Abstract
A comparative study is carried out to observe the effect of dispersing Zinc Oxide (ZnO) nanoparticles in two different host matrices of Polyvinylalcohol (PVA)—Polyvinylpyrrolidone (PVP)—Polyvinylalcohol (PVA)—Carboymethyl Cellulose (CMC) on their structural, optical and electrical properties. The concentration of ZnO in the blend films was kept low. The XRD diffractogram of both the polymer nanocomposite films (PNCs) exhibited characteristic peaks of ZnO confirming the dispersion of nanoparticles in blended films. The SEM micrographs of these PNC films had shown uniform dispersion of ZnO nanoparticles in both matrices. The analysis of optical and electrical properties indicates appreciable modification in these properties on inclusion of small amount of ZnO in both the matrices. ZnO dispersed PVA–CMC film shows enhanced absorption in UV region with decreased band gap and higher σdc values as compared to ZnO dispersed PVA–PVP film suggesting PVA–CMC–ZnO film to be a promising material in the area of green electronics and optoelectronics.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ponnamma D et al (2019) Synthesis, optimization and applications of ZnO/polymer nanocomposites. Mater Sci Eng C 98:1210–1240
Nangia R, Shukla NK, Sharma A (2019) Optical and structural properties of Se80Te15Bi5/PVA nanocomposite films. J Mol Struct 1177:323–330
Dhatarwal P, Sengwa RJ (2021) Investigation on the optical properties of (PVP/PVA)/Al2O3 nanocomposite films for green disposable optoelectronics. Phys B 412989
Rithin Kumar NB et al (2015) Studies on structural, optical and mechanical properties of MWCNTs and ZnO nanoparticles doped PVA nanocomposites. Nanotechnol Rev 4.5:457–467
Dhatarwal P, Sengwa RJ, Choudhary S (2020) Multifunctional (PVP/PEO)/SnO2 nanocomposites of tunable optical and dielectric properties. Optik 221:165368
Ali FM, Kershi RM (2020) Synthesis and characterization of La 3+ Ions incorporated (PVA/PVP) polymer composite films for optoelectronics devices. J Mater Sci Mater Electron 31(3):2557–2566
Yassin AY (2020) Dielectric spectroscopy characterization of relaxation in composite based on (PVA–PVP) blend for nickel–cadmium batteries. J Mater Sci Mater Electron 31(21):19447–19463
Chapi S, Raghu S, Devendrappa H (2016) Enhanced electrochemical, structural, optical, thermal stability and ionic conductivity of (PEO/PVP) polymer blend electrolyte for electrochemical applications. Ionics 22(6):803–814
Sengwa RJ, Choudhary S, Dhatarwal P (2019) Nonlinear optical and dielectric properties of TiO2 nanoparticles incorporated PEO/PVP blend matrix based multifunctional polymer nanocomposites. J Mater Sci Mater Electron 30(13):12275–12294
Choudhary S, Sengwa RJ (2018) ZnO nanoparticles dispersed PVA–PVP blend matrix based high performance flexible nanodielectrics for multifunctional microelectronic devices. Curr Appl Phys 18(9):1041–1058
Mohammed G, El Sayed AM, Morsi WM (2018) Spectroscopic, thermal, and electrical properties of MgO/polyvinyl pyrrolidone/polyvinyl alcohol nanocomposites. J Phys Chem Solids 115:238–247
Rajesh K, Crasta V, Kumar NR, Shetty G, Rekha PD (2019) Structural, optical, mechanical and dielectric properties of titanium dioxide doped PVA/PVP nanocomposite. J Polym Res 26(4):1
El Sayed AM, El-Gamal S, Morsi WM, Mohammed G (2015) Effect of PVA and copper oxide nanoparticles on the structural, optical, and electrical properties of carboxymethyl cellulose films. J Mater Sci 50(13):4717–4728
Abutalib MM (2019) Effect of zinc oxide nanorods on the structural, thermal, dielectric and electrical properties of polyvinyl alcohol/carboxymethyle cellulose composites. Phys B 57:108–116
El-Gamal S, El Sayed AM, Abdel-Hady EE (2018) Effect of cobalt oxide nanoparticles on the nano-scale free volume and optical properties of biodegradable CMC/PVA films. J Polym Environ 26(6):2536–2545
Hashim A, Hadi Q (2018) Synthesis of novel (polymer blend-ceramics) nanocomposites: structural, optical and electrical properties for humidity sensors. J Inorg Organomet Polym Mater 28(4):1394–1401
Zhu J, Li Q, Che Y, Liu X, Dong C, Chen X, Wang C (2020) Effect of Na2CO3 on the microstructure and macroscopic properties and mechanism analysis of PVA/CMC composite film. Polymers 12(2):453
