Heavy metal oxide (PbO and Bi2O3) glasses doped with transition metal (TM) ions (TiO2, V2O5, Cr2O3, and MnO2) and having low content of common glass formers (B2O3, SiO2, or P2O5) were prepared by the conventional melt annealing method. Ultraviolet, visible absorption, and photoluminescence properties of these glasses were measured, and the data were employed to investigate the prepared glassy samples. The optical absorption spectra of TiO2 and V2O5 exhibited three bands centered at about 240, 305, and 380 nm, followed by a broad asymmetrical near-visible band centered at 425–432 nm, while Cr2O3 and MnO2 exhibited an extended visible peak at 517–548 nm. Results showed that the luminescence intensity changed with different transition metal oxides. From the absorption edge data, the values of the optical band gap Eopt and Urbach energy (ΔE) were calculated. The calculated values of the optical energy gap were found to be dependent on the glass composition. The changing values of optical band gap and band tail can be related to the structural changes that are taking place in the glass samples. The variations of the luminescence intensity, values of optical band gap, band tail, and refractive index gave an indication of the potential use of the prepared glasses to design novel optical functional materials with higher optical performance.
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H. Singh, K. Singh, L. Gerward, K. Singh, H. S. Sahot, and R. Nathuram, Nucl. Instrum. Methods Phys. Res. B, 207, 257–262 (2003).
M. A. Marzouk, M. A. Ouis, and Y. M. Hamdy, Silicon, 4, 221–227 (2012).
A. R. Rodriguez, C. W. Parmelee, and A. E. Badger, J. Am. Ceram. Soc., 26, No. 5, 137–150 (1943).
M. A. Marzouk, J. Mol. Struct., 1019, 80–90 (2012).
S. S. Sastry and B. R.V. Rao, Int. J. Innov. Res. Sci., Eng. Technol., 4, 18681–18690 (2015).
F. H. ElBatal, M. A. Marzouk, and A. M. Abdel ghany, J. Mater. Sci., 46, 5140–5152 (2011).
F. H. ElBatal, Y. M. Hamdy, and S. Y. Marzouk, J. Non-Cryst. Solids, 355, 2439–2447 (2009).
F. H. El Batal, S. Ibrahim, and M. A. Marzouk, Radiat. Effects Defects Solids, 167, No. 4, 256–267 (2012).
C. R. Bamford, Colour Generation and Control in Glass, Glass Science and Technology, Vol. 2, Elsevier, Amsterdam (1977).
F. H. ElBatal, M. A. Marzouk, and A. M. Abdelghany, J. Non-Cryst. Solids, 357, 1027–1036 (2011).
A. Mekki, G. D. Khattak, D. Holland, M. Chinkhota, and L. E. Wenger, J. Non-Cryst. Solids, 318, 193–201 (2003).
H. A. ELBatal and N. A. Ghoneim, Nucl. Instrum. Methods Phys. Res. B, 124, 81–90 (1997).
N. Kiran, C.R. Kesavulu, A. Suresh Kumar, and J. L. Rao, Phys. B: Condens. Matter, 406, 1897–1901 (2011).
G. E. Malashkevich, G. I. Semkova , A. V. Semchenko, P. P. Pershukevich, and I. V. Prusova, JETP Lett., 88, No. 11, 740–744 (2008).
V. I. Glazkov, K. M. Golant, Yu. S. Zavorotny, V. F. Lebedev, and A. O. Rybaltovskii, Glass Phys. Chem., 28, No. 2, 201–206 (2002).
