Abstract
Embracing mixed oxide state response course, lead-free polycrystalline 0.075(K0.5Bi0.5TiO3)–0.925 (NaNbO3) or 0.075 (KBT)–0.925 (NN) ceramic integrate, and its optical, auxiliary, dielectric, ferroelectric, and impedance properties are investigated. Basic examination represents the arrangement of new perovskite, with an orthorhombic structure having space bunch as Pmc21. FESEM micrograph proves the closeness of homogeneous nature in morphology. FTIR analysis suggests that there is a change in the vibrational mode of phonons due to the inclusion of NN with KBT. The optical band gap of the material is 3.06 eV as obtained from the diffuse absorbance spectra which is suitable for the photo-catalytic application. From Raman spectra, it is seen quite different vibrational modes from 130 to 900 cm−1. Polarization study affirms the ferroelectric idea of the present investigation. Dielectric and complex impedance investigations are carried out in the frequency range of 102–106 Hz and temperature range of 30–500 °C. AC conductivity range is represented by Jonscher’s power law. AC conductivity reveals the semiconducting nature of the material.
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All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by [SKM], [BB], [BNP] [RKP], and [PRD]. The first draft of the manuscript was written by [SKM] and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Mohanty, S.K., Behera, B., Parida, B.N. et al. Impact of KBiTiO3 in optical and ferroelectric behavior of NaNbO3 solid solution. J Mater Sci: Mater Electron 34, 2126 (2023). https://doi.org/10.1007/s10854-023-11517-0
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DOI: https://doi.org/10.1007/s10854-023-11517-0