Abstract
Selective laser ablation (SLA) of silver (Ag) films, which were deposited on glass substrates by radio frequency (RF) magnetron sputtering, was performed by using a 532 nm nanosecond (ns) pulsed laser. Two kinds of simple and mask-free SLA strategies featured by two new scanning paths (i.e. frame-typed serial scanning, FTSS, and frame-line combined scanning, FLCS) were proposed to improve the edge quality and optical transmittances of the SLA patterns. The effects of laser scanning speed (v), hatch distance (HD) and scanning path on edge quality of the laser-ablated grooves and SLA patterns were systematically studied. The results indicated that compared with the conventional line-typed cyclic scanning (LTCS) path, which resulted in unsmooth edge with semicircle-shaped boundaries and some Ag residues, the proposed scanning paths of FTSS and FLCS produced clean and smooth edges without obvious heat-affected zone and Ag residues under the condition of using a v value of 15 mm/s and an HD value of 90 μm. As a result, the as-obtained SLA patterns exhibited relatively high optical transmittances. The simple methods of adopting the FTSS or FLCS path for improving the edge quality during SLA and thus the optical transmittance of SLA patterns may have great potential application in various fields.
Similar content being viewed by others
References
C.J. Hayden, C. Dalton, Direct patterning of microelectrode arrays using femtosecond laser micromachining. Appl. Surf. Sci. 256, 3761–3766 (2010)
S. Liébana, L.J. Jones, G.A. Drago, R.W. Pittson, D. Perrie, J.P. Hart, Design and development of novel screen-printed microelectrode and microbiosensor arrays fabricated using ultrafast pulsed laser ablation. Sens. Actuators, B 231, 384–392 (2016)
H. Yu, H. Lee, J. Lee, H. Shin, M. Lee, Laser-assisted patterning of solution-processed oxide semiconductor thin film using a metal absorption layer. Microelectron. Eng. 88, 6–10 (2011)
T. Hassinen, T. Ruotsalainen, P. Laakso, R. Penttilä, H.G.O. Sandberg, Roll-to-roll compatible organic thin film transistor manufacturing technique by printing, lamination, and laser ablation. Thin Solid Films 571, 212–217 (2014)
K. Zhao, Z.Y. Jia, J.W. Ma, W. Liu, L. Wang, Nanosecond multi-pulse laser milling for certain area removal of metal coating on plastics surface. Opt. Lasers Eng. 63, 58–69 (2014)
N. Farid, H. Chan, D. Milne, A. Brunton, G.M. O’Connor, Stress assisted selective ablation of ITO thin film by picosecond laser. Appl. Surf. Sci. 427, 499–504 (2018)
P.V.D. Weijer, P.C.P. Bouten, H. Fledderus, R.R. Janssen, S.H.P.M.D. Winter, H.B. Akkerman, Mechanistic study on black and grey spot growth in OLEDs performed on laser-ablated pinholes in the cathode. Org. Electron. 42, 59–65 (2017)
D. Walter, A. Fell, E. Franklin, D. Wang, K. Fong, K. Teng, K. Weber, A.W. Blakers, Damage-free ultraviolet nanosecond laser ablation for high efficiency back contact solar cell fabrication. Sol. Energy Mater. Sol. Cells 136, 1–10 (2015)
S. Harrison, O. Nos, G. D’Alonzo, C. Denis, A. Coll, D. Munoz, Back contact heterojunction solar cells patterned by laser ablation. Energy Procedia 92, 730–737 (2016)
S. Ring, S. Kirner, C. Schultz, P. Sonntag, B. Stannowski, L. Korte, R. Schlatmann, Emitter patterning for back-contacted Si heterojunction solar cells using laser written mask layers for etching and self-aligned passivation (LEAP). IEEE J. Photovoltaics 6, 894–899 (2016)
G. Heise, M. Englmaier, C. Hellwig, T. Kuznicki, S. Sarrach, H.P. Huber, Laser ablation of thin molybdenum films on transparent substrates at low fluences. Appl. Phys. A 102, 173–178 (2011)
N. Lasemi, U. Pacher, L.V. Zhigilei, O. Bomati-Miguel, R. Lahoz, W. Kautek, Pulsed laser ablation and incubation of nickel, iron and tungsten in liquids and air. Appl. Surf. Sci. 433, 772–779 (2018)
