Abstract
Novel mixed-matrix membranes based on polysulfone (PS) and fullerene C60 (up to 5 wt%) have been developed. Two membrane types formed from PS and PS-C60, a dense (diffusive) membrane and a supported membrane, consisted of a thin PS or PS-C60 selective layer (≈5 μm) on the surface of hydrophobic fluorocarbon polymer porous support (MFFC) were studied. The effect of fullerene incorporation on the structure and physical and chemical properties of PS membranes were investigated by scanning electron microscopy, nuclear magnetic resonance, contact angle measurements, sorption experiments, and wide-angle X-ray diffraction. The transport properties of the mixed matrix membranes containing up to 0.5 wt% fullerene were studied for the pervaporation of ethyl acetate–water mixture. The new mixed-matrix membranes, developed in this study, were selective to water, whereas the PS-0.5 % C60/MFFC composite membrane was found to have the best performance.
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References
Goh PS, Ismail AF (2015) Review: is interplay between nanomaterial and membrane technology the way forward for desalination? J Chem Technol Biotechnol 90:971–980. doi:10.1002/jctb.4531
Goh PS, Ismail AF, Sanip SM et al (2011) Recent advances of inorganic fillers in mixed matrix membrane for gas separation. Sep Purif Technol 81:243–264. doi:10.1016/j.seppur.2011.07.042
Hoek EMV, Ghosh AK, Huang X et al (2011) Physical-chemical properties, separation performance, and fouling resistance of mixed-matrix ultrafiltration membranes. Desalination 283:89–99. doi:10.1016/j.desal.2011.04.008
Yu J, Li L, Liu N, Lee R (2013) An approach to prepare defect-free PES/MFI-type zeolite mixed matrix membranes for CO2/N2 separation. J Mater Sci 48:3782–3788. doi:10.1007/s10853-013-7178-z
Garca MG, Marchese J, Ochoa NA (2012) High activated carbon loading mixed matrix membranes for gas separations. J Mater Sci 47:3064–3075. doi:10.1007/s10853-011-6138-8
Diallo MS, Duncan JS, Savage N et al (2014) Nanotechnology solutions for improving water quality. solutions for improving water quality a volume in micro and nano technologies. Nanotechnol Appl Clean Water. doi:10.1016/B978-1-4557-3116-9.00042-1
Cheryan M (1998) Ultrafiltration and microfiltration handbook. CRC press, Boca Raton
Chakrabarty B, Ak Ghoshal, Purkait MK (2008) SEM analysis and gas permeability test to characterize polysulfone membrane prepared with polyethylene glycol as additive. J Colloid Interface Sci 320:245–253. doi:10.1016/j.jcis.2008.01.002
Ohya H, Shiki S, Kawakami H (2009) Fabrication study of polysulfone hollow-fiber microfiltration membranes: optimal dope viscosity for nucleation and growth. J Memb Sci 326:293–302. doi:10.1016/j.memsci.2008.10.001
Chen SH, Liou RM, Lai CL et al (2008) Embedded nano-iron polysulfone membrane for dehydration of the ethanol/water mixtures by pervaporation. Desalination 234:221–231. doi:10.1016/j.desal.2007.09.089
Hunger K, Schmeling N, Jeazet HBT et al (2012) Investigation of cross-linked and additive containing polymer materials for membranes with improved performance in pervaporation and gas separation. Membranes 2:727–763. doi:10.3390/membranes2040727 (Basel)
Ismail AF, Goh PS, Sanip SM, Aziz M (2009) Transport and separation properties of carbon nanotube-mixed matrix membrane. Sep Purif Technol 70:12–26. doi:10.1016/j.seppur.2009.09.002
Wang N, Ji S, Li J et al (2014) Poly(vinyl alcohol)-graphene oxide nanohybrid “pore-filling” membrane for pervaporation of toluene/n-heptane mixtures. J Memb Sci 455:113–120. doi:10.1016/j.memsci.2013.12.023
Wang T, Shen J-N, Wu L-G, Bruggen BVD (2014) Improvement in the permeation performance of hybrid membranes by the incorporation of functional multi-walled carbon nanotubes. J Memb Sci 466:338–347. doi:10.1016/j.memsci.2014.04.054
Yeang QW, Zein SHS, Sulong AB, Tan SH (2013) Comparison of the pervaporation performance of various types of carbon nanotube-based nanocomposites in the dehydration of acetone. Sep Purif Technol 107:252–263. doi:10.1016/j.seppur.2013.01.031
Polotskaya GA, Penkova AV, Toikka AM et al (2007) Transport of small molecules through polyphenylene oxide membranes modified by fullerene. Sep Sci Technol 42:333–347. doi:10.1080/01496390600997963
Jin X, Hu JY, Tint ML et al (2007) Estrogenic compounds removal by fullerene-containing membranes. Desalination 214:83–90. doi:10.1016/j.desal.2006.10.019
Sudareva NN, Penkova AV, Kostereva TA et al (2012) Properties of casting solutions and ultrafiltration membranes based on fullerene-polyamide nanocomposites. Expr Polym Lett 6:178–188. doi:10.3144/expresspolymlett.2012.20
Polotskaya GA, Penkova AV, Pientka Z, Am Toikka (2012) Polymer membranes modified by fullerene C60 for pervaporation of organic mixtures. Desalin Water Treat 14:83–88. doi:10.5004/dwt.2010.1528
Taurozzi JS, Crock CA, Tarabara VV (2011) C60-polysulfone nanocomposite membranes: entropic and enthalpic determinants of C60 aggregation and its effects on membrane properties. Desalination 269:111–119. doi:10.1016/j.desal.2010.10.049
Martin JW (2006) Concise encyclopedia of the structure of materials. Elsevier, Philadelphia
Stephens PW (1994) Physics and chemistry of fullerenes. World Scientific, Singapore
Acknowledgements
The authors are grateful and acknowledge Grants from RFBR No. 15-58-04034 (A.V. Penkova); Grants from St. Petersburg State University (No. 12.50.1195.2014 (M.P. Sokolova), 12.42.1392.2015 (M.E. Dmitrenko); the Government of the Russian Federation Grant 074-U01 (D.A. Markelov). The experimental work was facilitated on the equipment of the Resource Center of X-ray diffraction studies and GEOMODEL, Interdisciplinary Resource center for Nanotechnology at St. Petersburg State University.
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Penkova, A.V., Dmitrenko, M.E., Sokolova, M.P. et al. Impact of fullerene loading on the structure and transport properties of polysulfone mixed-matrix membranes. J Mater Sci 51, 7652–7659 (2016). https://doi.org/10.1007/s10853-016-0047-9
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DOI: https://doi.org/10.1007/s10853-016-0047-9