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Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer

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Abstract

The zwitterionic dicarboxylate 1,1′-[(2,3,5,6-tetramethylbenzene-1,4-diyl)bis(methylene)]bis(pyridin-1-ium-4-carboxylate) (L) has been reacted with uranyl nitrate under solvo-hydrothermal conditions and in the presence of KReO4 to give the complex [UO2(L)(OH)(H2O)](ReO4) (1). This compound crystallizes as a cationic, monoperiodic coordination polymer with ReO4– as a simple counterion. The daisy-chain polymer is based on dinuclear rings built by the convergent zwitterionic ligands, these rings being linked to one another by double hydroxide bridges. In addition to a Coulombic interaction with a pyridinium ring, ReO4– is involved in one OH(water)⋅⋅⋅O and four CH⋅⋅⋅O interactions, and it is thus nestled in a cavity formed by three chains, seemingly with some selectivity over nitrate and chloride anions also present in the reaction mixture. This result illustrates the interest of zwitterionic dicarboxylates in building cationic assemblies able to trap ReO4–, a surrogate for the radioactive TcO4–, an anion of environmental relevance.

Graphical abstract

A zwitterionic dicarboxylate ligand was reacted with the uranyl ion to generate a cationic, daisychain coordination polymer including perrhenate as counterion. Examination of the Hirshfeld surface of the anion allows for an analysis of the weak interactions involved.

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Data availability

Crystallographic data have been deposited with the CCDC under number 2311986.

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Acknowledgements

This work was supported by KAKENHI Grant-in-Aid for Early-Career Scientists JP22K14698 for S. Kusumoto, and JSPS KAKENHI Grant Number 20K21213 for S. Hayami.

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Authors and Affiliations

  1. Department of Material & Life Chemistry, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama, 221-8686, Japan

    Sotaro Kusumoto & Yoshihiro Koide

  2. Technical University of Munich, Campus Straubing, Schulgasse 22, 94315, Straubing, Germany

    Youssef Atoini

  3. Department of Chemistry, Graduate School of Science and Technology, Institute of Industrial Nanomaterials (IINa), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan

    Shinya Hayami & Yang Kim

  4. Université de Strasbourg, ISIS, 8 allée Gaspard Monge, 67083, Strasbourg, France

    Jack Harrowfield

  5. Université Paris-Saclay, CEA, CNRS, NIMBE, 91191, Gif-sur-Yvette, France

    Pierre Thuéry

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  1. Sotaro Kusumoto
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  2. Youssef Atoini
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  3. Yoshihiro Koide
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  4. Shinya Hayami
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  5. Yang Kim
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  6. Jack Harrowfield
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  7. Pierre Thuéry
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Contributions

SK, YA, YK, SH, YK and PT contributed to the investigation. JH and PT wrote the main manuscript. All authors reviewed the manuscript.

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Correspondence to Yang Kim, Jack Harrowfield or Pierre Thuéry.

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Kusumoto, S., Atoini, Y., Koide, Y. et al. Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer. J Incl Phenom Macrocycl Chem (2024). https://doi.org/10.1007/s10847-024-01238-0

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