Hashim A, Hadi Q (2018) Structural, electrical and optical properties of (biopolymer blend/titanium carbide) nanocomposites for low cost humidity sensors. J Mater Sci Mater Electron 29(13):11598–604
Banerjee M, Jain A, Mukherjee GS (2019) Microstructural and optical properties of polyvinyl alcohol/manganese chloride composite film. Polym Compos 40(S1):E765–E775
Soliman TS, Rashad AM, Ali IA, Khater SI, Elkalashy SI (2020) Investigation of linear optical parameters and dielectric properties of polyvinyl alcohol/ZnO nanocomposite films. Phys Status Solidi A 217(19):2000321
Ji T, Zhang R, Dong X, Sameen DE, Ahmed S, Li S, Liu Y (2020) Effects of ultrasonication time on the properties of polyvinyl alcohol/sodium carboxymethyl cellulose/nano-ZnO/multilayer graphene nanoplatelet composite films. Nanomaterials 10(9):1797
Krishnaswamy S, Panigrahi P, Nagarajan GS (2020) Tailoring the optical properties of ZnO thin film by citrus limon doped polypyrrole. J Mater Sci Mater Electron 31(11):8502–8513
Dhatarwal P, Sengwa RJ (2020) Structural, dielectric dispersion and relaxation, and optical properties of multiphase semicrystalline PEO/PMMA/ZnO nanocomposites. Compos Interfaces 3:1–6
Sengwa RJ, Dhatarwal P (2021) Polymer nanocomposites comprising PMMA Matrix and ZnO, SnO2, and TiO2 nanofillers: a comparative study of structural, optical, and dielectric properties for multifunctional technological applications. Opt Mater 113:110837
Albaris H, Karuppasamy G (2019) CuO–ZnO p–n junction enhanced oxygen sensing property of polypyrrole nanocomposite at room temperature. J Mater Sci Mater Electron 30(10):9989–9998
Ramesan MT, Greeshma KP, Parvathi K, Anilkumar T (2020) Structural, electrical, thermal, and gas sensing properties of new conductive blend nanocomposites based on polypyrrole/phenothiazine/silver-doped zinc oxide. J Vinyl Addit Technol 26(2):187–195
Sengwa RJ, Dhatarwal P (2021) Nanofiller concentration-dependent appreciably tailorable and multifunctional properties of (PVP/PVA)/SnO2 nanocomposites for advanced flexible device technologies. J Mater Sci Mater Electron 1–14
Naveen CS, Jayanna HS, Lamani AR, Rajeeva MP (2014) Temperature dependent DC electrical conductivity studies of ZnO nanoparticle thick films prepared by simple solution combustion method. In: AIP conference proceedings, vol 1591, No 1, pp 402–404. American Institute of Physics
Hemalatha KS, Sriprakash G, Ambika Prasad MV, Damle R, Rukmani K (2015) Temperature dependent dielectric and conductivity studies of polyvinyl alcohol-zno nanocomposite films by impedance spectroscopy. J Appl Phys 118(15):154103
Shanthala VS, Shobha Devi SN, Murugendrappa MV (2017) Synthesis, characterization and DC conductivity studies of polypyrrole/copper zinc iron oxide nanocomposites. J Asian Ceram Soc 5(3):227–234
Acknowledgements
Authors are thankful to KIRAN Division, Department of Science and Technology (DST), New Delhi for the financial assistance provided through WOS-A project SR/WOS-A/PM-44/2017. Experimental facilities developed using financial assistance provided through DST-FIST (Level- I) and DRS (SAP) program have been utilized to carry out this work and it is gratefully acknowledged. Authors are thankful to Prof. P. N. Gajjar, Head, Department of Physics, School of Science, Gujarat University, Ahmedabad for his constant encouragement. The experimental facility for I-V measurements extended by Prof. Dhaka and Prof. M. Roy, Department of Physics, MLSU, Udaipur are highly acknowledged.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Jha, S., Bhavsar, V., Sooraj, K.P., Ranjan, M., Tripathi, D. (2022). Optical and Electrical Properties of ZnO Dispersed Polymer Nanocomposites Films. In: Bindhu, V., R. S. Tavares, J.M., Ţălu, Ş. (eds) Proceedings of Fourth International Conference on Inventive Material Science Applications. Advances in Sustainability Science and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-16-4321-7_22
Download citation
DOI: https://doi.org/10.1007/978-981-16-4321-7_22
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-16-4320-0
Online ISBN: 978-981-16-4321-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)