Abstract
Potentially, active nickel stannate (NiSnO3)/graphene nanosheets (GNS) composite was prepared using facile hydrothermal method. From XRD analysis, the average crystallite size of NiSnO3 nanoparticles and NiSnO3/GNS nanocomposite was found to be 5 and 3 nm, respectively. XPS analysis revealed chemical species and oxidation state of elements present on the surface of the samples. HRSEM analysis showed the formation of elongated shape of NiSnO3/graphene nanocomposite with size of ~ 6 nm. Moreover, the internal structure and interactions between stannate and graphene were examined using transmission electron microscope analysis. BET analysis revealed the significant increase in surface area of 162 m2/g in NiSnO3/GNS nanocomposite, whereas bare NiSnO3 nanoparticles showed 101 m2/g. Electrochemical performance of bare NiSnO3 and NiSnO3/GNS nanocomposite was studied using cyclic voltammetry and charge–discharge techniques. Cyclic voltammetry of NiSnO3/GNS resulted in maximum specific capacitance of 891 F/g at a scan rate of 5 mV/s which is higher than that of NiSnO3 alone 570 F/g at same scan rate. Electrochemical impedance spectra show negligible charge transfer resistance of 1.6 and 1.5 Ω for NiSnO3 and NiSnO3/GNS, respectively. Enhancement in the electrochemical performance of NiSnO3/GNS is mainly due to graphene incorporation which provided high surface area, thereby offering high interfacial sites, electrical conductivity and improved redox activity. Further, an asymmetric supercapacitor was constructed using NiSnO3/GNS nanocomposite and activated carbon acted as positive and negative electrodes within an operating potential window of 0–0.8 V. Fabricated asymmetric device delivered a high energy density of 42.54 Wh/kg at a power density of 0.34 kW/kg. Moreover, this device exhibited excellent charge–discharge cycling stability with 88.3% capacitance retention even after 4000 cycles.
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References
Moreno-Fernandez G, Ibanez J, Rojo JM, Kunowsky M (2017) Activated carbon fiber monoliths as supercapacitor electrodes. Adv Mater Sci Eng Volume 2017, Article ID 3625414. https://doi.org/10.1155/2017/3625414
Zhu Y, Ji X, Wu Z, Song W, Hou H, Wu Z, He X, Chen Q, Banks CE (2014) Spinel NiCo2O4 for use as a high-performance supercapacitor electrode material: understanding of its electrochemical properties. J Power Sources 267:888–900
Simon P, Gogotsi Y (2008) Materials for electrochemical capacitors. Nat Mater 7:845–854
Li Y, Tang F, Wang R, Wang C, Liu J (2016) A novel dual-ion hybrid supercapacitor based on NiCo2O4 nanowire cathode and MoO2–C nanofilm anode. ACS Appl Mater Interfaces 8(44):30232–30238
Bhisel SC, Awale DV, Vadiyar MM, Patil SK, Kokare BN, Kolekar SS (2017) Facile synthesis of CuO nanosheets as electrode for supercapacitor with long cyclic stability in novel methyl imidazole-based ionic liquid electrolyte. J Solid State Electrochem 21:2585–2591
Cheng Z, Pengfei Z, Sheng D, De-en J (2016) Boron supercapacitors. ACS Energy Lett 1:1241–1246
Maheswari N, Muralidharan G (2015) Supercapacitor behaviour of cerium oxide nanoparticles in neutral aqueous electrolytes. ACS Energy Fuels 29:8246–8253
Zhang J, Li L, Su H, Huang W, Dong X (2015) Binary metal oxide: advanced energy storage materials in supercapacitors. J Mater Chem A 3:43–59
Zhang J, Liu F, Cheng JP, Zhang NB (2015) Binary Nickel–Cobalt oxides electrode materials for high-performance supercapacitors: influence of its composition and porous nature. ACS Appl Mater Interfaces 7:17630–17640
Sung Lee M-T, Chang J-K, Hsieh Y-T, Tsai W-T (2008) Annealed Mn–Fe binary oxides for supercapacitor applications. J Power Sources 185:1550–1556
Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon J-M (2000) Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407:496–499
