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Morphology, structure and optical properties of PVA nanocomposites reinforced with bismuth oxide nanoparticles and carbon quantum dots

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Abstract

In this study, bismuth oxide (Bi2O3) and carbon quantum dots (CQDs) were synthesized, structural, morphological and optical properties of the obtained samples were investigated. Novel polymer nanocomposite films were obtained by using the casting method with introducing the produced Bi2O3 and CQDs nanoparticles to polyvinyl alcohol (PVA) at different rates. The structural features of the resulting polymer nanocomposite films were investigated by X-ray diffraction technique. The optical parameters of composite films were investigated using the absorption and transmittance spectra. The increase in the amount of Bi2O3 additives in the composite PVA films decreased the optical transmittance and energy band gap. Again, the increasing Bi2O3-doped to the composite films increased the reflectance, absorption coefficient and extinction coefficient values. The refractive index increased from 1.946 to 1.980 for Bi2O3 doped samples and the refractive index reached 2.468 with introducing CQDs to polymer composite film. The yellowness of polymer nanocomposite films was remarkably enhanced with CQDs addition. This novel material has potential use in fields in different fields, including optoelectronics and sensors.

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Acknowledgements

This study was supported by the Scientific Research Projects Coordination Unit of Kahramanmaraş Sütçü İmam University. Project number 2021/1-7 YLS.

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Kahramanmaraş Sütçü Imam Üniversitesi, 2021/1-7 YLS., Hasan Eskalen

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Authors and Affiliations

  1. Department of Opticianry, Elbistan Vocational School of Health Services, Kahramanmaraş Istiklal University, Kahramanmaraş, Turkey

    Mustafa Kavgacı

  2. Department of Opticianry, Vocational School of Health Services, Kahramanmaraş Sütçü İmam University, Kahramanmaraş, Turkey

    Hasan Eskalen

  3. Department of Material Science and Engineering, Graduate School of Natural and Applied Sciences, Kahramanmaraş Sütçü İmam University, Kahramanmaraş, Turkey

    Mustafa Kavgacı & Hasan Eskalen

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  1. Mustafa Kavgacı
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The manuscript was written with the contributions of all authors. All authors have approved the final version of the manuscript. MK: Experimental measurements, investigation, HE: Experimental measurements, investigation, review & editing, supervision.

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Correspondence to Hasan Eskalen.

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Kavgacı, M., Eskalen, H. Morphology, structure and optical properties of PVA nanocomposites reinforced with bismuth oxide nanoparticles and carbon quantum dots. J Mater Sci: Mater Electron 34, 1229 (2023). https://doi.org/10.1007/s10854-023-10617-1

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