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57Fe hyperfine parameters and phase compositions in Fe-Ni-Co alloys from iron, stony-iron and stony meteorites

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Abstract

Basing on Mössbauer studies of various iron, stony-iron and stony meteorites, we considered a possible relationship of the ranges of magnetic hyperfine field (Heff), Fe-Ni-Co phases and the ranges of Ni concentration in these phases. We suppose that possible relationship of the ranges of Heff with Fe-Ni-Co phases and with the ranges of Ni concentration can be taken as follows: ~345 kOe ≤ Heff ≤ ~365 kOe for the α2-phase (~ 8–25 at% of Ni), ~ 327 kOe < Heff ≤ ~345 kOe for the α-phase (up to 7 at% of Ni), ~ 283 kOe ≤ Heff ≤ ~327 kOe for the γ-phase (~ 26–48 at% of Ni) with the values of ~ 283 kOe ≤ Heff ≤ ~295 kOe which may also be associated with the ordered γ-FeNi(Co) phase (~ 48–52 at% of Ni). The paramagnetic γ-Fe(Ni, Co) phase with ~ 29–33 at% of Ni has the values of isomer shift (δ) in the range of ~ − 0.200 mm/s < δ < ~0.150 mm/s.

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Acknowledgements

This work was supported by the Ministry of Science and Higher Education of the Russian Federation, project № FEUZ-2023-0013. The research funding for M.V.G. and M.I.O. from the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program) is gratefully acknowledged.

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  1. Department of Experimental Physics, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federation

    Michael V. Goryunov & Michael I. Oshtrakh

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  1. Michael V. Goryunov
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M.V.G. and M.I.O did all measurements and spectra fittings. M.I.O. wrote the main manuscript text and prepared Figs. 1, 2, 3 and 4. All authors reviewed and approved the manuscript.

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Correspondence to Michael I. Oshtrakh.

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Goryunov, M.V., Oshtrakh, M.I. 57Fe hyperfine parameters and phase compositions in Fe-Ni-Co alloys from iron, stony-iron and stony meteorites. Hyperfine Interact 245, 19 (2024). https://doi.org/10.1007/s10751-024-01860-x

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