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Enhancing the linear and nonlinear optical properties by ZnS/V-doped polyvinyl alcohol/carboxymethyl cellulose/polyethylene glycol polymeric nanocomposites for optoelectronic applications

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Abstract

Vanadium-doped nano zinc sulfide (ZnS/V) was formed using solid state reaction method at low temperature. Polyvinyl alcohol (PVA)/carboxymethyl cellulose (CMC)/polyethylene glycol (PEG) films composed with different content of ZnS/V nanoparticles (0, 1, 3, 5, 10 wt%) were produced using casting technique. The structural feature of ZnS/V nanoparticles was examined using Rietveld method. The structure and optical characteristics of the filled PVA/CMC/PEG blended polymers were investigated applying X-ray diffraction, Fourier transform infrared, fluorescence, energy dispersive X-ray analysis, scanning electron microscope and diffused reflectance techniques. The investigated results indicated that the optical parameters including the refractive index and nonlinear optics of the blended polymer exhibited a considerable improvement by loading nano ZnS/V. The direct and indirect optical bandgaps could be tailored between (5.63, 5.28) eV for the pure blend and (3.64, 2.77) eV for blended polymer doped with10% ZnS/V. Broad FL spectra were obtained for all blended polymers with FL intensity greatly affected with ZnS/V nanoparticles while the FL peaks are shifted a little. These results indicate the possibility of applying the samples under the study in several potential optoelectronic applications.

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Acknowledgements

The authors acknowledge Taif University Researchers Supporting Project Number (TURSP-2020/249), Taif University, Taif, Saudi Arabia.

Funding

This study is supported by Taif University.

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Authors and Affiliations

  1. Physics & Astronomy Department, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia

    A. M. El-naggar & A. M. Kamal

  2. Physics Department, Faculty of Science, Ain Shams University, Cairo, Egypt

    Zein K. Heiba & Mohamed Bakr Mohamed

  3. Department of Physics, College of Science, Taif University, P.O. Box 11099, Taif, 21944, Saudi Arabia

    Y. Altowairqi

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  1. A. M. El-naggar
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  2. Zein K. Heiba
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  4. Y. Altowairqi
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  5. Mohamed Bakr Mohamed
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Correspondence to Zein K. Heiba or Mohamed Bakr Mohamed.

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El-naggar, A.M., Heiba, Z.K., Kamal, A.M. et al. Enhancing the linear and nonlinear optical properties by ZnS/V-doped polyvinyl alcohol/carboxymethyl cellulose/polyethylene glycol polymeric nanocomposites for optoelectronic applications. J Mater Sci: Mater Electron 33, 25127–25138 (2022). https://doi.org/10.1007/s10854-022-09217-2

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