Structural, Superconducting, and Magnetic Properties of Y_{1- x} Dy_xRh4B4 Borides

Abstract

Samples with nominal compositions Y_1-x Dy_xRh₄B₄ are prepared by argon-atmosphere arc melting. The phase composition of the samples and the elemental compositions of the individual phases present are determined by x-ray diffraction and electron-probe x-ray microanalysis. The results indicate that increasing the dysprosium content of the starting mixture increases the percentage of the magnetic phase and reduces that of the superconducting phase in the samples. The electrical resistivity, magnetic susceptibility, and magnetic moment of the samples are measured between 1.6 and 30 K (magnetic fields of up to 14 T). The magnetic phase present in the samples with 0.2 ≤ × ≤ is shown to undergo ferromagnetic ordering at T _magn ≃ 13–13.5 K. The samples with 0 ≤ × ≤ 0.6 contain a superconducting phase with T _c from 9.1 to 5.0 K. The superconducting and magnetic properties of the Y_0.6Dy_0.4Rh₄B₄ sample are examined in detail.