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TEM microstructural analysis of As-Bonded Al–Au wire-bonds

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Abstract

In this study the interface morphology of a model 99.999% (5N) Au wire bonded to Al pads in the as-bonded state was examined by scanning/transmission electron microscopy with energy dispersive spectroscopy. Specimens for transmission electron microscopy were prepared using the lift-out method in a dual-beam focused ion beam system. Analysis of the bond microstructure was conducted as a function of the Al pad content and as a function of the bonding temperature. Additions of Si and Cu to the Al pad affect the morphology and the uniformity of the interface. A characteristic-void line is formed between two intermetallic regions with different morphologies in the as-bonded samples. According to the morphological analysis it was concluded that a liquid phase forms during the bonding stage, and the void-line formed in the intermetallic region is the result of shrinkage upon solidification and not the Kirkendall effect.

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Acknowledgements

The authors thank the Russell Berrie Nanotechnology Institute at the Technion for use of the dual-beam FIB, and I. Popov for assistance with use of the TEM.

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Correspondence to Wayne D. Kaplan.

Appendix

Appendix

 

Structure Type

Pearson symbol

Space Group

Lattice Parameters [nm]

Al3Au8 [15]

Al3Au8

hR44

\(R\overline 3 c\)

a = 0.7724 c = 4.2083

AlAu4 [15]

W

cI2

\(\text{Im} \overline 3 m\)

a = 0.324

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Karpel, A., Gur, G., Atzmon, Z. et al. TEM microstructural analysis of As-Bonded Al–Au wire-bonds. J Mater Sci 42, 2334–2346 (2007). https://doi.org/10.1007/s10853-007-1592-z

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  • DOI: https://doi.org/10.1007/s10853-007-1592-z

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