S. Ruengsri, Sci. Technol. Nucl. Install., 2014, 1–5 (2014).
J. D. Lee, Concise Inorganic Chemistry, Blackwell Scientific, Oxford (1996).
A. S. Rao, B. Sreedhar, J. L. Rao, and S. V. J. Lakshman, J. Non-Cryst. Solids, 144, 169–174 (1992).
S. S. Sastry, S.Vedavyas, and B. R.V. Rao, Int. J. Innovat. Res. Sci. Eng. Technol., 3, 1146 –1151 (2014).
P. Chimalawong, J. Kaewkhao, and P. Limsuwan, Energy Res. J., 1, No. 2, 176–181 (2010).
N. Mott, E. Davis, Electronic Process in Non-Crystalline Materials, 2nd ed., Clarendon Press, Oxford (1979).
S. M. Sze, Semiconductor Devices: Physics and Technology, 3rd ed., John Wiley & Sons, Inc., Canada (2007).
F. Urbach, Phys. Rev., 92, 1324 (1953).
V. Dimitrov and S. Sakka, J. Appl. Phys., 79 , No. 3, 1736–1740 (1996).
C. R. Bamford, Phys. Chem. Glasses, 3, 189–202 (1962).
F. H. ElBatal, Y. M. Hamdy, and S. Y. Marzouk, Mater. Chem. Phys., 112, 991–1000 (2008).
M. A. Marzouk, F. H. ElBatal, and A. M. Abdelghany, Spectrochim. Acta, A: Mol. Biomol. Spectrosc., 114, 658–667 (2013).
F. A. Cotton, G. Wilkinson, C. A. Murillo, and M. Bohmann, Advanced Inorganic Chemistry, 6th ed., John Wiley-Interscience, New York (1999).
T. Bates, In Modern Aspects of the Vitreous State, 2, J. D. Mackenzie (Ed.), Butterworths, London (1962), pp. 195–254.
M. A. Marzouk, S. Ibrahim, and Y. M. Hamdy, J. Mol. Struct., 1076, 576–582 (2014).
B. I. Denker, B. I. Galagan, I. L. Shulman, S. E. Sverchkov, and E. M. Dianov, Appl. Phys. B, 103, 681–685 (2011).
S. P. Singh and B. Karmakar, In Bismuth: Characteristics, Production and Applications. Materials Science and Technologies, Nova, Hauppauge, New York, ch. 9 (2012).
S. P. Singh, R. P. S. Chakradhar, J. L. Rao, and B. Karmakar, J. Alloys Compd., 493, 256–262 (2010).
N. Iwamoto, H. Hidaka, and Y. Makino, J. Non-Crystall. Solids, 58, 131–141 (1983).
C. F. Song, M. K. Lu, P. Yang, D. Xu, and D.R. Yuan, J. Sol-Gel Sci. Technol., 25, 113–119 (2002).
T. Sato, M. Shirai, K. Tanaka, Y. Kawabe, and E. Hanamura, J. Lumin., 114, 155–161 (2005).
M. Vrankic, B. Grzeta, V. Mandic, E. Tkalcec, S. Milosevic, M. Ceh, and B. Rakvin, J. Alloys Compd., 543, 213–220 (2012).
A. R. Babu, C. Rajyasree, P. S. Rao, P. M. V. Teja, and D. K. Rao, J. Mol. Struct., 1005, 83–90 (2011).
K. Neeraja, T. G. V. M. Rao, A. Rupesh Kumar, A. Uma Lakshmi, N. Veeraiah, and M. Rami Reddy, J. Mol. Struct., 1054–1055, 339–348 (2013).
A. E. Nosenko and B. V. Padlyak, Mol. Phys. Rep., 8, 79–87 (1994).
M. Gao, S. Kapphan, and R. Pankrath, J. Phys. Chem. Solids, 61, 1959–1971 (2000).
B. V. Padlyak, W. R. Romanowski, R. Lisiecki, V. T. Adamiv, Ya. V. Burak, and I. M. Teslyuk, Synthesis, Opt. Mater., 34, 2112–2119 (2012).
B. Choudhury and A. Choudhury, Mater. Sci. Eng., B, 178, 794–800 (2013).
K. Bingham and S. Parke, Phys. Chem. Glasses, 6, 224–232 (1965).
A. Thulasiramudu and S. Buddhudu, J. Quant. Spectr. Radiat. Transfer, 102, 212–227 (2006).
F. H. A. Elbatal, M. A. Marzouk, Y. M. Hamdy, and H. A. ElBatal, J. Solid State Phys., 2014, 1–8 (2014).
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Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 84, No. 1, p. 168, January–February, 2017.
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Marzouk, M.A., Abo-Naf, S.M., Zayed, H.A. et al. Glass Former Effects on Photoluminescence and Optical Properties of Some Heavy Metal Oxide Glasses Doped with Transition Metal Ions. J Appl Spectrosc 84, 162–169 (2017). https://doi.org/10.1007/s10812-017-0445-z
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DOI: https://doi.org/10.1007/s10812-017-0445-z