Abstract
In this study, we report a novel PtSe2/graphene nanocomposite by facile ultrasonic-assisted techniques. The “as-prepared” nanocomposites were further characterized by various techniques such as X-ray diffraction, scanning electron microscopy with an energy dispersive X-ray analysis, transmission electron microscopy, UV–Vis absorbance spectra analysis, diffuse reflectance analysis, and Raman spectroscopic analysis. The photocatalytic activities of the composites were investigated by the degradation of rhudamine B and methylene blue as a standard dyes. The photodegradation rates of organic dyes by the nanocomposites are found to be markedly high. This study suggests that the as-prepared PtSe2/graphene composite can be utilized as highly efficient photocatalyst materials that employed visible light as an energy source.
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References
Zhang Y, Pan C (2012) Measurements of mechanical properties and number of layers of graphene from nano-indentation. Diam Relat Mater 24:1–5
Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388
Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 10:3498–3502
Balandin AA, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8(3):902–907
Bolotin KI, Sikes KJ, Jiang Z, Klima M, Fudenberg G, Honec J (2008) Ultrahigh electron mobility in suspended graphene. Solid State Commun 146(9):351–3155
Du X, Skachko I, Barker A, Andrei EY (2008) Approaching ballistic transport in suspended graphene. Nat Nanotechnol 3(8):491–495
Zhang KJ, Liu XH (2011) One step synthesis and characterization of CdS nanorod/graphene nanosheet composite. Appl Surf Sci 257:10379–10383
Zhao XM, Zhou SW, Jiang LP, Hou WH, Shen QM, Zhu JJ (2012) Graphene–Cds nanocomposites: facile one-step synthesis and enhanced photoelectrochemical cytosensing. Chem Eur J 18:4974–4981
Jia L, Wang DH, Huang YX, Xu AW, Yu HQ (2011) Highly durable N-doped graphene/CdS nanocomposites with enhanced photocatalytic hydrogen evolution from water under visible light irradiation. J Phys Chem C 115:11466–11473
Geng X, Niu L, Xing Z, Song R, Liu G, Sun M, Cheng G, Zhong H, Liu Z, Zhang Z, Sun L, Xu H, Lu L, Liu L (2010) Aqueous-processable noncovalent chemically converted graphene–quantum dot composites for flexible and transparent optoelectronic films. Adv Mater 22(5):638–642
Cao A, Liu Z, Chu S, Wu M, Ye Z, Cai Z, Chang Y, Wang S, Gong Q, Liu Y (2010) A facile one step method to produce graphene–CdS quantum dots nanocomposites as a promising optoelectronics material. Adv Mater 22:103–106
Yang X, Zhang X, Ma Y, Huang Y, Wang Y, Chen Y (2009) Superparamagnetic graphene oxide–Fe3O4 nanoparticles hybrids for controlled targeted drug carriers. J Mater Chem 19:2710–2714
Chu J, Li X, Xu P (2011) Fluorescent features of CdTe nanorods grafted to graphene oxide through an amidation process. J Mater Chem 21:11283–11287
Manga KK, Wang S, Jaiswal M, Bao Q, Loh KP (2010) High-grain graphene-titanium oxide photoconductor made from inject printable ionic solution. Adv Mater 22:5265–5270
Yang H, Guai GH, Guo C, Song Q, Jiang SP, Wang Y, Zhang W, Li CM (2011) NiO/Graphene composite for enhanced charge separation and collection in p-Type dye sensitized solar cell. J Phys Chem C 115:12209–12215
Liang YY, Li YG, Wang HL, Zhou JG, Dai HJ (2011) Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. Nat Mater 10:780–786
Zhang XY, Li HP, Cui XL, Lin YH (2010) Graphene/TiO2 nanocomposites: synthesis, characterization and application in hydrogen evolution from water photocatalytic splitting. J Mater Chem 20:2801–2806
Abdullah AZ, Ling PY (2010) Heat treatment effects on the characteristics and sonocatalytic performance of TiO2 in the degradation of organic dyes in aqueous solution. J Hazard Mater 173:159–167
Ullah K, Ye S, Zhu L, Meng ZD, Sarkar S, Oh WC (2014) Microwave assisted synthesis of noble-metal graphene hybrid photocatalyst for high efficient decomposition of organic dyes under visible light. Mater Sci Eng B 180:20–26
