Abstract
Temperature stable microwave dielectric ceramics CoZrNb2O8-xCaTiO3 (x = 1/60 ~ 1/10) were fabricated by a solid-state technique. The phase formation and sintering behavior were detected for the purpose of structure–property relationship exploration. Appropriate rate of CaTiO3 addition was benefit to the sintering temperature decrease of CoZrNb2O8. From x = 1/50 to x = 1/10, unexpected CaNb2O6 and Ti2Nb10O29 phases both formed, consequent on the chemical reaction between CoZrNb2O8 and CaTiO3. Co-based oxide might separate out in the form of liquid phase and decrease the sintering temperature. Increasing CaTiO3 ration degraded the quality factor Q × f, but at the same time enhanced the dielectric constant εr and temperature coefficient of resonant frequency τf. According to the Lichtenecker mixing rule, the estimated microwave dielectric properties basically agreed well with the measured values at first. However, excessive CaTiO3 incorporation caused lattice defects and gave noticeable deviation. In current work, CoZrNb2O8-1/40CaTiO3 composite displayed a rather small τf with Q × f= 64,600 GHz at 1225 °C.
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References
M.T. Sebastian, R. Ubic, H. Jantunen, Microwave Materials and Applications (Wiley, UK, 2017).
B. Li, W. Liu, H.S. Leng, Effect of non-stoichiometry on the microstructure and microwave dielectric properties of Ca5Mg4+xV6O24 (-0.05≤x≤0.15) ceramics. J. Mater. Sci. 55, 3795–3802 (2020)
C.L. Huang, M.H. Weng, Improved high Q value of MgTiO3-CaTiO3 microwave dielectric ceramics at low sintering temperature. Mater. Res. Bull. 36, 2741–2750 (2001)
X.M. Chen, Y. Suzuki, N. Sato, Sinterability improvement of Ba(Mg1/3Ta2/3)O3 dielectric ceramics. J. Mater. Sci. Mater. Electron. 5, 244–247 (1994)
D.J. Kim, J.W. Hahn, G.P. Han, S.S. Lee, T.G. Choy, Effects of alkaline-earth-metal addition on the sinterability and microwave characteristics of (Zr, Sn)TiO4 dielectrics. J. Am. Ceram. Soc. 83, 1010–1012 (2000)
A. Baumgarte, R. Blachnik, New M2+M4+Nb2O8 phases. J. Alloys Compd. 215, 117–120 (1994)
R. Xiang, H. Su, Q. Zhang, Y.X. Li, X.L. Tang, Crystal structure and improved microwave dielectric properties of ZnZr(1–x)TixNb2O8 ceramics. J. Mater. Sci. Mater. Electron. 31, 4769–4779 (2020)
Y. Cheng, R.Z. Zuo, Y. Lv, Preparation and microwave dielectric properties of low-loss MgZrNb2O8 ceramics. Ceram. Int. 39, 8681–8685 (2013)
P. Zhang, Y.G. Zhao, H.T. Wu, Bond ionicity, lattice energy, bond energy and microwave dielectric properties of ZnZr(Nb1-xAx)2O8 (A=Ta, Sb) ceramics. Dalton Trans. 44, 16684–16693 (2015)
X.S. Lyu, L.X. Li, S. Zhang, A new low-loss dielectric material ZnZrTa2O8 for microwave devices. J. Eur. Ceram. Soc. 36, 931–935 (2016)
X.S. Lyu, L.X. Li, H. Sun, S. Zhang, S. Li, High-Q microwave dielectrics in wolframite magnesium zirconium tantalite ceramics. Ceram. Int. 42, 2036–2040 (2016)
Y.J. Lin, S.F. Wang, B.C. Lai, Y.X. Liu, Y.L. Chang, J.R. Yang, Densification, microstructure evolution, and microwave dielectric properties of Mg1-xCaxZrTa2O8 ceramics. J. Eur. Ceram. Soc. 37, 2825–2831 (2017)
Y. Zhang, Y.C. Zhang, M.Q. Xiang, Crystal structure and microwave dielectric characteristics of Zr-substituted CoTiNb2O8 ceramics. J. Eur. Ceram. Soc. 36, 1945–1951 (2016)
S.D. Ramarao, V.R.K. Murthy, Crystal structure refinement and microwave dielectric properties of new low dielectric loss AZrNb2O8 (A: Mn, Zn, Mg and Co) ceramics. Scr. Mater. 69, 274–277 (2013)
H.Y. Yang, S.R. Zhang, Y.P. Li, H.C. Yang, S.Y. Yang, T.L. Wen, E.Z. Li, Investigations of dielectric properties of wolframite A0.5Zr0.5NbO4 ceramics by bond theory and far-infrared spectroscopy. Ceram. Int. 46, 3688–3694 (2020)
H.T. Wu, E.S. Kim, Characterization of crystal structure and microwave dielectric properties of AZrNb2O8 (A=Zn Co, Mg, Mn) ceramics based on complex bond theory. Ceram. Int. 42, 5785–5791 (2016)
J.X. Bi, C.F. Xing, X.S. Jiang, C.H. Yang, H.T. Wu, Low temperature sintering and microwave dielectric properties of CoZrNb2O8 ceramics with H3BO3 addition. J. Mater. Sci. Mater. Electron. 27, 6564–6569 (2016)