Yan L, Zhong-yang L, Chun-jiang Y, Dan L, Zhu-an X, Ke-fa C (2005) The impact of NiO on microstructure and electrical property of solid oxide fuel cell anode. J Zhejiang Univ Sci 6B(11):1124–1129
Dirksen JA, Duval K, Ring TA (2001) NiO thin-film formaldehyde gas sensor. Sens Actuators B 80:106–115
Hotovya I, Rehaceka V, Sicilianob P, Caponec S, Spiessd L (2002) Sensing characteristics of NiO thin films as NO2 gas sensor. Thin Solid Films 418:9–15
Xiao H, Yao S, Liu H, Qu F, Zhang X, Wu X (2016) NiO nanosheet assembles for supercapacitor electrode materials. Prog Nat Sci Mater Int 26:271–275
Vijayakumar S, Nagamuthu S, Muralidharan G (2013) Supercapacitor studies on NiO nanoflakes synthesized through a microwave route. ACS Appl Mater Interfaces 5:2188–2196
Kim S, Lee J-S, Ahn H-J, Song H-K, Jang J-H (2013) Facile route to an efficient NiO supercapacitor with a three-dimensional nanonetwork morphology. ACS Appl Mater Interfaces 5:1596–1603
Xiao H, Qu F, Wu X (2016) Ultrathin NiO nanoflakes electrode materials for supercapacitors. Appl Surf Sci 360:8–13
Yu W, Li BQ, Ding SJ (2016) Electroless fabrication and supercapacitor performance of CNT@ NiO-nanosheet composite nanotubes. IOP Nanotechnol 27:075605
Singh AK, Janotti A, Scheffler M, Van de Wallel CG (2008) Sources of electrical conductivity in SnO2. Phys Rev Lett 101:055502
Naje AN, Norry AS, Suhail AM (2013) Preparation and characterization of SnO2 nanoparticles. IJIRSET 2:7068–7072
Xue H, Zhao J, Taang J, Gong H, De P, Zhou H, Yamauchi Y, He J (2016) High-loading nano-SnO2 encapsulated in situ in three-dimensional rigid porous carbon for superior lithium-ion batteries. Chem Eur J 22:4915–4923
Das S, Jayaraman V (2014) SnO2: a comprehensive review on structures and gas sensors. Prog Mater Sci 66:112–255
Dubow JB, Burk DE (2005) Solar cells of indium tin oxide on silicon. IEEE Xplore Digit Libr 10(7):230–232
Dipak SV, Deok Yeon L, Supriya AP, Isuel L, Sambhaji BS, Wonjoo L, Myung SM, Rajaram MS, Nabeen SK, Sung-Hwan H (2013) Anodically fabricated self-organized nanoporous tin oxide film as a supercapacitor electrode material. RSC Adv 3:9431–9435
Yadav A (2016) Spray deposition of tin oxide thin films for supercapacitor applications: effect of solution molarity. J Mater Sci Mater Electron 27:6985–6991
Moghadama LN, Salavati-Niasari M (2017) Facile synthesis and characterization of NiO–SnO2 ceramic nanocomposite and its unique performance in organic pollutants degradation. J Mol Struct 1146:629–634
Mohd Faiz H, Rahman MM, Zaiping G, Zhixin C, Huakun L (2010) SnO2–NiO–C nanocomposite as a high capacity anode material for lithium-ion batteries. J Mater Chem 20:9707–9712
Petronela P, Anton A, Niculae O, Iulian P, Valentin N, Liviu S, Florin T (2016) Microstructure, electrical and humidity sensor properties of electrospun NiO–SnO2 nanofibers. Sens Actuators 222:1024–1031
Yude W, Xiaodan S, Yanfeng L, Zhenlai Z, Xinghui W (2000) Perovskite-type NiSnO3 used as the ethanol sensitive material. Solid State Electron 44:2009–2014
Mhamdi A, Dridi R, Arfaoui A, Awada C, Karyaoui M, Velasco-Davalos IA, Ruediger A, Amlouk M (2015) Structural, surface morphology and optical properties of NiSnO3 thin films prepared using spray technique. Opt Mater 47:386–390
Li X, Wang C (2012) Significantly increased cycling performance of novel “self-matrix” NiSnO3 anode in lithium ion battery application. RSC Adv 2:6150–6154
Fu L, Song K, Li X, Van Peter A, Aken C, Wang J, Maier YYu (2014) Direct evidence of a conversion mechanism in a NiSnO3 anode for lithium ion battery application. RSC Adv 4:36301–36306
Umeshbabu E, Rajeshkhannal G, Ranga Rao G (2015) Effect of solvents on the morphology of NiCo2O4/graphene nanostructures for electrochemical pseudocapacitor application. J Solid State Electrochem 20:1837–1844
