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Acetone and ethanol sensing characteristics of magnesium zinc ferrite nano-particulate chemi-resistive sensor

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Abstract

In the present work, acetone and ethanol sensing characteristics of wet chemically prepared magnesium zinc ferrite (MZFO) nano-particles have been investigated. X-ray diffraction and electron microscopy studies are carried out to know the phase formation behaviour and microstructure evolution of the synthesized particles. The gas sensing characteristics (response %, response time, recovery time, etc.) are estimated by varying the operating temperature of the sensor and concentrations of the test vapours. It is observed that the nanocrystalline MZFO-based sensor is more sensitive to acetone than ethanol. In addition, the sensor can detect even 10 ppm of acetone and ethanol vapours. The excellent repeatability of the sensing performances is verified by switching the sensor back and forth between air and test vapours.

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References

  1. Kim YS, Ha SC, Yang H, Kim YT (2007) Gas sensor measurement system capable of sampling volatile organic compounds (VOCs) in wide concentration range. Sens Actuators B 122:211–218

    Article  Google Scholar 

  2. Yang M, Huo L, Zhao H, Gao S, Rong Z (2009) Electrical properties and acetone-sensing characteristics of LaNi1−x Ti x O3 perovskite system prepared by amorphous citrate decomposition. Sens Actuators B 143:111–118

    Article  Google Scholar 

  3. Wang D, Zhen Y, Xue G, Fu F, Liu X, Li D (2013) Synthesis of mesoporous Bi2WO6 architectures and their gas sensitivity to ethanol. J Mater Chem C 1:4153–4162

    Article  Google Scholar 

  4. Righettoni M, Tricoli A, Pratsinis SE (2010) Thermally stable silica-doped ε-WO3 for sensing of acetone in the human breath. Chem Mater 22:3152–3157

    Article  Google Scholar 

  5. Kapse VD, Ghosh SA, Raghuwanshi FC, Kapse SD, Khandekar US (2009) Nanocrystalline Ni0.6Zn0.4Fe2O4: a novel semiconducting material for ethanol detection. Talanta 78:19–25

    Article  Google Scholar 

  6. Wagner T, Haffer S, Weinberger C, Klaus D, Tiemann M (2013) Mesoporous materials as gas sensors. Chem Soc Rev 42:4036–4053

    Article  Google Scholar 

  7. Kim HR, Choi KI, Kim KM, Kim ID, Cao G, Lee JH (2010) Ultra-fast responding and recovering C2H5OH sensors using SnO2 hollow spheres prepared and activated by Ni templates. Chem Commun 46:5061–5063

    Article  Google Scholar 

  8. Hu P, Du G, Zhou W, Cui J, Lin J, Liu H, Liu D, Wang J, Chen S (2010) Enhancement of ethanol vapor sensing of TiO2 nanobelts by surface engineering. ACS. Appl Mater Interfaces 2:3263–3269

    Article  Google Scholar 

  9. Chen D, Hou X, Li T, Yin L, Fan B, Wang H, Li X, Xu H, Lu H, Zhang R, Sun J (2011) Effects of morphologies on acetone-sensing properties of tungsten trioxide nanocrystals. Sens Actuators B153:373–381

    Article  Google Scholar 

  10. Prajapati CS, Sahay PP (2011) Alcohol-sensing characteristics of spray deposited ZnO nano-particle thin films. Sens Actuators B 160:1043–1049

    Article  Google Scholar 

  11. Franke ME, Koplin TJ, Simon U (2006) Metal and metal oxide nanoparticles in chemiresistors: does the nanoscale matter? Small 2:36–50

    Article  Google Scholar 

  12. Mukherjee K, Majumder SB (2012) Synthesis process induced improvement on the gas sensing characteristics of nano-crystalline magnesium zinc ferrite particles. Sens Actuators B 162:229–236

    Article  Google Scholar 

  13. Mukherjee K, Majumder SB (2010) Hydrogen sensing characteristics of wet chemical synthesized tailored Mg0.5Zn0.5Fe2O4 nanostructures. Nanotechnology 21:255504

