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Lightweight glass/Fe3O4-polyaniline composite hollow spheres with conductive and magnetic properties

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Abstract

Lightweight composite hollow spheres with conductive and magnetic properties were prepared by using Hollow Glass Spheres (HGS) as substrate. The morphology, composition, conductive, and magnetic properties of the resultant products were characterized by SEM, EDX, XRD, FTIR spectra, conductivity measurement, and vibrating-sample magnetometry. Polyaniline (PANI) were in situ polymerized on HGS with increasing ratios of PANI to HGS, resulting in the enhanced conductivity of HGS/PANI composites from 1.3 × 10−2 S/cm to 4.4 × 10−2 S/cm. Lightweight glass/Fe3O4-PANI composite hollow spheres (HGS/Fe3O4-PANI) with conductivity of 5.4 × 10−3 S/cm and magnetization of 9.25 emu/g were prepared by deposition of Fe3O4 nanoparticles onto HGS via electrostatic adsorption first, and then polymerization of aniline onto HGS/Fe3O4. The glass/PANI-Fe3O4 composite hollow spheres (HGS/PANI-Fe3O4) composed of Fe3O4 as the outmost layer and PANI as the inner layer were prepared for comparison. The conductivity and magnetization of HGS/PANI-Fe3O4 were 1.1 × 10−4 S/cm and 2.61 emu/g, respectively.

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References

  1. Rupali G, Amitabha D (2000) Chem Mater 12:608

    Article  Google Scholar 

  2. Phang SW, Tadokoro M, Watanabe J, Kuramoto N (2009) Polym Adv Technol 20:550

    Article  CAS  Google Scholar 

  3. Feng X, Mao C, Yang G, Hou W, Zhu J-J (2006) Langmuir 22:4384

    Article  CAS  Google Scholar 

  4. Chen Q, Zhao L, Li C, Shi G (2007) J Phys Chem C 111:18392

    Article  CAS  Google Scholar 

  5. Caruso F, Spasova M, Susha A, Giersig M, Caruso RA (2001) Chem Mater 13:109

    Article  CAS  Google Scholar 

  6. Salgueiriño-Maceira V, Correa-Duarte MA (2007) Adv Mater 19:4131

    Article  Google Scholar 

  7. An Z, Zhang J, Pan S (2009) Dalton Trans 3664

  8. Chiang J-C, Macdiarmid AG (1986) Synth Met 13:193

    Article  CAS  Google Scholar 

  9. Stejskal J, Sapurina I, Trchová M, Konyushenko EN (2008) Macromolecules 41:3530

    Article  CAS  Google Scholar 

  10. Hong RY, Feng B, Liu G, Wang S, Li HZ, Ding JM, Zheng Y, Wei DG (2009) J Alloy Compd 476:612

    Article  CAS  Google Scholar 

  11. Huang Z, Tang F (2004) J Colloid Interface Sci 275:142

    Article  CAS  Google Scholar 

  12. Mohapatra S, Pramanik N, Mukherjee S, Ghosh SK, Pramanik P (2007) J Mater Sci 42:7566. doi:10.1007/s10853-007-1597-7

    Article  CAS  Google Scholar 

  13. Cheng Y, Tan R, Wang W, Guo Y, Cui P, Song W (2010) J Mater Sci 45:5347. doi:10.1007/s10853-010-4583-4

    Article  CAS  Google Scholar 

  14. Qiu G, Wang Q, Nie M (2006) J Appl Polym Sci 102:2107

    Article  CAS  Google Scholar 

  15. Lee H-Y, Pwei S-P, Wang L, Chen P-H (2008) Mater Chem Phys 112:805

    Article  CAS  Google Scholar 

  16. Yang C, Li H, Xiong D, Cao Z (2009) React Funct Polym 69:137

    Article  CAS  Google Scholar 

  17. Wang X, Tang S, Liu J, He Z, An L, Zhang C, Hao J, Feng W (2009) J Nanopart Res 11:923

    Article  CAS  Google Scholar 

  18. Kong L, Lu X, Jin E, Jiang S, Bian X, Zhang W, Wang C (2009) J Solid State Chem 182:2081

    Article  CAS  Google Scholar 

  19. Wang X, Liu J, Feng X, Guo M, Sun D (2008) Mater Chem Phys 112:319

    Article  CAS  Google Scholar 

  20. Rohatgi PK, Matsunaga T, Gupta N (2009) J Mater Sci 44:1485. doi:10.1007/s10853-008-3165-1

    Article  CAS  Google Scholar 

  21. Mcbride SP, Shukla A, Bose A (2002) J Mater Sci 37:4217. doi:10.1023/A:1020056407402

    Article  CAS  Google Scholar 

  22. Chalivendra VB, Shukla A, Bose A, Parameswaran V (2003) J Mater Sci 38:1631. doi:10.1023/A:1023203121299

    Article  CAS  Google Scholar 

  23. Koopman M, Chawla KK, Ricci W, Carlisle K, Gladsyz GM, Lalor M, Jones ML, Kerr K, George MP, Gouadec G, Tournié A (2009) J Mater Sci 44:1435. doi:10.1007/s10853-008-2963-9

    Article  CAS  Google Scholar 

  24. Chen L, Xu Z, Dai H, Zhang S (2010) J Alloy Compd 497:221

    Article  CAS  Google Scholar 

  25. Zhang ZM, Wan MX (2003) Synth Met 132:205

    Article  CAS  Google Scholar 

  26. Ding S-J, Zhang C-L, Yang M, Qu X-Z, Lu Y-F, Yang Z-Z (2006) Polymer 47:8360

    Article  CAS  Google Scholar 

  27. Yang M, Ma J, Zhang C, Yang Z, Lu Y (2005) Angew Chem Int Ed 44:6727

    Article  CAS  Google Scholar 

  28. Zhou B, Shen J, Wu Y, Wu G, Ni X (2007) Mater Sci Eng C 27:1291

    Article  CAS  Google Scholar 

  29. Ding H, Shen J, Wan M, Chen Z (2008) Macromol Chem Phys 209:864

    Article  CAS  Google Scholar 

  30. Wang J, Chen Q, Zeng C, Hou B (2004) Adv Mater 16:137

    Article  CAS  Google Scholar 

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Acknowledgements

This study was supported by the NSF of China (51003020), and the Natural Scientific Research Innovation Foundation in Harbin Institute of Technology (HIT.NSRIF.2009124).

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, 150001, China

    Jing Wang, Huifang Xu, Jianwei Song, Beiling Gao & Yudong Huang

  2. Heilongjiang Institute of Science and Technology, Harbin, 150027, China

    Haijiao Zhang

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  1. Jing Wang
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  2. Huifang Xu
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  3. Jianwei Song
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  4. Haijiao Zhang
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  5. Beiling Gao
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Correspondence to Huifang Xu.

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Wang, J., Xu, H., Song, J. et al. Lightweight glass/Fe3O4-polyaniline composite hollow spheres with conductive and magnetic properties. J Mater Sci 46, 2955–2962 (2011). https://doi.org/10.1007/s10853-010-5171-3

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  • DOI: https://doi.org/10.1007/s10853-010-5171-3

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