Abstract
Layered double hydroxide (LDH) was synthesized in the presence of sodium dodecyl sulfate. X-ray diffraction (XRD) and infrared spectrum revealed that dodecyl sulfate (DS) anions were successfully intercalated into the interlayers of LDH. Poly(vinylidene fluoride)/LDH nanocomposite membranes were prepared by mixing the DS intercalated LDH with poly(vinylidene fluoride) (PVDF) in N,N’′-dimethylformamide solution followed by the solvent evaporation. The nanocomposite membranes were further swollen with a H3PO4 solution in ethylene carbonate-propylene carbonate to obtain the proton conducting nanocomposite gel electrolytes. XRD and transmission electron microscope results showed that LDH particles were well-dispersed in the polymer matrix and partially intercalated by polymer chains. The proton conductivity was highly enhanced in the nanocomposite gel electrolyte systems. In the case of the nanocomposite gel electrolyte containing 7.40 wt.% LDH, the proton conductivity increased by about 2.5 times compared to pure PVDF gel electrolyte.
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Raducha D, Wieczorek W, Florjanczyk Z, Stevens R (1996) J Phys Chem 36:20126
Zukowska G, Rogowska R, Wojda A, Zygadlo-Monikowska E, Florjanczyk Z (2000) Solid State Ionics 136–137:1205
Ericson H, Svanberg C, Brodin A, Grillone AM, Panero S, Scrosati B, Jacobsson P (2000) Electrochim Acta 45:1409
Wieczorek W, Zukowska G, Borkowska B, Chung SH, Greenbaum S (2001) Electrochim Acta 46:1427
Tarascon JM, Gozda AS, Schmutz CN, Shokoohi F, Waren PC (1996) Solid State Ionics 86–88:49
Jiang Z, Caroll B, Abraham KM (1997) Electrochim Acta 42:2667
Fuller J, Breda AC, Carlin RT (1997) J Electrochem Soc 144:67
Osaka T, Kitahara M, Uchida Y, Momma T, Nishimura K (1999) J Power Sources 81–82:734
Zukowska G, Rogowska M, Weczkowska E, Wieczorek W (1999) Solid State Ionics 119:289
Sekhon SS, Singh HP (2002) Solid State Ionics 152–153:169
Singh HP, Sekhon SS (2003) Eur Polym J 39:93
Sekhon SS, Singh HP (2004) Electrochim Acta 50:621
Choi BK, Park SH, Joo SW, Gong MS (2004) Electrochim Acta 50:649
Croce F, Curini R, Martinelli A, Persi L, Ronci F, Scrosati B, Caminti R (1999) J Phys Chem B 103:10632
Capiglia C, Mustarelli P, Quartarone E, Tomasi C, Magistris A (1999) Solid State Ionics 118:73
Xiong HM, Zhao X, Chen JS (2001) J Phys Chem B 105:10169
Kumar B, Scanlon L, Marsh R, Mason R, Higgins R, Baldwin R (2001) Electrochim Acta 46:1515
Antonucci PL, Arico AS, Creti P, Ramunni E, Antonucci V (1999) Solid State Ionics 125:431
Miyake N, Wainright JS, Savinell RF (2001) J Electrochem Soc 148A:898
Jung DH, Cho SY, Peek DH, Shin DR, Kim JS (2003) J Power Sources 116:205
Liao CS, Ye WB (2003) J Polym Res 10:241
Liao CS, Ye WB (2004) Electrochim Acta 49:4993
Liao CS, Ye WB (2004) Materials Chem Phys 88:207
Cho MS, Shin B, Nam JD, Lee YK, Song KG (2004) Polym Int 53:1523
Cho MS, Shin B, Choi SD, Lee Y, Song KG (2004) Electrochim Acta 50:331
Rives V, Ulibarri MA (1999) Cood Chem Rev 181:61
del Acro M, Martin C, Martin I, Rives V, Trulillano R (1993) Spectrochim Acta 49A:1575
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The authors thank the Science and Technology Department of Zhejiang Province for financially supporting this research.
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Bao, YZ., Cong, LF., Huang, ZM. et al. Preparation and proton conductivity of poly(vinylidene fluoride)/layered double hydroxide nanocomposite gel electrolytes. J Mater Sci 43, 390–394 (2008). https://doi.org/10.1007/s10853-007-2100-1
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DOI: https://doi.org/10.1007/s10853-007-2100-1