Abstract
Pure phase, zinc ferrite (ZnFe2O4) nanoparticles were synthesized at lower temperature (80 °C) by auto combustion synthesis method. The resulting ‘as synthesized’ powder was heat treated (HT) at 560 °C for 2 h in air atmosphere. As-synthesized particles had sizes ~10 nm with spherical shape. Further, these spherically shaped nanoparticles tended to change their morphology to hexagonal plate shape with increasing HT temperature. The band gap of the ‘as synthesized’ and HT zinc ferite, as determined by using UV–Vis spectroscopy were found to be 1.92 and 1.86 eV respectively. Gas responses of the ZnFe2O4 nanoparticles were measured by exposing them to ethanol gas vapors. It was found that the zinc ferrite nanoparticles exhibited various sensing responses to ethanol gas at different operating temperature. The best sensitivity was observed at low temperature for ‘as synthesized’ ferrite nanoparticles than HT zinc ferrite nanoparticles. Sensing material that had smaller particle size and larger specific surface area was observed to have larger gas sensitivity and vice-versa.
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References
Gadkari A B, Shinde T J, and Vasambekar P N, IEEE Sens J, 11 (2011) 849.
Jiang Y, Song W, Xie C, Wang A, Zeng D, and Hu M, Mater Lett 60 (2006) 1374.
Chen N S, Yang X J, Liu E S, and Huang, J L, Sens Actuators B 66 (2000) 178.
Kapse V D, Ghosh S A, Raghuwanshi F C, and Kapse S D, Chem Phys 113 (2009) 638.
Mukherjee K, and Majumder S B, Talanta 81 (2010) 1826.
Chu X F, Liu X Q, and Meng G Y, Mater Sci Eng B 64 (1999) 60.
Martinelli G, and Carotta M C, Sens Actuators B 7 (1992) 717.
Arshak K, and Gaidan L, Thin Solid Films 495 (2006) 292.
Xiangfeng E, and Chemou Z, Sens Actuators B 96 (2003) 504.
Sugimoto M, Am J Ceram Soc 82 (1999) 269.
Bahadur D, Bull Mater Sci 15 (1992) 431.
Nicolae R, Elena R, Florin T, and Popa P D, Sens Transducers J 78 (2007) 1134.
Gul I H, Ahmed W, and Maqsood A, J Magn Mater 320 (2008) 270.
Van Uitert L G, J Chem Phys 24 (1955) 306.
Gopal Reddy C V, Manorama S V, and Rao V J, J Mater Sci Lett 19 (2000) 775.
Liu Y L, Liu Z M, Yang Y, Yang H F, Shen G L, and Yu R Q, Sens Actuators B 107 (2005) 600.
Zenger M, Int J Mater Prod Technol 9 (1994) 265.
Tyagi S, Baskey H B, Agarwala R C, Agarwala V, and Shami T C, Ceram Int 37 (2011) 2631.
Tyagi S, Baskey H B, Agarwala R C, Agarwala V, and Shami T C, J Electron Mater 40 (2011) 2004.
Ataie A, Heshmati-Manesh S, and Kazempour H, J Mater Sci 37 (2002) 2125.
Ataie A, and Heshmati-Manesh S, J Eur Ceram Soc 21 (2001) 1951.
Jang J S, Hong S J, and Lee J S, J Korean Phys Soc 54 (2009) 204.
Joshi G P, Saxena N S, Mangal R, Mishra A, and Sharma T P, Bull Mater Sci 26 (2003) 387.
Zhang G, Li C, and Cheng F, Chen J, Sens Actuators B 120 (2007) 403.
Yamazoe N, Sens Actuators B 5 (1991) 7.
Kadu A V, Jagtap S V, and Chaudhari G N, Curr Appl Phys 9 (2009) 1246.
Arshak K, and Gaidan I, Mater Sci Eng B 118 (2005) 44.
Moseley P T, Sens Actuators B 3 (1991) 167.
Rezlescu N, Rezlescu E, Tudorache F, and Popa P D, Romanian Rep Phys 61 (2009) 223.
Kapase V D, Ghosh S A, Raghuwanshi F C, Kapase S D, and Khandekar U S, Talanta 78 (2009) 19.
Rezlescu N, Rezlescu E, Tudorache F, and Popa P D, Sens Transducers 78 (2007) 1134.
Jiao Z, Wu M. Gu J, and Qin Z, IEEE Sens J 3 (2003) 435.
Mukherjee K, and Majumder S B, Sens Actuators B 162 (2012) 229.
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The authors are thankful to the Director, CSIR-Central Scientific Instruments Organization, Chandigarh for the support and the encouragement provided to carry out this work.
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Tyagi, S., Batra, N. & Paul, A.K. Influence of Temperature on Reducing Gas Sensing Performance of Nanocrystalline Zinc Ferrite. Trans Indian Inst Met 68, 707–713 (2015). https://doi.org/10.1007/s12666-014-0503-7
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DOI: https://doi.org/10.1007/s12666-014-0503-7