Abstract
Bi2O3–TeO2–CdO glasses’ structural, thermal, optical, and gamma ray shielding behaviour were studied. Raman spectroscopy revealed that the glasses include BiO3, BiO6, TeO4, TeO3 units as well as CdO metal oxide clusters. The glasses lost just a small percentage of their original weight (less than 2%) on heating upto 800 °C, indicating that they can survive extreme heat without suffering any major changes to their structure or capabilities. The glass transition temperature (Tg) drops from 455 to 408 °C when Bi2O3 is added. The thermal profile of the glasses shows two exothermic peaks. As the Bi2O3 concentration in the samples rose, the indirect band gap energy dropped from 3.066 to 2.951 eV. With the use of the Phy-X program, the radiation shielding parameters have been calculated for the prepared glasses for energies ranging from 0.015 to 15 MeV. The linear attenuation coefficient (LAC) is high at 0.015 MeV (varied between 485.4 and 538.8 cm−1 for CTB4 glass, which is the glass with the largest percentage of Bi2O3, demonstrates the highest levels of LAC. The enhancement in the LAC due to the inclusion of Bi2O3 is observed in the prepared glasses. The enhancement in LAC is more pronounced at lower energies, especially below 0.03 MeV. From the effective atomic number data, increasing the amount of Bi2O3 in the glasses results in improved radiation shielding efficacy, particularly at lower energy.
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The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.
References
G. Pintori, E. Cattaruzza, XPS/ESCA on glass surfaces: a useful tool for ancient and modern materials. Opt. Mater. X 13, 100108 (2022)
M.I. Abualsayed, Radiation attenuation attributes for BaO–TiO2–SiO2–GeO2 glass series: a comprehensive study using Phy-X software. Radiochim. Acta 111(3), 211–216 (2023)
A.H. Almuqrin, M.I. Sayyed, A. Kumar, B.O. El-bashir, I. Akkurt, Optical, mechanical properties and gamma ray shielding behavior of TeO2–Bi2O3–PbO–MgO–B2O3 glasses using FLUKA simulation code. Opt. Mater. 113, 110900 (2021)
M.I. Sayyed, A.H. Almuqrin, A. Kumar, J.F.M. Jecong, I. Akkurt, Optical, mechanical properties of TeO2–CdO–PbO–B2O3 glass systems and radiation shielding investigation using EPICS2017 library. Optik 242, 167342 (2021)
H. Aljawhara, M.I. Almuqrin, N.S. Sayyed, S.D. Prabhu, Kamath, Influence of Bi2O3 on mechanical properties and radiation-shielding performance of lithium zinc bismuth silicate glass system using Phys-X software. Materials. 15, 1327 (2022)
M.S. Al-Buriahi, T. Kavas, E. Kavaz, R. Kurtulus, I.O. Olarinoye, Recycling potential of cathode ray tubes (CRTs) waste glasses based on Bi2O3 addition strategies. Waste Manag. 148, 43–49 (2022). https://doi.org/10.1016/j.wasman.2022.04.033
M.I. Sayyed, The role of Bi2O3 on radiation shielding characteristics of ternary bismuth tellurite glasses. Optik 270, 169973 (2022)
M.I. Sayyed, N.S. Prabhu, J.F.M. Jecong, S.D. Kamath, The mechanical and radiation shielding characteristics of the Li2O–Bi2O3–CdO–B2O3 glass system after swapping Li2O with Bi2O3. Optik 258, 168950 (2022)
S. Kaewjaeng, N. Chanthima, J. Thongdang, S. Reungsri, S. Kothan, J. Kaewkhao, Synthesis and radiation properties of Li2O–BaO–Bi2O3–P2O5 glasses. Mater. Today Proc. 43, 2544–2553 (2021)
R.A.H. El-Mallawany, Tellurite glasses handbook: physical properties and data, 2nd edn. (Routledge, Abingdon, 2016)
M. Çelikbilek, A.E. Ersundu, N. Solak, S. Aydin, Crystallization kinetics of the tungsten–tellurite glasses. J. Non-cryst. Solids. 357, 88–95 (2011)
