Abstract
Viscoelastic properties of hollow particle-reinforced composites called syntactic foams are studied using a dynamic mechanical analyzer. Glass hollow particles of three different wall thicknesses are incorporated in the volume fraction range of 0.3–0.6 in vinyl ester resin matrix to fabricate twelve compositions of syntactic foams. Storage modulus, loss modulus, and glass transition temperature are measured and related to the microstructural parameters of syntactic foams. In the first step, a temperature sweep from −75 to 195 °C is applied at a fixed loading frequency of 1 Hz to obtain temperature dependent properties of syntactic foams. In the next step, selected four compositions of syntactic foams are studied for combined effect of temperature and loading frequency. A frequency sweep is applied in the range 1–100 Hz and the temperature is varied in the range 30–140 °C. Time–temperature superposition (TTS) principle is used to generate master curves for storage modulus over a wide frequency range. The room temperature loss modulus and maximum damping parameter, Tanδ, are found to have a linear relationship with the syntactic foam density. Increasing volume fraction of particles helps in improving the retention of storage modulus at high temperature in syntactic foams. Cole–Cole plot and William–Landel–Ferry equation are used to interpret the trends obtained from TTS. The correlations developed between the viscoelastic properties and material parameters help in tailoring the properties of syntactic foams as per requirements of an application.
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References
Shutov F (1986) Advances in polymer science: chromatography/foams/copolymers. Springer, New York
John B, Nair CPR (2010) Update on syntactic foams. iSmithers Rapra, Shropshire
Gupta N, Woldesenbet E (2004) J Cell Plast 40:461. doi:10.1177/0021955x04048421
Shabde V, Hoo K, Gladysz G (2006) J Mater Sci 41:4061. doi:10.1007/s10853-006-7637-x
Gladysz G, Perry B, McEachen G, Lula J (2006) J Mater Sci 41:4085. doi:10.1007/s10853-006-7646-9
Gupta N, Woldesenbet E, Mensah P (2004) Compos A Appl Sci Manuf 35:103. doi:10.1016/j.compositesa.2003.08.001
Gupta N, Kishore K, Woldesenbet E, Sankaran S (2001) J Mater Sci 36:4485. doi:10.1023/a:1017986820603
Poveda R, Achar S, Gupta N (2012) JOM J Miner Met Mater Soc 64:1148. doi:10.1007/s11837-012-0402-5
Dimchev M, Caeti R, Gupta N (2010) Mater Des 31:1332. doi:10.1016/j.matdes.2009.09.007
Hodge AJ, Kaul RK, McMahon WM (2000) In: Loud S, Karbhari V, Adams DO, Strong AB (eds) Proceedings of the 45th international SAMPE symposium. SAMPE Publishing, Long Beach
Grosjean F, Bouchonneau N, Choqueuse D, Sauvant-Moynot V (2009) J Mater Sci 44:1462. doi:10.1007/s10853-008-3166-0
Bouchonneau N, Sauvant-Moynot V, Choqueuse D, Grosjean F, Poncet E, Perreux D (2010) J Petrol Sci Eng 73:1. doi:10.1016/j.petrol.2010.03.023
Shunmugasamy V, Pinisetty D, Gupta N (2012) J Mater Sci 47:5596. doi:10.1007/s10853-012-6452-9
Porfiri M, Nguyen N, Gupta N (2009) J Mater Sci 44:1540. doi:10.1007/s10853-008-3040-0
Lin T, Gupta N, Talalayev A (2009) J Mater Sci 44:1520. doi:10.1007/s10853-008-3074-3
McGrath LM, Parnas RS, King SH, Schroeder JL, Fischer DA, Lenhart JL (2008) Polymer 49:999. doi:10.1016/j.polymer.2007.12.014
Yasmin A, Daniel IM (2004) Polymer 45:8211. doi:10.1016/j.polymer.2004.09.054
Ferry JD (1980) In: Viscoelastic properties of polymers. Wiley, New York
Menard KP (1999) Dynamic mechanical analysis a practical introduction. CRC Press, Boca Raton
Gupta N, Nagorny R (2006) J Appl Polym Sci 102(2): 1254. doi:10.1002/app.23548
Gupta N, Ye R, Porfiri M (2010) Compos B Eng 41:236. doi:10.1016/j.compositesb.2009.07.004
Rizzi E, Papa E, Corigliano A (2000) Int J Solids Struct 37:5773. doi:10.1016/s0020-7683(99)00264-4
Bardella L, Genna F (2001) Int J Solids Struct 38:7235. doi:10.1016/s0020-7683(00)00228-6