Z.B. Feng, C.F. Xing, J.X. Bi, X.S. Jiang, H.T. Wu, Sintering characteristics and microwave dielectric properties of low loss CoZrNb2O8 ceramics achieved by reaction sintering process. J. Alloys Compd. 686, 923–929 (2016)
P.L. Wise, I.M. Reaney, W.E. Lee, T. Price, D.M. Iddles, D. Cannell, Structure-microwave property relations in (SrxCa1-x)n+1TinO3n+1. J. Eur. Ceram. Soc. 21, 1723–1726 (2001)
Y. Yuan, S.R. Zhang, X.H. Zhou, L.C. Xiang, Investigation on the synthesis of (Zn1-xMgx)TiO3 and the modulation effect of CaTiO3. J. Mater. Sci. Mater. Electron. 19, 343–347 (2008)
W. Wang, L.Y. Li, S.M. Xiu, B. Shen, Microwave dielectric properties of (Mg0.4Zn0.6)2SiO4-CaTiO3 ceramics sintered with Li2CO3-H3BO3 for LTCC technology. J. Alloys Compd. 639, 359–364 (2015)
F.F. Ning, L. Gan, S.F. Yuan, Z.M. Qi, J. Jiang, T.J. Zhang, Correlation between vibrational modes of A-site ions and microwave dielectric properties in (1–x)CaTiO3-x(Li0.5Sm0.5)TiO3 ceramics. J. Alloys Compd. 729, 742–748 (2017)
Y. Kobayashiy, M. Katoh, Microwave measurement of dielectric properties of low-loss materials by the dielectric rod resonator method. IEEE Trans. Microw. Theory 33, 586–592 (1985)
L.X. Li, H. Sun, X.S. Lv, S. Li, Microstructure and microwave dielectric characteristics of the CaxZn1-xTiNb2O8 temperature stable ceramics. J. Mater. Sci. Mater. Electron. 27, 126–133 (2016)
P. Zhang, T. Wang, W.S. Xia, L.X. Li, Microwave dielectric properties of a new ceramic system NdNbO4 with CaF2 addition. J. Alloys Compd. 535, 1–4 (2012)
A. Manan, Y. Iqbal, I. Qazi, Phase, microstructural characterization and dielectric properties of Ca-substituted Sr5Nb4TiO17 ceramics. J. Mater. Sci. 46, 3415–3423 (2011)
X.J. Chua, J. Luxa, A.Y.S. Eng, S.M. Tan, Z. Sofer, M. Pumera, Negative electrocatalytic effects of p-doping niobium and tantalum on MoS2 and WS2 for the hydrogen evolution reaction and oxygen reduction reaction. ACS Catal. 6, 5724–5734 (2016)
J.J. Wang, G.Y. Xiao, T.Q. Zhang, S. Hao, Z.Q. Jia, Y.L. Li, Fabrication of Co3O4/polyaniline-based carbon electrode for high-performance supercapacitor. J. Alloys Compd. (2020). https://doi.org/10.1016/j.jallcom.2020.158071
W.J. Luo, L.X. Li, S.H. Yu, B. Zhang, J.L. Qiao, Raman, EPR and structural studies of novel CuZrNb2O8 ceramic for LTCC applications. Ceram. Int. 45, 15314–15319 (2019)
G.L. Song, Y.C. Song, J. Su, K. Zhang, L.Y. Xing, H.G. Yang, N. Zhang, High temperature dielectric properties and magnetic behavior of K1-xCaxNbO3 ceramic. Phys. B 602, 412593 (2021)
I. Bertóti, M. Mohai, J.L. Sullivan, S.O. Saied, Surface characterisation of plasma-nitrided titanium: an XPS study. Appl. Surf. Sci. 84, 357–371 (1995)
Z.W. Zhang, L. Fang, H.C. Xiang, M.Y. Xu, Y. Tang, H. Jantunen, C.C. Li, Structural, infrared reflectivity spectra and microwave dielectric properties of the Li7Ti3O9F ceramic. Ceram. Int. 45, 10163–10169 (2019)
Y.Z. Hao, H. Yang, G.H. Chen, Q.L. Zhang, Microwave dielectric properties of Li2TiO3 ceramics doped with LiF for LTCC applications. J. Alloys Compd. 552, 173–179 (2013)
R.C. Pullar, J. Breeze, N.M.N. Alford, Characterization and microwave dielectric properties of M2+Nb2O6 ceramics. J. Am. Ceram. Soc. 88, 2466–2471 (2005)
W.S. Kim, T.H. Kim, E.S. Kim, K.H. Yoon, Microwave dielectric properties and far infrared reflectivity spectra of the (Zr0.8Sn0.2)TiO4 ceramics with additives. J. Jpn. Appl. Phys. 37, 5367–5371 (1998)
S.J. Penn, N.M. Alford, A. Templeton, X.R. Wang, M.S. Xu, M. Reece, K. Schrapel, Effect of porosity and grain size on the microwave dielectric properties of sintered alumina. J. Am. Ceram. Soc. 80, 1885–1888 (1997)
S.H. Wu, G.Q. Wang, Y.S. Zhao, H. Su, BaO-TiO2 microwave ceramics. J. Eur. Ceram. Soc. 23, 2565–2568 (2003)
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This work was supported by the National Natural Science Foundation of China (51902268), the Sichuan Science and Technology Program (2019YFG0234).
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Zhang, Y., Jiang, X., Ding, S. et al. Microwave dielectric property adjustment of CoZrNb2O8 ceramics by CaTiO3 addition. J Mater Sci: Mater Electron 32, 12661–12670 (2021). https://doi.org/10.1007/s10854-021-05901-x
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DOI: https://doi.org/10.1007/s10854-021-05901-x