A. Sharma, M.I. Sayyed, O. Agar, H.O. Tekin, Simulation of shielding parameters for TeO2-WO3-GeO2 glasses using FLUKA code. Results Phys 13, 102199 (2019)
S. Sharma, Metallic glass–based nanocomposites (CRC Press, Boca Raton, 2020). https://doi.org/10.1201/9780429021992
M.S. Al-Buriahi, V.P. Singh, A. Alalawi, C. Sriwunkum, B.T. Tonguc, Mechanical features and radiation shielding properties of TeO2–Ag2O–WO3 glasses. Ceram. Int. 46(10), 15464–15472 (2020)
K.A. Naseer, K. Marimuthu, M.S. Al-Buriahi, A. Alalawi, H.O. Tekin, Influence of Bi2O3 concentration on barium–telluro–borate glasses: physical, structural and radiation-shielding properties. Ceram. Int. 47(1), 329–340 (2020)
M.S. Al-Buriahi, B. Tonguç, U. Perisanoglu, E. Kavaz, The impact of Gd2O3 on nuclear safety proficiencies of TeO2–ZnO–Nb2O5 glasses: a GEANT4 Monte Carlo study. Ceram. Int. 46, 23347–23356 (2020)
D.A. Aloraini, A. Kumar, A.H. Almuqrin, M.I. Sayyed, Effect of adding SrO, TeO2, PbO, and Bi2O3 heavy metal oxides on the optical and gamma ray shielding properties of Li2O–K2–B2O3 glasses. Optik 247, 167848 (2021)
S.A.M. Issa, A.M.A. Mostafa, Effect of Bi2O3in borate–tellurite–silicate glass system for development of gamma-rays shielding materials. J. Alloys Compd. 695, 302–310 (2017). https://doi.org/10.1016/j.jallcom.2016.10.207
J. Anjaiah, C. Laxmikanth, Optical properties of neodymium ion doped lithium borate glasses. J. Pure Appl. Ind. Phys. 5(6), 173–183 (2015)
R. Vijaya Kumar, P. Gayathri Pavani, B. Ramesh, M. Shareefuddin, K. Siva, Kumar, Structural studies of xLi2O–(40–x)Bi2O3–20CdO–40B2O3 glasses. Opt. Mater. 35(12), 2267–2274 (2013)
A. Vegiri, C.P.E. Varsamis, Clustering and percolation in lithium borate glasses. J. Chem. Phys. 120(16), 7689–7695 (2004)
N. Shinkai, R. Bradt, G.E. Rindone, Elastic modulus and fracture toughness of ternary PbO–ZnO–B2O3 glasses. J. Am. Ceram. Soc. 65(2), 123–126 (1982)
S. Sindhu, S. Sanghi, S. Rani, A. Agarwal, V.P. Seth, Modification of structure and electrical conductivity of cadmium borate glasses in the presence of V. Mater. Chem. Phys. 2O5(2), 236–243 (2008)
M.E. Zayas, H. Arizpe, S.J. Castillo, F. Medrano, G.C. Diaz, J.M. Rincon et al., Glass formation area and structure of glassy materials obtained from ZnO–CdO–TeO2 ternary system. Phys. Chem. Glasses. 46, 46–50 (2005)
H. Aljawhara, A. Almuqrin, H.J. Kumar, M.I. Alasali, Sayyed, Impact of high concentration of the Bi2O3 on the physical, mechanical and gamma ray shielding capability of the Bi2O3–TeO2–CdO glass system. J. Mater. Sci. Mater. Electron. 34, 1112 (2023)
V. Bhatia, D. Kumar, A. Kumar, V. Mehta, S. Chopra, A. Vij, S.M.D. Rao, S.P. Singh, Mixed transition and rare earth ion doped borate glass: structural, optical and thermoluminescence study. J. Mater. Sci. Mater. Electron. 30, 677–686 (2019)
F.F. Al-Harbi, N.S. Prabhu, M.I. Sayyed, H. Aljawhara, A. Almuqrin, S.D. Kumar, Kamath, Evaluation of structural and gamma ray shielding competence of Li2O–K2O–B2O3–HMO (HMO = SrO/TeO2/PbO/Bi2O3) glass system. Optik 248, 168074 (2021)
D. Souri, Z.E. Tahan, A new method for the determination of optical band gap and the nature of optical transitions in semiconductors. Appl. Phys. B 119, 273–279 (2015)
B.M. Alotaibi, M.I. Sayyed, A. Kumar, M. Alotiby, K.A. Mahmoud, H.A. Al-Yousef, N.A.M. Alsaif, Y. Al-Hadeethi, Fabrication of TeO2-doped strontium borate glasses possessing optimum physical, structural, optical and gamma ray shielding properties. Eur. Phys. J. Plus. 136, 468 (2021)
Z. Pan, D.O. Henderson, S.H. Morgan, A Raman investigation of lead haloborate glasses. J. Chem. Phys. 101, 1767–1774 (1994)
