x = 0.05, the M type BaFe9.95Al2Mg0.05O19 hexaferrites shows the excellent magnetic characteristics having mB = 9.4098µB, Ms = 49.95 emu/g, Hc = 4.98 kOe, and Ha = 1.6kOe. The findings suggest that M-type hexagonal ferrite’s magnetic properties can be significantly enhanced by varying the cationic substitutions.

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Acknowledgements

The authors are thankful to the Deanship of Scientific Research at King Khalid University for funding this work through a large group Research Project under Grant Number RGP2/236/44.

Funding

Funding was supported by Deanship of Scientific Research at King Khalid University for funding this work through a large group Research Project under Grant Number (RGP2/236/44).

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Authors and Affiliations

  1. School of Materials and Energy, Yunnan University, Kunming, 650091, People’s Republic of China

    Sana Ullah Asif

  2. Department of Industrial & Manufacturing Engineering (RCET), University of Engineering & Technology, Lahore, Pakistan

    Ubaid-ur-Rehman Ghori

  3. Division of Science and Technology, Department of Physics, University of Education, Lahore, Pakistan

    Muhammad Ahsan & Fahim Ahmed

  4. Department of Chemistry, College of Arts and Sciences, Prince Sattam Bin Abdulaziz University, Wadi Al-Dawasir, 11991, Saudi Arabia

    Ebraheem Abdu Musad Saleh & M. M. Moharam

  5. Chemical and Electrochemical Processing Department, Central Metallurgical Research and Development Institute (CMRDI), P.O. Box 87, Helwan, 11421, Egypt

    M. M. Moharam

  6. Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, Dammam, 31441, Saudi Arabia

    Eman A. Alabbad

  7. Basic and Applied Scientific Research Centre, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, Dammam, 31441, Saudi Arabia

    Eman A. Alabbad

  8. Catalysis Research Group (CRG), Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, Abha, 61413, Saudi Arabia

    Fatma A. Ibrahim & Mohamed S. Hamdy

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  1. Sana Ullah Asif
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Contributions

All the authors contributed equally to this work. SUA, and FA, gave the idea. MA, synthesized material, SUA, FA, FAI, MMH, EAMS, and MSH analyzed the data. EAA, and URG, formatted the initial draft. The manuscript was written through the contributions of all authors. All authors have approved the final version of the manuscript.

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Correspondence to Sana Ullah Asif or Fahim Ahmed.

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Asif, S.U., Ghori, UuR., Ahsan, M. et al. Structural and magnetic influence by mg on BaFe10Al2O19 hexaferrites prepared via ceramic route for potential magnetic applications. J Mater Sci: Mater Electron 34, 2211 (2023). https://doi.org/10.1007/s10854-023-11645-7

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