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Complete desorption of interlayer hydrogen phosphate in Mg/Al-layered double hydroxides by means of anion exchange with 1-octanesulfonate

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Abstract

Hydrogen phosphate intercalated Mg/Al-layered double hydroxides (LDH-HPO4) were synthesized by a homogeneous precipitation method with urea and anion exchange. The intercalated hydrogen phosphate was removed by anion exchange with Na2CO3, NaOH–NaCl, and 1-octanesulfonate solutions. The phosphate removal behavior was characterized by X-ray diffraction (XRD), Fourier Transform-InfraRed (FT-IR) spectroscopy, and elemental analysis. Complete removal of interlayer hydrogen phosphate from LDH-HPO4 was realized using 1-octanesulfonate solution. Two reasons are proposed to explain complete hydrogen phosphate removal from the interlayer space of LDH-HPO4. Complete desorption and cyclability suggest this is a viable technique to use as an efficient adsorption/desorption system in industrial applications.

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Authors and Affiliations

  1. School of Chemical Sciences, The University of Auckland, 23 Symonds St, 1142, Auckland, New Zealand

    Akihiro Shimamura & James B. Metson

  2. Department of Chemical and Material Engineering, The University of Auckland, 20 Symonds St, 1142, Auckland, New Zealand

    Mark I. Jones

  3. Department of Chemical Science and Technology, Graduate School of Advanced Technology and Science Department, The University of Tokushima, 2-1 Minamijosanjima, Tokushima, 770-8506, Japan

    Eiji Kanezaki

Authors
  1. Akihiro Shimamura
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  2. Mark I. Jones
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  3. Eiji Kanezaki
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  4. James B. Metson
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Correspondence to Akihiro Shimamura.

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Shimamura, A., Jones, M.I., Kanezaki, E. et al. Complete desorption of interlayer hydrogen phosphate in Mg/Al-layered double hydroxides by means of anion exchange with 1-octanesulfonate. J Mater Sci 47, 1142–1147 (2012). https://doi.org/10.1007/s10853-011-5960-3

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  • DOI: https://doi.org/10.1007/s10853-011-5960-3

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