    Article  Google Scholar 

  14. Mukherjee K, Majumder SB (2013) Synthesis of embedded and isolated Mg0.5Zn0.5Fe2O4 nano-tubes and investigation on their anomalous gas sensing characteristics. Sens Actuators B 177:55–63

    Article  Google Scholar 

  15. Sharma A, Tomar M, Gupta V (2012) Room temperature trace level detection of NO2 gas using SnO2 modified carbon nanotubes based sensor. J Mater Chem 22:23608–23616

    Article  Google Scholar 

  16. Roy B, Chakrabarty S, Mondal O, Pal M, Dutta A (2012) Effect of neodymium doping on structure, electrical and optical properties of nanocrystalline ZnO. Mater Charact 70:1–7

    Article  Google Scholar 

  17. Sun P, Zhu Z, Zhao P, Liang X, Sun Y, Liu F, Lu G (2012) Gas sensing with hollow α-Fe2O3 urchin-like spheres prepared via template-free hydrothermal synthesis. CrystEngComm 14:8335–8337

    Article  Google Scholar 

  18. Karmakar M, Mondal B, Pal M, Mukherjee K (2014) Acetone and ethanol sensing of barium hexaferrite particles: a case study considering the possibilities of non-conventional hexaferrite sensor. Sens Actuators B 190:627–633

    Article  Google Scholar 

  19. Song P, Wang Q, Yang Z (2012) Preparation, characterization and acetone sensing properties of Ce-doped SnO2 hollow spheres. Sens Actuators B 173:839–846

    Article  Google Scholar 

  20. Sutka A, Zavickis J, Mezinskis G, Jakovlevs D, Barloti J (2013) Ethanol monitoring by ZnFe2O4 thin film obtained by spray pyrolysis. Sens Actuators B 176:330–334

    Article  Google Scholar 

  21. Lou X, Liu S, Shi D, Chu W (2007) Ethanol-sensing characteristics of CdFe2O4 sensor prepared by sol–gel method. Mater Chem Phys 105:67–70

    Article  Google Scholar 

  22. Rezlescu N, Rezlescu E, Tudorache F, Popa PD (2009) Gas sensing properties of porous Cu, Cd and Zn ferrites. Rom Rep Phys 61:223–234

    Google Scholar 

  23. Sutka A, Parna R, Mezinskis G, Kisand V (2014) Effects of Co ion addition and annealing conditions on nickel ferrite gas response. Sens Actuators B 192:173–180

    Article  Google Scholar 

  24. Sutka A, Mezinskis G, Lusis A, Stingaciu M (2012) Gas sensing properties of Zn-doped p-type nickel ferrite. Sens Actuators B 171:354–360

    Article  Google Scholar 

  25. Rezlescu E, Tudorache F, Popa PD, Rezlescu N (2008) Role of Cu2+ concentration on the microstructure and gas sensing properties of Ni1−x Cu x Fe2O4 (0 ≤ x ≤ 0.8) ferrite. Sens Transducers J 91:100–108

    Google Scholar 

  26. Rezlescu N, Doroftei C, Rezlescu E, Popa PD (2008) Lithium ferrite for gas sensing applications. Sens Actuators B 133:420–425

    Article  Google Scholar 

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Acknowledgements

The authors would like to express their gratitude to the Director, CSIR-CMERI for his kind permission to publish the paper. The support provided by Council of Scientific and Industrial Research (CSIR) and the help rendered by the scientific & technical staffs of Centre for Advanced Materials Processing (CAMP), CSIR-CMERI, Durgapur is sincerely acknowledged. M. Karmakar thanks BRNS (Project No. 2011/37P/14/BRNS) for supporting her fellowship. P. Das thanks DST, Govt of India for providing her the research fellowship. Dr. K. Mukherjee wishes to acknowledge Department of Science and Technology, Govt of India for providing him Inspire Faculty Award (Ref. DST/IFA12-CH-43).

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Karmakar, M., Das, P., Pal, M. et al. Acetone and ethanol sensing characteristics of magnesium zinc ferrite nano-particulate chemi-resistive sensor. J Mater Sci 49, 5766–5771 (2014). https://doi.org/10.1007/s10853-014-8302-4

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  • DOI: https://doi.org/10.1007/s10853-014-8302-4

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