Bhoyate S, Mensah-Darkwa K, Kahol PK, Gupta RK (2017) Recent development on nanocomposites of graphene for supercapacitor applications. Curr Graphene Sci 1:26–43
Junbo H, Yuyan S, Michael EW, Robert MB, Baolian Y (2011) Graphene-based electrochemical energy conversion and storage: fuel cells, supercapacitors and lithium ion batteries. Phys Chem Chem Phys 13:15384–15402
Russo P, Hu A, Compagnini G (2013) Synthesis, properties and potential applications of porous graphene: a review. Nano-Micro Lett 5:260–273
Wu C, Deng S, Wang H, Sum Y, Liu J, Yan H (2014) Preparation of novel three-dimensional NiO/ultrathin derived graphene hybrid for supercapacitor applications. ACS Appl Mater Interfaces 6:1106–1112
Velmurugana V, Srinivasaraoa Y, Ramachandrana R, Saranyaa M, Santhosh C, Grace AN (2016) Synthesis of tin oxide/graphene (SnO2/G) nanocomposite and its electrochemical properties for supercapacitor applications. Mater Res Bull 84:145–151
Li C, Liu S, Liu L (2012) Preparation and characterization of flower like nickel oxide. Appl Mech Mater 121–126:1044–1048
Alagiri M, Ponnusamy S, Muthamizhchelvan C (2012) Synthesis and characterization of NiO nanoparticles by sol–gel method. J Mater Sci Mater Electron 23:728–732
Xu J, Li Y, Huang H, Zhu Y, Wang Z, Xie Z, Wang X, Chen D, Shen G (2011) Synthesis, characterizations and improved gas-sensing performance of SnO2 nanospike arrays. J Mater Chem 21:19086–19092
Chen J, Zou M, Li J, Wen W, Jiang L, Chen L, Feng Q, Huang Z (2016) NiSnO3 nanoparticles/reduced graphene oxide composite with enhanced performance as lithium-ion battery anode material. RSC Adv 6:85374–85380
Johra FT, Lee JW, Jung WG (2014) Facile and safe graphene preparation on solution based platform. J Ind Eng Chem 20:2883–2887
Khorsand ZA, Abd Majid WH, Abrishami ME, Yousefi R (2011) X-ray analysis of ZnO nanoparticles by Williamson–Hall and size-strain plot methods. Solid State Sci 13:251–256
Anitha SN, Jayakumari I (2015) Synthesis and analysis of noncrystalline Fe2Mn2Ni0.5Zn1.5O9 at different treating temperatures. J Nanosci Technol 1:26–31
Naveen AN, Selladurai S (2016) Novel synthesis of highly porous three-dimensional nickel cobaltite for supercapacitor applications. Ionics 22:1471–1483
Rajender G, Giri PK (2016) Strain induced phase formation, microstructural evolution and bandgap narrowing in strained TiO2 nanocrystals grown by ball milling. J Alloys Compd 676:591–600
Chen H-L, Lu Y-M, Hwang W-S (2005) Effect of film thickness on structural and electrical properties of sputter-deposited nickel oxide films. Mater Trans 46:872–879
Bushroa AR, Rahbari RG, Masjuki HH, Muhamad MR (2012) Approximation of crystallite size and microstrain via XRD line broadening analysis in TiSiN thin films. Vacuum 86:1107–1112
Basharata F, Ranab UA, Shahida M, Serwar M (2015) Heat treatment of electrodeposited NiO films for improved catalytic water oxidation. RSC Adv 5:86713–86722
Anna Paola C, Armando L, Roberto R (2009) Nanoparticle thin films for gas sensors prepared by matrix assisted pulsed laser evaporation. Sensors 9:2682–2696
Carlos Sergio F, Pamyla Layene S, Juliano Alves B, Raimundo Ribeiro P, Leandro Aparecido P (2015) Rice husk reuse in the preparation of SnO2/SiO2 nanocomposite. Mater Res 18:639–643
Tan L, Wang L, Wang Y (2011) Hydrothermal synthesis of SnO2 nanostructures with different morphologies and their optical properties. J Nanomater 23:1–10
Gunasekaran S, Rajkumar R (2003) Fourier transform infrared spectrum and normal coordinate analysis of chloroxylenol. Indian J Pure Appl Phys 41:839–843
Zhao Y, Frost RL, Yang J, Martens WN (2008) Size and morphology control of Gallium oxide hydroxide GaO(OH), Nano- to micro-sized particles by soft-chemistry route without surfactant. J Phys Chem C 112:3568