K. Trabelsi, A. Hajjaji, I. Ka, M. Gaidi, B. Bessais, M.A.E.I. Khakani, Optoelectronic and photocatalytic properties of in situ platinum-doped TiO2 films deposited by means of pulsed laser ablation technique. J. Mater. Sci. 28, 3317–3324 (2017)
G. Heise, M. Dickmann, M. Domke, A. Heiss, T. Kuznicki, J. Palm, I. Richter, Investigation of the ablation of zinc oxide thin films on copper-indium-selenide layers by ps laser pulses. Appl. Phys. A 104, 387–393 (2011)
Y. Shi, Z. Wu, L. Du, S. Li, Y. Jiang, Effect of the thickness of Si film on Si/Se film doped silicon prepared by femtosecond laser. J. Mater. Sci. 29, 4526–4532 (2018)
G. Heise, M. Domke, J. Konrad, S. Sarrach, J. Sotrop, H.P. Huber, Laser lift-off initiated by direct induced ablation of different metal thin films with ultra-short laser pulses. J. Appl. Phys. 45, 315303 (2012)
G. Tang, A.C. Hourd, A. Abdolvand, Nanosecond pulsed laser blackening of copper. Appl. Phys. Lett. 101, 231902 (2012)
H. Yoo, H. Shin, M. Lee, Direct patterning of double-layered metal thin films by a pulsed Nd:YAG laser beam. Thin Solid Films 518, 2775–2778 (2010)
H. Lee, H. Shin, Y. Jeong, J. Moon, M. Lee, Laser-direct photoetching of metal thin film for the electrode of transistor. Appl. Phys. Lett. 95, 071104 (2009)
H. Yu, H. Shin, M. Lee, Single-step fabrication of double-layered metal thin film pattern for the electrodes of electronic devices. Curr. Appl. Phys. 11, S179–S182 (2011)
L. Romoli, M.M.A. Khan, M. Valentini, Through-the-thickness selective laser ablation of ceramic coatings on soda-lime glass. Opt. Laser Technol. 90, 113–121 (2017)
G. Tang, A. Abdolvand, Laser-assisted highly organized structuring of copper. Opt. Mater. Express 1, 1425–1432 (2011)
S. Richards, M.A. Baker, M.D. Wilson, A. Lohstroh, P. Seller, Femtosecond laser ablation of cadmium tungstate for scintillator arrays. Opt. Lasers Eng. 83, 116–125 (2016)
E. Williams, E.B. Brousseau, A. Rees, Nanosecond Yb fibre laser milling of aluminium: effect of process parameters on the achievable surface finish and machining efficiency. Int. J. Adv. Manuf. Technol. 74, 769–780 (2014)
M. Arronte, P. Neves, R. Vilar, Modeling of laser cleaning of metallic particulate contaminants from silicon surfaces. J. Appl. Phys. 92, 6973–6982 (2002)
J.M. Lee, C. Curran, K.G. Watkins, Laser removal of copper particles from silicon wafers using UV, visible and IR radiation. Appl. Phys. A 73, 219–224 (2001)
G. Vereecke, E. Rohr, M.M. Heyns, Laser-assisted removal of particles on silicon wafers. J. Appl. Phys. 85, 3837–3843 (1999)
K. Wu, Y. Xia, H.Z. Yuan, J.Y. Zhang, G. Liu, J. Sun, Cohesive and adhesive properties of nanocrystalline Ti thin films on polyimide substrates. Mater. Sci. Eng. A 744, 746–753 (2019)
H.J. Kim, K.W. Seo, H.K. Yong, J. Choi, H.K. Kim, Direct laser patterning of transparent ITO–Ag–ITO multilayer anodes for organic solar cells. Appl. Surf. Sci. 328, 215–221 (2015)
L.J. Huang, B.J. Li, N.F. Ren, Enhancing optical and electrical properties of Al-doped ZnO coated polyethylene terephthalate substrates by laser annealing using overlap rate controlling strategy. Ceram. Int. 42, 7246–7252 (2016)
A.H.A. Lutey, A. Fortunato, A. Ascari, S. Carmignato, C. Leone, Laser cutting of lithium iron phosphate battery electrodes: characterization of process efficiency and quality. Opt. Laser Technol. 65, 164–174 (2015)
J. Shi, H. Wang, D. Zhang, F. Chen, X. Yao, Femtosecond laser directly writing microholes in Bi(Nb0.998V0.002)O4 ceramic and multi-photon induced large scale nanometer wires array. J. Mater. Sci. 22, 1–5 (2011)
G. Tang, A. Abdolvand, Structuring of titanium using a nanosecond-pulsed Nd:YVO4 laser at 1064 nm. Int. J. Adv. Manuf. Technol. 66, 1769–1775 (2013)