B. Mihailova, M. Gospodinov, L. Konstantinov, Raman spectroscopy study of sillenites. I. comparison between Bi12(Si,Mn)O20 single crystals. J. Phys. Chem. Solids. 60, 1821–1827 (1999)
B. Mihailova, G. Bogachev, V. Marinova, L. Konstantinov, Raman spectroscopy study of sillenites. II. Effect of doping on Raman spectra of Bi0TiO20. J. Phys. Chem. Solids. 60, 1829–1834 (1999)
V. Sreenivasulu, G. Upender, V.C. Mouli, M. Prasad, Structural, thermal and optical properties of TeO2–ZnO–CdO–BaO glasses doped with VO2+. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 148, 215–222 (2015)
A. Ashrafi, Raman-active wurtzite CdO nanophase and phonon signatures in CdO/ZnO heterostructures fabricated by non-equilibrium laser plasma ablation and stress control. Appl. Phys. Lett. 98, 133119 (2011)
T.M. Khan, T. Shahid, M. Zakria, R.I. Shakoor, Optoelectronic properties and temperature dependent mechanisms of composite-hydroxide-mediated approach for the synthesis of CdO nanomaterials. Electron. Mater. Lett. 11, 366–373 (2015)
F.D. Hardcastle, I.E. Wachs, The molecular structure of bismuth oxide by Raman spectroscopy. J. Solid State Chem. 97, 319–331 (1992)
H.T. Fan, S.S. Pan, X.M. Teng, C. Ye, Li,structure and thermal stability of δ-Bi2O3 thin films deposited by reactive sputtering. J. Phys. D Appl. Phys. 39, 1939–1943 (2006)
I.S. Mustafa, H.M. Kamari, W.M.D.W. Yusoff, S.A. Aziz, A.A. Rahma, Structural and optical properties of lead-boro-tellurrite glasses induced by gamma-ray. Int. J. Mol. Sci. 14(2), 3201–3214 (2013). https://doi.org/10.3390/ijms14023201
T.R. Hart, R.L. Aggarwal, B. Lax, Temperature dependence of Raman scattering in silicon. Phys. Rev. B 1, 638 (1970)
El S. Yousef, S.F. Mansour, M.Y. Hassaan, A.M. Emara, Synthesis optical properties of novel TeO2 based glasses. Optik. 127, 8933–8939 (2016). https://doi.org/10.1016/j.ijleo.2016.06.113
J. Lin, W. Huang, Z. Sun, C.S. Ray, D.E. Day, Structure and non-linear optical performance of TeO2–Nb2O5–ZnO glasses. J. Non-cryst. Solids. 336, 189–194 (2004). https://doi.org/10.1016/j.jnoncrysol.2004.02.007
H. Ticha, J. Schwarz, L. Tichy, Raman spectra and optical band gap in some PbO–ZnO–TeO2 glasses. Mater. Chem. Phys. 237, 121834 (2019)
A. Kaur, A. Khanna, V.G. Sathe, F. Gonzalez, B. Ortiz, Optical, thermal, and structural properties of Nb2O5–TeO2 and WO3–TeO2 glasses. Phase Transit. 86, 598–619 (2013). https://doi.org/10.1080/01411594.2012.727998
G. Upender, S. Ramesh, M. Prasad, V.G. Sathe, V.C. Mouli, Optical band gap, glass transition temperature and structural studies of (100–2x)TeO2–xAg2O–xWO3 glass system. J. Alloys Compd. 504, 468–474 (2010). https://doi.org/10.1016/j.jallcom.2010.06.006
H. Fares, I. Jlassi, H. Elhouichet, M. Férid, Investigations of thermal, structural and optical properties of tellurite glass with WO3 adding. J. Non-cryst. Solids (2014). https://doi.org/10.1016/j.jnoncrysol.2014.04.012
M.S. Dahiya, S. Khasa, A. Agarwal, Structural, optical and thermal properties of transition metal ions doped bismuth borate glasses. Phys. Chem. Glasses Eur. J. Glass Sci. Technol. B 57, 45–52 (2016)
M. Udovic, P. Thomas, A. Mirgorodsky, O. Durand, M. Soulis, O. Masson, T. Merle-Méjean, J.C. Champarnaud-Mesjard, Thermal characteristics, Raman spectra and structural properties of new tellurite glasses within the Bi2O3–TiO2–TeO2 system. J. Solid State Chem. 179, 3252–3259 (2006)
R.S. Kundu, S. Dhankhar, R. Punia, K. Nanda, N. Kishore, Bismuth modified physical, structural and optical properties of mid-IR transparent zinc boro-tellurite glasses. J. Alloys Compd. 587, 66–73 (2014)