Perera SD, Mariano RG, Vu K, Nour N, Seitz O, Chabal Y, Balkus KJ Jr (2012) Hydrothermal synthesis of graphene–TiO2 nanotube composites with enhanced photocatalytic activity. ACS Catal 2:949–956
Meng ZD, Zhu L, Ghosh T, Park CY, Ullah K, Nikam V, Oh WC (2012) Ag2Se–grephene/TiO2 nanocomposite son chemical synthesis and enhanced photocatalytic properties under visible light. Bull Korean Chem 11:3761–3766
Dong Z, Vasilii IA, Boris IY, Xu Z (2013) Pseudo Hall–Petch strength reduction in polycrystalline graphene. Nano Lett 3(4):1829–1833
Murphy AB (2007) Band-gap determination from diffuse reflectance measurements of semiconductor films and application to photoelectrochemical water-splitting. Sol Energy Mater Sol Cells 91:1326–1337
Guo Q, Kim SJ, Kar M, Shafarman WN, Birkmire RW, Stach EA, Agrawal R, Hillhouse HW (2008) Development of CuInSe2 nanocrystal and nanoring inks for low cast solar cell. Nano Lett 8:2982–2987
Zhang X, Tang Y, Li T, Wang Y, Liu X, Liu C, Luo S (2013) Reduced graphene oxide and PbS nanoparticles co-modified TiO2 nanotube arrays as a recyclable and stable photocatalyst for efficient degradation of pentachlorophenol. Appl Catal A 457:78–84
Al-Kuhaili MF, Kayani A, Durrani SMA, Bakhtiari IA, Haider MB (2013) Band gap engineering of Zinc Selenide thin films through alloying with Cadmium Telluride. ACS Appl Mater Interfaces 5:5366–5372
Ullah K, Meng ZD, Ye S, Zhu L, Oh WC (2013) Synthesis and characterization of novel PbS-Graphene/TiO2 composite with enhanced photocatalytic activity. J Ind Eng Chem. doi:10.1016/j.jiec.2013.06.040
Rao R, Podila R, Tsuchikawa R, Katoch R, Tishler J, Rao D, Ishigami AM (2011) Effects of layer stacking on the combination of the Raman modes in graphene. ACS Nano 5:1594–1599
Kudin K, Ozbas B, Schniepp H, Prud’homme R, Aksay I, Car R (2008) Raman spectra of graphite oxide and functionalized graphene. Nano Lett 1, 8:36–41
Yoon I, Kim C-D, Min B-K, Kim Y-K, Kim B, Jung W-S (2009) Characterization of graphene sheets formed by the reaction of carbon monoxide with aluminum sulfide. Bull Korean Chem Soc 30:3045–3048
Shen J, Yan B, Shi M, Ma H, Li N, Ye M (2011) One step hydrothermal synthesis of TiO2-reduced graphene oxide sheets. J Mater Chem 21:3415–3421
Kamat PV (2010) Graphene-based nanoarchitectures: anchoring semiconductor and metal nanoparticles on a two-dimensional carbon support. J Phys Chem Lett 1:520–527
Stankovich S, Dikin DA, Dommett GH, Kohlhass BK, Zimney ME, Stach JE, Piner AD, Nguyen ST, Ruoff RS (2006) Graphene-based composite materials. Nature 442:282–286
Ghosh T, Oh WC (2012) Review on reduced grapheme oxide by chemical exfoliation method and its simpler alternative of ultrasonication and heat treatment method for obtaining grapheme. J Photocatal Sci 3(1):17–23
Shixiong M, Gongxuan L (2012) Dye-cosensitized graphene/Pt photocatalyst for high efficient visible light hydrogen evolution. Int J Hydrogen Energy 37:10564–10574
Li Y, Li X, Li J, Yin J (2006) Photocatalytic degradation of methyl orange by TiO2-coated activated carbon and kinetic study. J Water Res 40:1119–1126
Ullah K, Zhu L, Meng ZD, Ye S, Sun Q, Oh WC (2013) A Facile and fast synthesis of novel composite Pt-Graphene/TiO2 with enhanced photocatalytic activity under UV–Vis light. Chem Eng J 231:76–83
Kamat P (2011) Graphene-based nanoassemblies for energy conversion. J Phys Chem Lett 2:242–251
Yu Y, Ma LL, Huang WY, Du FP, Yu JC, Yu JG (2005) Sonication assisted deposition of Cu2O nanoparticles on multiwall carbon nanotubes with polyol process. Carbon 43:670–673
Deng C, Hub H, Ge X, Han C, Zhoa D, Shao G (2011) One-pot sonochemical fabrication of hierarchical hollow CuO submicrospheres. Ultrason Sonochem 19:932–937
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Ullah, K., Zhu, L., Meng, ZD. et al. Synthesis and characterization of novel PtSe2/graphene nanocomposites and its visible light driven catalytic properties. J Mater Sci 49, 4139–4147 (2014). https://doi.org/10.1007/s10853-014-8109-3
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DOI: https://doi.org/10.1007/s10853-014-8109-3