P. Knotek, J. Navesnik, T. Cernohorsky, M. Kincl, M. Vlcek, L. Tichy, Ablation of (GeS2)0.3(Sb2S3)0.7 glass with an ultra-violet nano-second laser. Mater. Res. Bull. 64, 42–50 (2015)
B.Y. Wu, P. Liu, J. Duan, L.M. Deng, X.Y. Zeng, X.Z. Wang, Study on picosecond pulse laser ablation of Cr12MoV cold work mold steel. Mater. Des. 110, 549–557 (2016)
C.C. Yang, Y.C. Lin, C.C. Yang, Y.H. Lin, K.C. Huang, K.M. Lin, W.T. Hsiao, Laser-induced coloring of titanium alloy using ultraviolet nanosecond pulses scanning technology. J. Alloys Compd. 715, 349–361 (2017)
A. Latif, M.S. Rafiq, K.A. Bhatti, A. Perveen, Crater geometry and morphological changes on gold sheet during laser microdrilling. Int. J. Adv. Manuf. Technol. 85, 2847–2855 (2016)
P. Umenne, V.V. Srinivasu, Femtosecond-laser fabrication of micron and sub-micron sized S-shaped constrictions on high T c superconducting YBa2Cu3O7−x thin films: ablation and lithography issues. J. Mater. Sci. 28, 5817–5826 (2017)
F. Abrinaei, M. Shirazi, Nonlinear optical investigations on Al doping ratio in ZnO thin film under pulsed Nd:YAG laser irradiation. J. Mater. Sci. 28, 17541–17550 (2017)
M.A. Morsi, A. Rajeh, A.A. Menazea, Nanosecond laser-irradiation assisted the improvement of structural, optical and thermal properties of polyvinyl pyrrolidone/carboxymethyl cellulose blend filled with gold nanoparticles. J. Mater. Sci. 30, 2693–2705 (2019)
H.Y. Kim, J.W. Yoon, W.S. Choi, K.R. Kim, S.H. Cho, Ablation depth control with 40 nm resolution on ITO thin films using a square, flat top beam shaped femtosecond NIR laser. Opt. Lasers Eng. 84, 44–50 (2016)
A. Sonal, S. Sharma, Aggarwal, Optical investigation of soda lime glass with buried silver nanoparticles synthesised by ion implantation. J. Non-Cryst. Solids 485, 57–65 (2018)
B.J. Li, G.Y. Yang, L.J. Huang, W. Zu, H. Li, Y.L. Wang, S.S. Li, N.F. Ren, Surface morphology and photoelectric properties of FTO ceramic thin films under a simple transparent cover-assisted laser annealing. Mater. Res. Bull. 108, 151–155 (2018)
L.J. Huang, N.F. Ren, B.J. Li, M. Zhou, Improvement in overall photoelectric properties of Ag/FTO bilayer thin films using furnace/laser dual annealing. Mater. Lett. 116, 405–407 (2014)
B.J. Li, H. Li, L.J. Huang, H.D. Cao, W. Zu, N.F. Ren, H. Ding, X. Kong, J.L. Zhang, Performance optimization of fluorine-doped tin oxide thin films by introducing ultrasonic vibration during laser annealing. Ceram. Int. 43, 7329–7337 (2017)
J. Huang, X. Liu, Y. Lu, Y. Zhou, J. Xu, J. Li, H. Wang, J. Fang, Y. Yang, W. Wang, R. Tan, W. Song, Seed-layer-free growth of ultra-thin Ag transparent conductive films imparts flexibility to polymer solar cells. Sol. Energy Mater. Sol. Cells 184, 73–81 (2018)
R.P. Domingues, M.S. Rodrigues, M. Proença, D. Costa, E. Alves, N.P. Barradas, F.J. Oliveira, R.F. Silva, J. Borges, F. Vaz, Thin films composed of Au nanoparticles embedded in AlN: influence of metal concentration and thermal annealing on the LSPR band. Vacuum 157, 414–421 (2018)
Acknowledgements
This work was funded by the National Natural Science Foundation of China (Grant Nos. 51805220 and 61405078), the Natural Science Foundation of Jiangsu Province of China (Grant No. BK20140567) and the Jiangsu University Study-abroad Fund (Reference No. UJS-2017-013). The authors would like to thank the support of the Young Backbone Teacher Cultivating Project of Jiangsu University.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Li, B., Li, H., Huang, L. et al. Improving edge quality and optical transmittance of Ag films on glass substrates by selective nanosecond pulsed laser ablation using various scanning methods. J Mater Sci: Mater Electron 30, 13729–13739 (2019). https://doi.org/10.1007/s10854-019-01755-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-01755-6