Mansour AN (1994) Characterization of NiO by XPS. Surf Sci Spectra 3:231–238
Stranick MA, Moskwa A (1993) SnO2 by XPS. Surf Sci Spectra 2:50–54
Huang Y-L, Tien H-W, Ma C-CM, Yang S-Y, Wu S-Y, Liu H-Y, Mai Y-W (2011) Effect of extended polymer chains on properties of transparent graphene nanosheets conductive film. J Matter Chem 21:18236–18241
Wang DH, Hu Y, Zhao JJ, Zeng LL, Taob XM, Chen W (2014) Holey reduced graphene oxide nanosheets for high performance room temperature gas sensing. J Mater Chem A 2:17415–17420
Padmanathan N, Selladurai S (2014) Electrochemical capacitance of porous NiO–CeO2 binary oxide synthesized via sol–gel technique for supercapacitor. Ionics 20:409–420
Naveen AN, Selladurai S (2016) Novel synthesis of highly porous three-dimensional nickel cobaltite for supercapacitor application. Ionics 22:1471–1483
Matthew PY, Dong S, Nebojsa SM, Xiaowei T (2012) Pseudocapacitive NiO fine nanoparticles for supercapacitor reactions. J Electrochem Soc 159:A1598–A1603
Li-Qiang M, Aamir Minhas K, Xiaocong T, Kalele Mulonda H, Yun-Long Z, Xu L, Xu X (2013) Synergistic interaction between redox-active electrolyte and binder-free functionalized carbon for ultrahigh supercapacitor performance. Nat Commun 4:2923
Pandit B, Dubal DP, Sankapal B (2017) Large scale flexible solid state symmetric supercapacitor through inexpensive solution processed V2O5 complex surface architecture. Electrochim Acta 242:382–389
Chen PC, Shen G, Shi Y, Chen H, Zhou C (2010) Preparation and characterization of flexible asymmetric supercapacitors based on transition-metal-oxide nanowire/single-walled carbon nanotube hybrid thin-film electrodes. ACS Nano 4:4403–4411
Cottineau T, Toupin M, Delahaye T, Brousse T, Belanger D (2006) Nanostructured transition metal oxides for aqueous hybrid electrochemical supercapacitors. Appl Phys A 82:599–606
Ma W, Chen S, Yang S, Chen W, Weng W, Cheng Y, Zhu M (2017) Flexible all-solid-state asymmetric supercapacitor based on transition metal oxide nanorods/reduced graphene oxide hybrid fibers with high energy density. Carbon 113:151–158
Singh A, Chandra A (2015) Significant performance enhancement in asymmetric supercapacitors based on metal oxides, carbon nanotubes and neutral aqueous electrolyte. Sci Rep 5:15551
Li Q, Li Y, Peng H, Cui X, Zhou M, Feng K, Xiao P (2016) Layered NH4CoxNi1−xPO4·H2O (0 ≤ x ≤ 1) nanostructures finely tuned by Co/Ni molar ratios for asymmetric supercapacitor electrodes. J Mater Sci 51:9946–9957. https://doi.org/10.1007/s10853-016-0151-x
Xu Y, Xuan H, Gao J, Liang T, Han X, Yang J, Zhang Y, Li H, Han P, Du Y (2018) Hierarchical three-dimensional NiMoO4-anchored rGO/Ni foam as advanced electrode material with improved supercapacitor performance. J Mater Sci 53:8483–8498. https://doi.org/10.1007/s10853-018-2171-1
Li T, Wu Y, Wang Q, Zhang D, Zhang A, Miao M (2017) TiO2 crystalline structure and electrochemical performance in two-ply yarn CNT/TiO2 asymmetric supercapacitors. J Mater Sci 52:7733–7744. https://doi.org/10.1007/s10853-017-1033-6
Xu W, Mu B, Wang A (2018) All-solid-state high-energy asymmetric supercapacitor based on natural tubular fibers. J Mater Sci 53:11659–11670. https://doi.org/10.1007/s10853-018-2418-x
Acknowledgements
The authors are grateful to Dr. R.K. Sharma and Mr. U.K. Goutam, Scientific officers, RRCAT, Indore, for providing XPS analysis.
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Saranya, P.E., Selladurai, S. Facile synthesis of NiSnO3/graphene nanocomposite for high-performance electrode towards asymmetric supercapacitor device. J Mater Sci 53, 16022–16046 (2018). https://doi.org/10.1007/s10853-018-2742-1
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DOI: https://doi.org/10.1007/s10853-018-2742-1