H.A.A. Sidek, S. Rosmawati, Z.A. Talib, M.K. Halimah, W.M. Daud, Synthesis and optical properties of ZnO–TeO2 glass system. Am. J. Appl. Sci. 6, 1489 (2009)
A.E. Al-salami, E.R. Shaaban, A TEM study and non-isothermal crystallization kinetic of tellurite glass-ceramics. J. Mater. Sci. 45, 5929–5936 (2010)
A. Šantić, A. Moguš-Milanković, K. Furić, M. Rajić-Linarić, C.S. Ray, D.E. Day, Structural properties and crystallization of sodium tellurite glasses. Croat. Chem. Acta 81, 559–567 (2008)
N. Berwal, S. Dhankhar, P. Sharma, R.S. Kundu, R. Punia, N. Kishore, Physical, structural and optical characterization of silicate modified bismuth–borate–tellurite glasses. J. Mol. Struct. 1127, 636–644 (2017)
M. Abdel-Baki, F.A. Abdel-Wahab, F. El-Diasty, One-photon band gap engineering of borate glass doped with ZnO for photonics applications. J. Appl. Phys. 111, 073506 (2012)
S. Sindhu, S. Sanghi, A. Agarwal, V.P. Seth, N. Kishore, Effect of Bi2O3 content on the optical band gap, density and electrical conductivity of MO–Bi2O3–B2O3 (M = Ba, Sr) glasses. Mater. Chem. Phys. 90, 83–89 (2005)
M.H.M. Zaid, K.A. Matori, S.H. Ab Aziz, H.M. Kamari, Z.A. Wahab, N. Effendy, I.M. Alibe, Comprehensive study on compositional dependence of optical band gap in zinc soda lime silica glass system for optoelectronic applications. J. NonCryst. Solids. 449, 107–112 (2016)
Z.M. Elqahtani, M.I. Sayyed, A. Kumar, J.F.M. Jecong, A.H. Almuqrin, Impact of Bi2O3 on optical properties and radiation attenuation characteristics of Bi2O3–Li2O–P2O5 glasses. Optik 248, 168081 (2021)
N.B. Mohamed, A.K. Yahya, M.S.M. Deni, S.N. Mohamed, M.K. Halimah, H.A.A. Sidek, Effects of concurrent TeO2 reduction and ZnO addition on elastic and structural Properties of (90–x)TeO2–10Nb2O5–(x)ZnO glass. J. Non-cryst Solids 356, 1626–1630 (2010)
V. Rajendran, N. Palanivelu, B.K. Chaudhuri, Characterisation of semiconducting V2O5–Bi2O3–TeO2 glasses through ultrasonic measurements. J. Non-cryst Solids 320, 195–209 (2003)
Y. Wang, S. Dai, F. Chen, T. Xu, Q. Nie, Physical properties and optical band gap of new tellurite glasses within the TeO2–Nb2O5–Bi2O3 system. Mater. Chem. Phys. 113, 407–411 (2009)
M.I. Erdem Sakar, M. Sayyed, M. Kurudirek, Phy-X/PSD: development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry. Radiation Physics and Chemistry 166, 108496 (2020)
B. Speit Radiation-shielding glasses providing safety against electrical discharge and being resistant to discoloration (1991) Google Patents
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The authors express their gratitude to the Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R57), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.
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DAA: Writing, Editing and Proof Reading; Funding Acquisition. AHA: Writing, Editing and Proof Reading; Funding Acquisition. MIS: Writing, Editing and Proof Reading, Conceptualization, Writing Original Draft. AK: Methodology; Writing Original Draft; Validation; Conceptualization; Data Analysis. SY: Methodology; Software; Validation, Data Curation; Validation; Conceptualization.
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Aloraini, D.A., Almuqrin, A.H., Sayyed, M.I. et al. Characterizing the properties of Bi2O3–TeO2–CdO glasses: a multidimensional investigation of their structure, thermal behaviour, optical properties, and gamma ray shielding capability. J Mater Sci: Mater Electron 34, 1795 (2023). https://doi.org/10.1007/s10854-023-11206-y
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DOI: https://doi.org/10.1007/s10854-023-11206-y