Abstract
Manganese dioxides (MnO2) with controllable crystalline structure were synthesized by varying the synthesis conditions through a hydrothermal route with KMnO4 and MnSO4·H2O as precursors. Crystalline structures and morphologies of the samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy. The paper studied the nanowires growth mechanism under different experimental conditions, and the resulting lithium storage performance of MnO2 nanowires with different crystalline structure was also discussed.
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Acknowledgments
The authors appreciate the support of the Science and Technology Foundation of China Academy of Engineering Physics (No.2012B0302041) and Graduate student innovation fund of the South West Petroleum University (No.GIFSS0714). We are indebted to Magaret Yau, Jiahui Lin, Jicheng Zhang, Jiangping Wang and Shaomin Li for their kind help and fruitful discussions.
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Zhang, Y., Liu, H., Zhu, Z. et al. Control synthesis and lithium ion battery performance of manganese dioxide nanowires with tunable structures but similar morphology. J Appl Electrochem 43, 705–710 (2013). https://doi.org/10.1007/s10800-013-0559-9
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DOI: https://doi.org/10.1007/s10800-013-0559-9