Capela C, Ferreira JAM, Costa JD (2010) Mater Sci Forum 636–637:280. doi:10.4028/www.scientific.net/MSF.636-637.280
Sankaran S, Sekhar K, Raju G, Kumar M (2006) J Mater Sci 41:4041. doi:10.1007/s10853-006-7607-3
Hu G, Yu D (2011) Mater Sci Eng, A 528:5177. doi:10.1016/j.msea.2011.03.071
Ferreira JAM, Capela C, Costa JD (2011) Strain 47:275. doi:10.1111/j.1475-1305.2009.00681.x
John B, Nair CPR, Ninan KN (2010) Mater Sci Eng, A 527:5435. doi:10.1016/j.msea.2010.05.016
Lefebvre X, Sauvant-Moynot V, Choqueuse D, Chauchot P (2009) Oil Gas Sci Technol: Rev d’IFP Energies Nouvelles 64:165. doi:10.2516/ogst/2008053
Tagliavia G, Porfiri M, Gupta N (2009) J Compos Mater 43:561. doi:10.1177/0021998308097683
Asif A, Rao VL, Ninan KN (2010) Mater Sci Eng, A 527:6184. doi:10.1016/j.msea.2010.06.058
Wouterson EM, Boey FYC, Hu X, Wong S-C (2007) Polymer 48:3183. doi:10.1016/j.polymer.2007.03.069
Guo Z, Pereira T, Choi O, Wang Y, Hahn HT (2006) J Mater Chem 16:2800. doi:10.1039/B603020C
Guo Z, Wei S, Shedd B, Scaffaro R, Pereira T, Hahn HT (2007) J Mater Chem 17:806. doi:10.1039/B613286C
Guo Z, Ng HW, Yee GL, Hahn HT (2009) J Nanosci Nanotechnol 9:3278. doi:10.1166/jnn.2009.VC06
Ray D, Sarkar BK, Das S, Rana AK (2002) Compos Sci Technol 62:911. doi:10.1016/s0266-3538(02)00005-2
Zhu J, Wei S, Ryu J, Budhathoki M, Liang G, Guo Z (2010) J Mater Chem 20:4937. doi:10.1039/C0JM00063A
Corning Dow (2004) FSRs in extreme applications: proof of the new paradigm. A Dow Corning Publication, Midland
Zwynenburg J (2010) Articles on plastics testing characterizing foam hinged lid containers utilizing dynamic mechanical analysis (DMA). http://www.ides.com/articles/testing/2010/characterizing-foam-hinged-lid-containers.asp. Accessed 24 Sept 2012
Huang JS, Gibson LJ (1993) J Mech Phys Solids 41:55. doi:10.1016/0022-5096(93)90063-l
Tagliavia G, Porfiri M, Gupta N (2010) Compos B Eng 41:86. doi:10.1016/j.compositesb.2009.03.004
Karthikeyan CS, Sankaran S, Kishore (2005) Macromol Mater Eng 290: 60. doi:10.1002/mame.200400177
Nji J, Li G (2008) Compos A Appl Sci Manuf 39:1404. doi:10.1016/j.compositesa.2008.05.001
Brennan AB, Wang YQ, DeSimone JM, Stompel S, Samulski ET (1993) Polymer 34:807. doi:10.1016/0032-3861(93)90366-i
Xia Z, Sue H-J, Hsieh AJ, Huang JWL (2001) J Polym Sci B 39:1394. doi:10.1002/polb.1111
Mahieux CA, Reifsnider KL (2001) Polymer 42:3281. doi:10.1016/s0032-3861(00)00614-5
Mahieux CA, Reifsnider KL (2002) J Mater Sci 37:911. doi:10.1023/a:1014383427444
Mahieux CA, Reifsnider KL (2002) J Elastomers Plast 34:79. doi:10.1106/009524402022348
Tagliavia G, Porfiri M, Gupta N (2010) Int J Solids Struct 47:2164. doi:10.1016/j.ijsolstr.2010.04.025
Tagliavia G, Porfiri M, Gupta N (2011) Int J Solids Struct 48:1141. doi:10.1016/j.ijsolstr.2010.12.017
Robertson CG, Lin CJ, Rackaitis M, Roland CM (2008) Macromolecules 41:2727. doi:10.1021/ma7022364
Pothan LA, Oommen Z, Thomas S (2003) Compos Sci Technol 63:283. doi:10.1016/s0266-3538(02)00254-3
Williams ML, Landel RF, Ferry JD (1955) J Am Chem Soc 77:3701. doi:10.1021/ja01619a008
Bozorg-Haddad A, Iskander M (2011) J Mater Eng Perform 20:1219. doi:10.1007/s11665-010-9743-9
Bozorg-Haddad A, Iskander M (2011) J Mater Civ Eng 23:1154. doi:10.1061/(ASCE)MT.1943-5533.0000278
Acknowledgements
This study was supported by the Office of Naval Research grant N00014-10-1-0988 with Dr. Yapa D.S. Rajapakse as the program manager. The authors thank the MAE Department for providing facilities and support. TA Instruments is acknowledged for technical discussions. Dr. Dung D. Luong is thanked for help in conducting some experiments.
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Shunmugasamy, V.C., Pinisetty, D. & Gupta, N. Viscoelastic properties of hollow glass particle filled vinyl ester matrix syntactic foams: effect of temperature and loading frequency. J Mater Sci 48, 1685–1701 (2013). https://doi.org/10.1007/s10853-012-6927-8
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DOI: https://doi.org/10.1007/s10853-012-6927-8